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4-Methoxybenzylchloride

4-Methoxybenzylchloride Structure
4-Methoxybenzylchloride structure
CAS No.
824-94-2
Chemical Name:
4-Methoxybenzylchloride
Synonyms
PMBCl;4-METHOXYBENZYL CHLORIDE;P-METHOXYBENZYL CHLORIDE;PBMCl;4-(Chloromethyl)-1-methoxybenzene;4-Methoxybenzylchloride, stabilized, 98% 5GR;p-Anisyl chloride;NSC 172955;ANISYL CHLORIDE;AKOS BBS-00003861
CBNumber:
CB3330683
Molecular Formula:
C8H9ClO
Molecular Weight:
156.61
MDL Number:
MFCD00000915
MOL File:
824-94-2.mol
MSDS File:
SDS
Last updated:2025-11-25 16:34:26
Product description Number Pack Size Price
4-Methoxybenzyl Chloride (stabilized with Amylene) >98.0%(GC)(T) M0676 25mL $93
4-Methoxybenzyl Chloride (stabilized with Amylene) min. 98.0 % M0676 100ML $267
4-MethoxybenzylChloride(Stabilized) M261105 5g $95
4-Methoxybenzyl chloride,Contains Potassium carbonate as stabilizer. ≥ 99% (GC) 00213 100G $120
4-Methoxybenzyl chloride 97% 2707-5-14 100g $274
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4-Methoxybenzylchloride Properties

Melting point −1 °C(lit.)
Boiling point 117-118 °C14 mm Hg(lit.)
Density 1.155 g/mL at 25 °C(lit.)
refractive index n20/D 1.548(lit.)
Flash point 229 °F
storage temp. Inert atmosphere,2-8°C
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
form Liquid
color Clear colorless to pale yellow
Water Solubility slowly decomposes
Stability Moisture Sensitive
InChI InChI=1S/C8H9ClO/c1-10-8-4-2-7(6-9)3-5-8/h2-5H,6H2,1H3
InChIKey MOHYOXXOKFQHDC-UHFFFAOYSA-N
SMILES C1(CCl)=CC=C(OC)C=C1
CAS DataBase Reference 824-94-2(CAS DataBase Reference)
FDA UNII Q500ZS03TI
NIST Chemistry Reference «alpha»-Chloro-4-methoxytoluene(824-94-2)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H290-H314
Precautionary statements  P234-P260-P264-P280-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P390-P405-P406-P501
Hazard Codes  C
Risk Statements  34
Safety Statements  26-27-36/37/39-45
RIDADR  UN 3265 8/PG 3
WGK Germany  3
F  10-19-21
Autoignition Temperature 109℃
Hazard Note  Corrosive
TSCA  No
HazardClass  8
PackingGroup  III
HS Code  29093090
NFPA 704
1
3 0

4-Methoxybenzylchloride price More Price(27)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical M0676 4-Methoxybenzyl Chloride (stabilized with Amylene) >98.0%(GC)(T) 824-94-2 25mL $93 2025-07-31 Buy
TCI Chemical M0676 4-Methoxybenzyl Chloride (stabilized with Amylene) min. 98.0 % 824-94-2 100ML $267 2025-07-31 Buy
TRC M261105 4-MethoxybenzylChloride(Stabilized) 824-94-2 5g $95 2021-12-16 Buy
Chem-Impex 00213 4-Methoxybenzyl chloride,Contains Potassium carbonate as stabilizer. ≥ 99% (GC) 824-94-2 100G $120 2021-12-16 Buy
SynQuest Laboratories 2707-5-14 4-Methoxybenzyl chloride 97% 824-94-2 100g $274 2021-12-16 Buy
Product number Packaging Price Buy
M0676 25mL $93 Buy
M0676 100ML $267 Buy
M261105 5g $95 Buy
00213 100G $120 Buy
2707-5-14 100g $274 Buy

4-Methoxybenzylchloride Chemical Properties,Uses,Production

Chemical Properties

Colorless liquid

Uses

4-Methoxybenzylchloride is used in a synthesis of diarymethanes via Suzuki cross-coupling with postassium aryltrifluoroborates. It is also an O/N protecting group reagent which can be mildly oxidatively cleaved, e.g., with ceric ammonium nitrate.

Reactions

4-Methoxybenzylchloride reacts with strong oxidizing agents and strong bases.

Synthesis Reference(s)

Journal of Medicinal Chemistry, 20, p. 190, 1977 DOI: 10.1021/jm00212a002
The Journal of Organic Chemistry, 53, p. 3634, 1988 DOI: 10.1021/jo00250a048

General Description

4-Methoxybenzyl chloride undergoes mild oxidative claevage with ceric ammonium nitrate.

Hazard

4-Methoxybenzylchloride is danger, it may be corrosive to metals. It causes severe skin burns and eye damage.

Hazard

4-Methoxybenzylchloride is danger, it may be corrosive to metals. It causes severe skin burns and eye damage.

Purification Methods

Purify 4-anisyl chloride by fractional distillation under vacuum, and the middle fraction is redistilled at 10-6 mm at room temperature by intermittent cooling of the receiver in liquid N2, and the middle fraction is collected. [Mohammed & Kosower J Am Chem Soc 93 2709 1971, Beilstein 6 IV 2137.]

4-Methoxybenzylchloride synthesis

105-13-5
824-94-2
Synthesis of 4-Methoxybenzylchloride from 4-Methoxybenzyl alcohol

4-Methoxybenzylchloride Preparation Products And Raw materials

Raw materials

Preparation Products

4-Methoxybenzyl cyanide 1-(4-METHOXYBENZYL)PIPERAZINE 1,6:2,3-Dianhydro-β-D-mannopyranose H-BETA,BETA-DIMETHYL-L-CYS(PMEOBZL)-OH 4-METHOXYBENZYLMAGNESIUM CHLORIDE
4(3H)-Pyrimidinone, 5-bromo-6-(difluoromethyl)-3-[(4-methoxyphenyl)methyl]- 1-(4-METHOXYBENZYL)-1H-INDOLE-2,3-DIONE Methyl 1-[(4-methoxyphenyl)methyl]-1H-indazole-3-carboxylate 2-Propenoic acid, (4-methoxyphenyl)methyl ester 3-bromo-6-((4-methoxybenzyl)oxy)benzaldehyde
Carbamimidothioicacid, (4-methoxyphenyl)methyl ester, hydrochloride (1:1) 2-Pyrimidinamine, 5-bromo-N,N-bis[(4-methoxyphenyl)methyl]- Benzaldehyde, 2-[(4-methoxyphenyl)methoxy]-

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4-Methoxybenzylchloride Suppliers

Global( 519)Suppliers
Supplier Tel Email Country ProdList Advantage
Nanjing Qiangshan New Material Co.,Ltd.
+86-13951653990 jjx35259720@hotmail.com China 27 58
Hebei Chuanghai Biotechnology Co,.LTD 		+86-13131129325 sales1@chuanghaibio.com China 5249 58
Henan Bao Enluo International TradeCo.，LTD 		+86-17331933971 deasea125996@gmail.com China 2472 58
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 20134 58
Capot Chemical Co.,Ltd. 		+86-（0）57185586718; +8613336195806 sales@capot.com China 29735 60
Dalian Richfortune Chemicals Co., Ltd 		+86-86-411-84820922 +86-8613904096939 sales@richfortunechem.com China 305 57
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21612 55
Nanjing ChemLin Chemical Industry Co., Ltd. 		025-83697070 product@chemlin.com.cn CHINA 3009 60
Speranza Chemical Co., Ltd. 		+86-86-075521030354 +8618688942810 sophieliu@speranzachem.com China 925 55
Zjartschem 		+86-571 87238903 jocelynpan@zjarts.com CHINA 988 58
Supplier Advantage
Nanjing Qiangshan New Material Co.,Ltd.
58
Hebei Chuanghai Biotechnology Co,.LTD 		58
Henan Bao Enluo International TradeCo.，LTD 		58
Henan Fengda Chemical Co., Ltd 		58
Capot Chemical Co.,Ltd. 		60
Dalian Richfortune Chemicals Co., Ltd 		57
Henan Tianfu Chemical Co.,Ltd. 		55
Nanjing ChemLin Chemical Industry Co., Ltd. 		60
Speranza Chemical Co., Ltd. 		55
Zjartschem 		58

View Lastest Price from 4-Methoxybenzylchloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Methoxybenzylchloride pictures 2025-12-01 4-Methoxybenzylchloride
824-94-2
 US $0.00 / kg 1kg 99% 10000KGS Shaanxi Dideu New Materials Co. Ltd
4-Methoxybenzylchloride pictures 2025-11-20 4-Methoxybenzylchloride
824-94-2
 US $0.00-0.00 / kg 1kg 98% 100tons Shandong Vital Biotechnology Co., Ltd.
4-Methoxybenzylchloride pictures 2025-09-25 4-Methoxybenzylchloride
824-94-2
 US $10.00-1.00 / kg 1kg 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd

4-Methoxybenzylchloride Spectrum

4-Methoxybenzylchloride(824-94-2)1HNMR4-Methoxybenzylchloride(824-94-2)IR14-Methoxybenzylchloride(824-94-2)Raman

824-94-2(4-Methoxybenzylchloride)Related Search:

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4-Methoxybenzyl alcohol 4-Methoxybenzylamine 4-Chlorobenzyl cyanide 4-Nitrobenzyl chloroformate 4-Chlorobenzyl chloride
Benzyl chloroformate 3-Bromoanisole 4-Methylbenzyl chloride 4'-Methoxyacetophenone 4-Methoxybenzyl cyanide
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alpha-Chloro-4-methoxytoluene Anisole, p-(chloromethyl)- Benzene, 1-(chloromethyl)-4-methoxy- p-(Chloromethyl)anisole Anisyl Chloride 4-(Chloromethyl)anisole 4-Methoxybenzyl chloride contains potassiuM carbonate as stabilizer, 98% The Methoxy benzyl chloride para-chloromethylanisole METHOXYBENZYLCHLORIDE(P-) 1-CHLOROMETHYL-4-METHOXYBENZENE AKOS BBS-00003861 ANISYL CHLORIDE 4-(CHLOROMETHYL)ANISOL 4-(CHLOROMETHYL)ANISOLE P-methoxyl benzylchloride 4-Methoxybenzylchloride99% 4-Methoxybenzylchloride 99% 4-Methoxybenzene methyl chloride α-Chloro-4-methoxytoluene 4-Methoxybenzylchloride, stabilized, 98% 4-METHOXYBENZYL CHLORIDE (STABILIZED WITH CALCIUM CARBONATE) 4-METHYOXYBENZYL CHLORIDE 4-METHOXYBENZYLCHLORIDE / 4-(CHLOROMETHYL)ANISOLE 4) PARA METHOXY BENZYL CHLORIDE 1-(Chloromethyl)-4-methoxybenzene, 4-(Chloromethyl)anisole 4-Methoxybenzyl Chloride (stabilized with Amylene) 4-Methoxybenzylchloride, 98%, stabilized 4-Chloromethylphenyl methyl ether 4-Methoxy-1-(chloromethyl)benzene 4-Methoxybenzylchloride ,98% 4-Methoxybenzylchlor 4-Methoxybenzylchloride, stabilized, 98% 25GR 4-Methoxybenzyl chloride, 98%, stabilized with potassium carbonate 4-Methoxybenzyl chloride, 98% (Stabilized with Calcium carbote) 4-Methoxybenzyl chloride, 98%, for synthesis 4-MethoxybenzylChloride(stabilizedwithAmylene)> 4-methoxychlorobenzyl 1-(Chloromethyl)-4-(methyloxy)benzene 4-(Chloromethyl)anisole (stabilized with Amylene) 4-Methyloxybenzyl chloride Anisyl Chloride (stabilized with Amylene) NSC 172955 p-(Chloromethyl)(methoxy)benzene α-Chloro-p-methoxytoluene P-METHOXYBENZYL CHLORIDE p-Anisyl chloride 4-METHOXYBENZYL CHLORIDE PMBCl PBMCl 4-Methoxybenzylchloride, stabilized, 98% 5GR 4-(Chloromethyl)-1-methoxybenzene p-methoxychlorbenzyl 4-Methoxy Benzyl chloride, contains 1% potassium carbonate as stabilizer, 95% 4-Methoxybenzyl Chloride (stabilized with Potassium carbonate) Monensin Impurity 4 1-(Chloromethyl)-4-methoxybenzene,97%(stabilized with K2CO3) 4-Methoxybenzyl chloride - stabilised with potassium carbonate 824-94-2