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Ethyl 1,1,2,2-tetrafluoroethyl ether

CAS No.
512-51-6
Chemical Name:
Ethyl 1,1,2,2-tetrafluoroethyl ether
Synonyms
HFE-347E;Ethyltetrafluoroethyl ether;1,1,2,2-TETRAFLUOROETHYL ETHYL ETHER;HFE-374E;374pcebetagamma;Hydrofluoroethers;Hydrofluoro Ethers;Tetrafluoroethyl Ether;HYDROFLUOROETHER(HFE-374);1,1,2,2-Tetrafluoro ethyl ether
CBNumber:
CB4201225
Molecular Formula:
C4H6F4O
Molecular Weight:
146.08
MDL Number:
MFCD00069162
MOL File:
512-51-6.mol
MSDS File:
SDS
TDS File:
TDS
Last updated:2026-05-28 02:11:23

Ethyl 1,1,2,2-tetrafluoroethyl ether Properties

Melting point -86°C (lit.)
Boiling point 57 °C
Density 1.198
refractive index 1.294
Flash point 56-58°C
form clear liquid
color Colorless to Almost colorless
Specific Gravity 1.198
Major Application battery manufacturing
InChI InChI=1S/C4H6F4O/c1-2-9-4(7,8)3(5)6/h3H,2H2,1H3
InChIKey HBRLMDFVVMYNFH-UHFFFAOYSA-N
SMILES C(OCC)(F)(F)C(F)F
CAS DataBase Reference 512-51-6(CAS DataBase Reference)
EPA Substance Registry System Ethane, 1-ethoxy-1,1,2,2-tetrafluoro- (512-51-6)
UNSPSC Code 12352100
NACRES NA.21

SAFETY

Risk and Safety Statements

Symbol(GHS)  Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
Signal word  Danger
Hazard statements  H225-H315-H319-H335
Precautionary statements  P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Hazard Codes  F,Xi
Risk Statements  11
Safety Statements  16-23-33
RIDADR  3271
WGK Germany  WGK 3
RTECS  KI3590000
Hazard Note  Flammable
HazardClass  3
PackingGroup  II
HS Code  2909199090
Storage Class 3 - Flammable liquids
Hazard Classifications Flam. Liq. 2
Toxicity LC inhalation in rat: > 30000ppm/4H
NFPA 704
3
2 0

Ethyl 1,1,2,2-tetrafluoroethyl ether price More Price(26)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 934046 Ethyl 1,1,2,2-tetrafluoroethyl ether ≥99%, anhydrous, battery grade 512-51-6 50G $220 2026-04-30 Buy
TCI Chemical E1019 Ethyl 1,1,2,2-Tetrafluoroethyl Ether >98.0%(GC) 512-51-6 5g $23 2026-04-30 Buy
TCI Chemical E1019 Ethyl 1,1,2,2-Tetrafluoroethyl Ether >98.0%(GC) 512-51-6 25g $46 2026-04-30 Buy
Fluoryx FC13-3700 > 99% 512-51-6 100g $85 2026-09-18 Buy
Fluoryx FC13-3700 > 99% 512-51-6 25g $101 2026-09-18 Buy
Product number Packaging Price Buy
934046 50G $220 Buy
E1019 5g $23 Buy
E1019 25g $46 Buy
FC13-3700 100g $85 Buy
FC13-3700 25g $101 Buy

Ethyl 1,1,2,2-tetrafluoroethyl ether Chemical Properties, Uses, Production

Description

Ethyl 1,1,2,2-tetrafluoroethyl ether (ETFE) is a fluorinated linear ether with several fundamental properties that make it useful in batteries. First, ETFE is miscible with many polar organic solvents used in electrolyte formulations, which improves the ionic conductivity of the battery. Additionally, ETFE has a relatively low viscosity (486 mPas at 23 °C) and a low boiling point (58 °C), which make it a versatile diluent for low-temperature applications.

Uses

Ethyl 1,1,2,2-tetrafluoroethyl ether (ETFE) is a highly effective additive in lithium-ion and sodium-ion batteries for improving battery performance, increasing safety, and reducing flammability. ETFE is a versatile co-solvent with high miscibility, which allows it to be blended with other solvents to achieve high ionic conductivities. It is also a good SEI-forming electrolyte additive, stabilizing the Na electrode surface and enhancing the stability of high-voltage batteries. ETFE is particularly useful as an electrolyte co-solvent in lithium-sulfur (Li-S) batteries. Studies have shown that ETFE-containing electrolytes improve the stability of the electrolyte/anode interface and enhance the cycling, rate, and self-discharging of the Li-S cell more than glyme-based cosolvents or unblended solvents.

116-14-3
141-52-6
512-51-6
Synthesis of Ethyl 1,1,2,2-tetrafluoroethyl ether from Tetrafluoroethylene and Sodium ethoxide

Ethyl 1,1,2,2-tetrafluoroethyl ether Preparation Products And Raw materials

Global Suppliers ( 192)
Supplier Tel Email Country ProdList Advantage
Fuxin Ruifeng Fluorine Chemicals Co.,Ltd 13941692605; 18741878758 fxrffhx@163.com China 49 58
Hubei Wande Chemical Co., Ltd 15377098680 15377098680 1148280011@qq.com China 9426 58
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30103 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24512 81
Energy Chemical 400-0056266 18918157536; sales8178@energy-chemical.com China 45000 61
Shanghai Sinch Parmaceuticals Tech. Co. Ltd. +86-21-54098501 sales@sinch.com.cn China 11592 64
Pure Chemistry Scientific Inc. 001-857-928-2050 or 1-888-588-9418 sales@chemreagents.com United States 10174 62
XiaoGan ShenYuan ChemPharm co,ltd 15527621225; 15527621225 1791901229@qq.com China 6723 52
TOKYO CHEMICAL INDUSTRY CO., LTD. 03-36680489 Sales-JP@TCIchemicals.com Japan 28364 80

View Latest Price from Ethyl 1,1,2,2-tetrafluoroethyl ether manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
CHLUMOFIUOR? CH-374 Tetrafluoroethyl ethyl ether pictures 2025-04-10 CHLUMOFIUOR? CH-374 Tetrafluoroethyl ethyl ether
512-51-6
1kg 99% 20 tons Changyi Longchang Bio-Chemical Co., LTD
Ethyl 1,1,2,2-tetrafluoroethyl ether pictures 2025-04-04 Ethyl 1,1,2,2-tetrafluoroethyl ether
512-51-6
1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
Ethyl 1,1,2,2-tetrafluoroethyl ether pictures 2023-05-03 Ethyl 1,1,2,2-tetrafluoroethyl ether
512-51-6
1KG 99.5% 10000 Wuhan Silworld Chemical Co.,Ltd
ether,ethyl1,1,2,2-tetrafluoroethyl 1,1,2,2-Tetrafluoro ethyl ether 3-Oxa-1,1,2,2-tetrafluoropentane, 1-Ethoxy-1,1,2,2-tetrafluoroethane Ethane,1-ethoxy-1,1,2,2-tetrafluoro- HYDROFLUOROETHER(HFE-374) 1-ethoxy-1,1,2,2-tetrafluoro-ethan 1-ethoxy-1,1,2,2-tetrafluoroethane 374pcebetagamma ETHYL 1,1,2,2-TETRAFLUOROETHYL ETHER HFE-374E Ethyl1,1,2,2-TetrafluoroethylEther> Tetrafluoroethyl Ether 1,1,2,2-TETRAFLUOROETHYL ETHYL ETHER CHLUMOFIUOR CH-374 Tetrafluoroethyl ethyl ether Hydrofluoro Ethers Hydrofluoroethers Ethyltetrafluoroethyl ether HFE-347E 512-51-6 C4H6F4O HCF2CF2OCH2CH3