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1,4-DINITROBENZENE

1,4-DINITROBENZENE
1,4-DINITROBENZENE structure
CAS No.
100-25-4
Chemical Name:
1,4-DINITROBENZENE
Synonyms
nsc3809;1.4-Dinitr;dithanea-4;Dithane a-4;p-dinitrlbinzene;P-DINITROBENZENE;p-dinitro-benzen;1,4-Dinitrobenzol;1,4-dinitrlbenzene;1,4-Dinitrobenzenn
CBNumber:
CB3152579
Molecular Formula:
C6H4N2O4
Formula Weight:
168.11
MOL File:
100-25-4.mol

1,4-DINITROBENZENE Properties

Melting point:
170-173 °C(lit.)
Boiling point:
183.4 °C34 mm Hg(lit.)
Density 
1.625 g/mL at 25 °C(lit.)
refractive index 
1.725 (589.3 nm)
Flash point:
150 °C
storage temp. 
2-8°C
solubility 
alcohol: soluble1g in 300ml
form 
Crystals or Powder
color 
Ochre to orange
Water Solubility 
Soluble in water. (0.8 g/L) at 20°C.
Merck 
14,3273
BRN 
1105828
Stability:
Stable, but may be shock-sensitive. May explode if heated. Incompatible with oxidizing agents, strong bases, nitric acid, many metals, tin oxides.
CAS DataBase Reference
100-25-4(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T+,N,T,F
Risk Statements  26/27/28-33-34-50/53-52/53-39/23/24/25-23/24/25-11
Safety Statements  28-36/37-45-60-61-16
RIDADR  UN 3443 6.1/PG 2
WGK Germany  3
RTECS  CZ7525000
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29042090
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H300 Fatal if swallowed Acute toxicity,oral Category 1, 2 Danger P264, P270, P301+P310, P321, P330,P405, P501
H310 Fatal in contact with skin Acute toxicity,dermal Category 1, 2 Danger P262, P264, P270, P280, P302+P350,P310, P322, P361, P363, P405, P501
H320 Causes eye irritation Serious eye damage/eye irritation Category 2B Warning P264, P305+P351+P338,P337+P313
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H370 Causes damage to organs Specific target organ toxicity, single exposure Category 1 Danger P260, P264, P270, P307+P311, P321,P405, P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P262 Do not get in eyes, on skin, or on clothing.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P311 Call a POISON CENTER or doctor/physician.
P320 Specific treatment is urgent (see … on this label).
P330 Rinse mouth.
P391 Collect spillage. Hazardous to the aquatic environment
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P307+P311 IF exposed: call a POISON CENTER or doctor/physician.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container to..…

1,4-DINITROBENZENE price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 102369 1,4-Dinitrobenzene 98% 100-25-4 5g $50 2018-11-13 Buy
Sigma-Aldrich 442250 1,4-Dinitrobenzene analytical standard 100-25-4 442250 $54.6 2018-11-23 Buy
TCI Chemical D0819 1,4-Dinitrobenzene >99.0%(GC) 100-25-4 5g $46 2018-11-22 Buy
TCI Chemical D0819 1,4-Dinitrobenzene >99.0%(GC) 100-25-4 25g $155 2018-11-22 Buy
Alfa Aesar A10293 1,4-Dinitrobenzene, 98+% 100-25-4 5g $42.2 2018-11-13 Buy

1,4-DINITROBENZENE Chemical Properties,Uses,Production

Chemical Properties

light yellow powder

Definition

ChEBI: A dinitrobenzene carrying nitro groups at positions 1 and 4.

Uses

manufacture of dyes, dye intermediates, explosives, plastics.

General Description

Colorless to yellow solid. Sinks and mixes slowly with water.

Air & Water Reactions

Slowly mixes with water.

Reactivity Profile

All three isomers have similar properties and may react vigorously with oxidizing materials. Their reaction with nitric acid (nitration) will lead to a mixture of trinitrobenzenes possessing high-explosive properties [Urbanski, 1967, vol. 3, p. 290]. If heat and reaction conditions of the nitration are not controlled, detonation comparable to TNT may occur [Anon., J. R. Inst. Chem., 1960, 84, p. 451]. Mixture of 1,3-dinitrobenzene with tetranitromethane was found highly explosive [Urbanski, 1964, vol. 1, 592]. 1,2-dinitrobenzene is a severe explosion hazard when shocked or exposed to heat or flame. When heated to decomposition all dinitrobenzens emit toxic fumes of nitrogen oxides [Sax, 9th ed., 1996, p. 1374].

Health Hazard

INHALATION OR INGESTION: Headache, vertigo, nausea, vomiting, diarrhea, fever, rapid weak pulse, decreased blood pressure, cyanosis, exhaustion, hepatomegaly, jaundice, albuminurea, hematuria, visual scotomata, amblyopia and nystagmus. EYES: Irritation. SKIN: Stains skin yellow; if skin contact is prolonged, can be absorbed into blood causing same symptoms as for inhalation.

Safety Profile

Suspected carcinogen. Poison by ingestion. Mutation data reported. Mxture with nitric acid is a high explosive. When heated to decomposition it emits toxic fumes of NOx. See also 0and mDINITROBENZENE

Purification Methods

Crystallise 1,4-dinitrobenzene from EtOH or EtOAc. Dry it under vacuum over P2O5. It can be sublimed in a vacuum. [Beilstein 5 IV 741.]

1,4-DINITROBENZENE Preparation Products And Raw materials

Raw materials

Preparation Products


1,4-DINITROBENZENE Suppliers

Global( 91)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
+86 (0)571-855 867 18
+86 (0)571-858 647 95 sales@capotchem.com China 19954 60
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32651 55
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 24118 58
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 19997 58
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40395 62
3B Pharmachem (Wuhan) International Co.,Ltd. 86-21-50328103 * 801、802、803、804 Mobile:18930552037
86-21-50328109 3bsc@sina.com China 15926 69
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30291 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 / 800-988-0390
021-67121385 Sales-CN@TCIchemicals.com China 24648 81
Energy Chemical 021-58432009 / 400-005-6266
021-58436166-800 info@energy-chemical.com China 44187 61

View Lastest Price from 1,4-DINITROBENZENE manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-07-31 1,4-DINITROBENZENE
100-25-4
US $1500.00 / KG 1KG 98% 100kg career henan chemical co

1,4-DINITROBENZENE Spectrum


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