METIRAM
- CAS No.
- 9006-42-2
- Chemical Name:
- METIRAM
- Synonyms
- amarex;POLYRAM;FMC9102;METIRAM;THIUMET;Metriam;nia9102;polymat;Methiram;MetriraM
- CBNumber:
- CB3220555
- Molecular Formula:
- C12H12N6S16Zn
- Molecular Weight:
- 818.69388
- MDL Number:
- MFCD00166315
- MOL File:
- 9006-42-2.mol
| Melting point | 156℃ (approx, Decomposition) |
|---|---|
| storage temp. | 0-6°C |
| solubility | DMSO (Slightly, Heated) |
| form | Solid |
| color | Off-White |
| EWG's Food Scores | 6 |
| Proposition 65 List | Metiram |
| Pesticides Freedom of Information Act (FOIA) | Metiram |
| EPA Substance Registry System | Metiram (9006-42-2) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS09 |
|---|---|
| Signal word | Warning |
| Hazard statements | H317-H410 |
| Precautionary statements | P261-P272-P280-P302+P352-P333+P313-P321-P363-P501-P273-P391-P501 |
| RIDADR | UN 1282 3 / PGII |
| RTECS | TR6250000 |
METIRAM price More Price(1)
METIRAM Chemical Properties,Uses,Production
Chemical Properties
Light yellow solid or powder at room temperature. Characteristic dithiocarbamate odor.
Uses
Metriram is a polymeric dithiocarbamic fungicide used in agriculture. Metiram is present as a mixture rather than a complex and is not assigned an ISO name. Metiram is used commonly in the protection of grapevines, apples, tomatoes, potatoes as well as other crops.
Definition
ChEBI: Zineb is a polymeric complex of zinc with the ethylene bis(dithiocarbamate) anionic ligand. Formerly used as an agricultural fungicide for the control of downy mildews and rusts, its use is no longer permitted in the US or the EU. It has a role as an antifungal agrochemical. It is a macromolecule, a zinc coordination entity and a dithiocarbamate salt. It contains an ethylenebis(dithiocarbamate).
General Description
Yellow powder. Non corrosive. Insoluble in water. Used as an fungicide.
Air & Water Reactions
Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids and bases. Insoluble in water.
Reactivity Profile
METIRAM is a dithiocarbamate. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides.
Hazard
Toxic by ingestion and inhalation.
Agricultural Uses
Fungicide: Metiram is used to protect fruits, vegetables, field crops and other crops and ornamentals against many types of fungi and other foliar diseases.
Trade name
ATLAS® BRAND[C]; AMAREX®; NIA 9102®[C]; NIAGARA[C]; POLYCARBACIN®; POLYCARBACINE®; POLYCARBAZIN®; POLYCARBAZINE®; POLYMARCIN®; POLYMARCINE®; POLYMARSIN®; POLYMARZIN®; POLYMARZINE®; POLYRAM®
Potential Exposure
Metiram is a dithiocarbamate fungicide used on fruits, vegetables, field crops and other crops and on ornamentals to protect against many types of fungi and other foliar diseases.
Shipping
UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
Incompatibilities
Combustible material. Dust may form explosive mixture in air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Dithiocarbamate esters are combustible. They react violently with powerful oxidizers such as calcium hypochlorite. Poisonous gases are generated by the thermal decomposition of dithiocarbamate compounds, including carbon disulfide, oxides of sulfur, oxides of nitrogen, hydrogen sulfide, ammonia, and methylamine. Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Flammable gases are generated by the combination of dithiocarbamate with aldehydes, nitrides, and hydrides. Dithiocarbamate are incompatible with acids, peroxides, and acid halides. Thermal decomposition products in fire includes oxides of nitrogen and sulfur. Corrosive to iron, copper brass and zinc metals, especially in the presence of moisture. Heat alkalies (lime), moisture can cause decomposition. Decomposes on prolonged storage. Degradation produces ethylene thiourea.
Waste Disposal
Do not discharge into drains or sewers. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform to EPA regulations governing storage, transportation, treatment, and waste disposal. A potential candidate for liquid injection incineration at a temperature range of 650 to 1600℃ and a residence time 0.1 to 2 seconds. Also, a potential candidate for rotary kiln incineration at a temperature range of 820 to 1600℃ and residence times of seconds for liquids and gases, and hours for solids.
METIRAM Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
| Shandong chuangyingchemical Co., Ltd. | 18853181302 | sale@chuangyingchem.com | CHINA | 5909 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
| career henan chemical co | +86-0371-86658258 15093356674; | factory@coreychem.com | China | 29826 | 58 |
| SIMAGCHEM CORP | +86-13806087780 | sale@simagchem.com | China | 17367 | 58 |
| TargetMol Chemicals Inc. | +1-781-999-5354 +1-00000000000 | marketing@targetmol.com | United States | 19892 | 58 |
| Hebei Duling International Trade Co. LTD | +8618712993135 | sales01@hbduling.cn | China | 15741 | 58 |
| LEAPCHEM CO., LTD. | +86-852-30606658 | market18@leapchem.com | China | 43348 | 58 |
| Shanghai Acmec Biochemical Technology Co., Ltd. | +undefined18621343501 | product@acmec-e.com | China | 33350 | 58 |
| Aladdin Scientific | +1-833-552-7181 | sales@aladdinsci.com | United States | 57511 | 58 |
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