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R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& structure

CAS No.: 133545-16-1

Chemical Name:: R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&

Synonyms: SL-A101-1;(R)-(+)-MeO-BIPHEP;97% (R)-MeO-BIPHEP;R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&;R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&;R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&(6,6'-Dimethoxy-2,2'-biphenyldiyl)bis(diphenylphosphine);(R)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'- bipheny;(R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosph...;(R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine)

CBNumber:: CB6502935

Molecular Formula:: C38H32O2P2

Molecular Weight:: 582.62

MDL Number:: MFCD03095430

MOL File:: 133545-16-1.mol

MSDS File:: SDS

Last updated:2023-04-23 13:52:06

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R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& Properties

Melting point	213-216 °C
alpha	101 º (C=0.3 IN TOLUENE)
Boiling point	651.1±55.0 °C(Predicted)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
form	crystal
color	off-white

SAFETY

Risk and Safety Statements

WGK Germany	3
F	8-10-23
HS Code	29319090

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& price More Price(13)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Strem Chemicals	15-0178	(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP	133545-16-1	100mg	$96	2024-03-01	Buy
Strem Chemicals	15-0178	(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP	133545-16-1	500mg	$355	2024-03-01	Buy
Strem Chemicals	15-0178	(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP	133545-16-1	2g	$1207	2024-03-01	Buy
Strem Chemicals	15-0178	(R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% (R)-MeO-BIPHEP	133545-16-1	10g	$4824	2024-03-01	Buy
BLDpharm	BD256651	(R)-(6,6'-Dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine) 98+%	133545-16-1	5g	$1377	2021-12-16	Buy

Product number	Packaging	Price	Buy
15-0178	100mg	$96	Buy
15-0178	500mg	$355	Buy
15-0178	2g	$1207	Buy
15-0178	10g	$4824	Buy
BD256651	5g	$1377	Buy

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& Chemical Properties,Uses,Production

Chemical Properties

White powder

Uses

Ligand for ruthenium-catalyzed greener amine synthesis by enamine reduction with hydrogen gas.

Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination

Reactions

In many respects the catalytic profile of the MeOBIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.
Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives.

1.Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.
Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds.
Conjugate addition using 2-heteroaryl titanates and zinc reagents.
Enantio- and regioselective heck-type reaction of aryl boronic acids with 2,3-dihydrofuran
Rhodium-catalyzed carbonyl Z-dienylation.
Rhodium-catalyzed asymmetric 1,4 addition of arylboronic acids to maleimides and enones.

General Description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& Preparation Products And Raw materials

Raw materials

Preparation Products

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& Suppliers

Global( 67)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
career henan chemical co	+86-0371-86658258 15093356674;	sales@coreychem.com	China	29914	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Chongqing Chemdad Co., Ltd	+86-023-6139-8061 +86-86-13650506873	sales@chemdad.com	China	39916	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49391	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	+86-021-61551413 +8618813727289	contact@trustwe.com	China	5738	58
Wuhan Fortuna Chemical Co., Ltd	+86-027-59207850	info@fortunachem.com	China	6000	58
XINXIANG RUNYU MATERIAL CO., LTD.	+86-13592593621; +8613592593621	sales@runvmat.com	China	425	58
changzhou huayang technology co., ltd	+8615250961469	2571773637@qq.com	China	9821	58
Labnetwork lnc.	+86-27-50766799 +8618062016861	contact@labnetwork.com	China	19994	58
Hefei TNJ Chemical Industry Co.,Ltd.	0551-65418684 +8618949823763	sales@tnjchem.com	China	25363	58

Supplier	Advantage
career henan chemical co	58
Hubei Jusheng Technology Co.,Ltd.	58
Chongqing Chemdad Co., Ltd	58
CONIER CHEM AND PHARMA LIMITED	58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.	58
Wuhan Fortuna Chemical Co., Ltd	58
XINXIANG RUNYU MATERIAL CO., LTD.	58
changzhou huayang technology co., ltd	58
Labnetwork lnc.	58
Hefei TNJ Chemical Industry Co.,Ltd.	58

View Lastest Price from R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2023-01-31	(R)-(6,6'-Dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine) 133545-16-1	US $0.00 / KG	1KG	98%min	30tons/month	WUHAN FORTUNA CHEMICAL CO., LTD
	2019-08-09	R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& 133545-16-1	US $1.00 / KG	1KG	98%	1kg,5kg,100kg	Career Henan Chemical Co

(R)-(6,6'-Dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine)
133545-16-1
US $0.00 / KG
98%min
WUHAN FORTUNA CHEMICAL CO., LTD

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&
133545-16-1
US $1.00 / KG
98%
Career Henan Chemical Co

133545-16-1(R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-&)Related Search:

R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& (R)-DIFLUORPHOS(TM) (S)-(-)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole,min.98%(S)-SEGPHOS (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny (R)-CYCLOHEXYL SONIPHOS

(R)-C3-TUNEPHOS-RUTHENIUM COMPLEX (R)-(+)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% R-(+)-N,N'-DIMETHYL-7,7'-BIS(DI(3,5-XYLYL)PHOSPHINO)-3,3',4,4'-TETRAHYDRO-8,8'-BI-2H-1,4-BENZOXAZINE ISOPROPANOL ADDUCT (R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BIPHENYL (S)-(-)-2,2'-Bis[di(3,5-di-t-butylphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%

(R)-C3-TUNEPHOS (S)-(+)-5,5'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole,min.98%(S)-DTBM-SEGPHOS (S)-(-)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% R-(+)-6,6'-BIS(DIPHENYLPHOSPHINO)-2,2',3,3'-TETRAHYDRO-5,5'-BI-1,4-BENZODIOXIN SOLPHOS SL-A001-1

(R)-METHYL SONIPHOS CHLORO[(R)-(+)-5,5'-DICHLORO-6,6'-DIMETHOXY-2,2'-BIS(DIPHENYL-PHOSPHINO)-1,1'-BIPHENYL](P-CYMENE)RUTHENIUM(II) CHLORIDE CH2CL2 ADDUCT (S)-(-)-2,2'-BIS[3'',4''-METHYLENEOXYPHENYLPHOSPHINO]-5,6-5',6'-DIMETHYLENEOXY-BIPHENYL

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R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& (R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%(R)-MeO-BIPHEP (R)-(+)-MeO-BIPHEP, SL-A101-1, (R)-(+)-2,2μ-Bis(diphenylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl 97% (R)-MeO-BIPHEP (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-diMethoxy-1,1'-biphenyl,(R)-MeO-BIPHEP (R)-(+)-MeO-BIPHEP SL-A101-1 (R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) >=97%, optical purity ee: >=99% (S)-(6,6,-dimethoxy-[1,1,-biphenyl]-2,2,-diyl)bis(diphenylphosphine) (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,97% (R)-MeO-BIPHEP (6,6'-Dimethoxy-2,2'-biphenyldiyl)bis(diphenylphosphine) 1,1'-[(1R)-6,6'-Dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis(1,1-diphenyl)-phosphine Phosphine, 1,1'-[(1R)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-diphenyl- (R)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'- bipheny (R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosph... R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& (R)-(+)-2,2'-Bis(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl R(+)-2 2'-BIS-(DIPHENYLPHOSPHINO)-6 6'-& (R)-(+)-(6,6’-Dimethoxybiphenyl-2,2’-diyl)bis(diphenylphosphine) (R)-(6,6'-Dimethoxy-[1,1'-biphenyl]-2,2'-diyl)bis(diphenylphosphine) 133545-16-1 C38H32O2P2 Chiral Phosphine MeOBIPHEP Series