Methyl 4-methoxyacetoacetate
- CAS No.
- 41051-15-4
- Chemical Name:
- Methyl 4-methoxyacetoacetate
- Synonyms
- 4-Methoxyacetoacetate;Methyl 4-methoxy-3-oxobu;Methyl methoxyacetoacetate;Methyl 4-Methoxyacetoacetat;Dolutegravir Intermediates2;METHYL 4-METHOXYACETOACETATE;Methyl 3-oxo-4-methoxybutyrate;METHYL 4-METHOXYACETOXYACETATE;methyl 4-methoxy-3-oxobutyrate;Methyl4-Methoxyacetoacetate>
- CBNumber:
- CB5291234
- Molecular Formula:
- C6H10O4
- Molecular Weight:
- 146.14
- MDL Number:
- MFCD00010183
- MOL File:
- 41051-15-4.mol
- MSDS File:
- SDS
Melting point | -80℃ |
---|---|
Boiling point | 89 °C/8.5 mmHg (lit.) |
Density | 1.129 g/mL at 25 °C (lit.) |
refractive index |
n |
Flash point | 193 °F |
storage temp. | Sealed in dry,Room Temperature |
form | clear liquid |
pka | 9.88±0.46(Predicted) |
Specific Gravity | 1.129 |
color | Colorless to Light yellow to Light orange |
BRN | 1761215 |
InChIKey | QGBPKJFJAVDUNC-UHFFFAOYSA-N |
LogP | 0.340 (est) |
CAS DataBase Reference | 41051-15-4(CAS DataBase Reference) |
NIST Chemistry Reference | Methyl 4-methoxyacetoacetate(41051-15-4) |
EPA Substance Registry System | Methyl 4-methoxyacetoacetate (41051-15-4) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 26-36 | |||||||||
WGK Germany | 3 | |||||||||
F | 10 | |||||||||
HS Code | 29189900 | |||||||||
NFPA 704 |
|
Methyl 4-methoxyacetoacetate price More Price(30)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 281506 | Methyl 4-methoxyacetoacetate 97% | 41051-15-4 | 5g | $58.56 | 2024-03-01 | Buy |
Sigma-Aldrich | 281506 | Methyl 4-methoxyacetoacetate 97% | 41051-15-4 | 25g | $201 | 2024-03-01 | Buy |
TCI Chemical | M1031 | Methyl 4-Methoxyacetoacetate >97.0%(GC) | 41051-15-4 | 5g | $50 | 2024-03-01 | Buy |
TCI Chemical | M1031 | Methyl 4-Methoxyacetoacetate >97.0%(GC) | 41051-15-4 | 25g | $139 | 2024-03-01 | Buy |
TRC | M320845 | Methyl 4-Methoxyacetoacetate | 41051-15-4 | 10g | $165 | 2021-12-16 | Buy |
Methyl 4-methoxyacetoacetate Chemical Properties,Uses,Production
Chemical Properties
colorless to yellow liquid
Uses
Methyl 4-methoxyacetoacetate has been used in generation of a small focused library of diversely functionalized dihydropyrimidine derivatives via one-pot three-component Biginelli cyclocondensation of β-ketoesters, aldehydes and (thio)ureas.
Uses
Methyl 4-Methoxyacetoacetate is a reactant in the formation of an abiotic poorphyrinogen in aqueous solution.
Preparation
The preparation method of a 4-methoxyl group methyl acetoacetate: add solvents tetrahydrofurane in a kettle. and pass into rare gas element, the temperature in the kettle arranging reactor is 15-25℃, industrial sodium hydride and metal alkaline compound is added under whipped state, add solvents tetrahydrofurane again, the mixed solution reaction 4-6h of methyl alcohol and 4-chloro methyl acetoacetate is dripped in less than 20℃, then be warming up to 20-25℃ and continue reaction 4-15h, TLC detection reaction is complete, reduce system temperature to 6-10℃, add the hydrochloric acid soln regulation system pH=5-7 that volumetric molar concentration is 2mol/L, stratification, after separatory, upper strata is concentrated is spin-dried for removing solvents tetrahydrofurane, then colorless product 4-methoxyl group methyl acetoacetate is obtained by wiped film molecular distillation.
Methyl 4-methoxyacetoacetate Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Baynoe Chem (Suzhou) Co., Ltd. | +86-512 65869404 +86-18934593683 | sales06@baynoe.com | China | 292 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12456 | 58 |
Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5993 | 58 |
Hangzhou ICH Biofarm Co., Ltd | +undefined8613073685410 | sales@ichemie.com | China | 985 | 58 |
Anhui Ruihan Technology Co., Ltd | +8617756083858 | daisy@anhuiruihan.com | China | 994 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15928 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9348 | 55 |
Fluoropharm Co., Ltd. | +86-0571-85586753; +8613336034509 | sales@fluoropharm.com | China | 1290 | 60 |
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View Lastest Price from Methyl 4-methoxyacetoacetate manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2023-11-02 | Methyl 4-methoxyacetoacetate
41051-15-4
|
US $20.00-1.00 / kg | 1kg | 0.99 | 10 tons | Hebei Yanxi Chemical Co., Ltd. | ||
2023-11-01 | Methyl 4- Methoxyacetoacetate
41051-15-4
|
US $0.00-0.00 / kg | 1kg | 99.0% | 20 tons | Hangzhou ICH Biofarm Co., Ltd | ||
2023-10-19 | Methyl 4-methoxyacetoacetate
41051-15-4
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd |
- Methyl 4-methoxyacetoacetate
41051-15-4
- US $20.00-1.00 / kg
- 0.99
- Hebei Yanxi Chemical Co., Ltd.
- Methyl 4- Methoxyacetoacetate
41051-15-4
- US $0.00-0.00 / kg
- 99.0%
- Hangzhou ICH Biofarm Co., Ltd
- Methyl 4-methoxyacetoacetate
41051-15-4
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
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