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TERT-BUTYL METHYL MALONATE

TERT-BUTYL METHYL MALONATE structure

CAS No.: 42726-73-8

Chemical Name:: TERT-BUTYL METHYL MALONATE

Synonyms: TERT-BUTYL METHYL MA;T-BUTYL METHYL MALONATE;ert-ButylMethylMalonate;TERT-BUTYL METHYL MALOTE;Methyl tert-butyl malonate;TERT-BUTYL METHYL MALONATE;TERT-BUTYL-(METHYLMALONAT);tert.-Butyl methylemalonate;tert.-Butyl methyl malonate,95%;tert-Butyl methyl malonate

CBNumber:: CB7772557

Molecular Formula:: C8H14O4

Molecular Weight:: 174.19

MDL Number:: MFCD00042856

MOL File:: 42726-73-8.mol

MSDS File:: SDS

Last updated:2025-07-24 18:13:46

Product description	Number	Pack Size	Price
tert-Butyl methyl malonate 95%	360015	10ml	$174
tert-Butyl Methyl Malonate min. 95.0 %	B2747	5G	$82
tert-Butyl Methyl Malonate min. 95.0 %	B2747	25G	$246
tert-Butyl methyl malonate	B809128	500mg	$60
tert-Butyl methyl malonate	FB72074	25g	$70
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TERT-BUTYL METHYL MALONATE Properties

Melting point	-10 °C
Boiling point	80 °C11 mm Hg(lit.)
Density	1.03 g/mL at 25 °C(lit.)
refractive index	n20/D 1.415(lit.)
Flash point	175 °F
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
form	Liquid
pka	11.83±0.46(Predicted)
color	Clear colorless to slightly yellow
BRN	1772136
InChI	InChI=1S/C8H14O4/c1-8(2,3)12-7(10)5-6(9)11-4/h5H2,1-4H3
InChIKey	XPSYZCWYRWHVCC-UHFFFAOYSA-N
SMILES	C(OC(C)(C)C)(=O)CC(OC)=O
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H227

Precautionary statements

P210e-P280a-P370+P378a-P403+P235-P501a

Safety Statements

23-24/25

WGK Germany

HS Code

29171900

NFPA 704

	2
0		0

TERT-BUTYL METHYL MALONATE price More Price(30)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	360015	tert-Butyl methyl malonate 95%	42726-73-8	10ml	$174	2023-06-20	Buy
TCI Chemical	B2747	tert-Butyl Methyl Malonate min. 95.0 %	42726-73-8	5G	$82	2025-07-31	Buy
TCI Chemical	B2747	tert-Butyl Methyl Malonate min. 95.0 %	42726-73-8	25G	$246	2025-07-31	Buy
TRC	B809128	tert-Butyl methyl malonate	42726-73-8	500mg	$60	2021-12-16	Buy
Biosynth Carbosynth	FB72074	tert-Butyl methyl malonate	42726-73-8	25g	$70	2021-12-16	Buy

Product number	Packaging	Price	Buy
360015	10ml	$174	Buy
B2747	5G	$82	Buy
B2747	25G	$246	Buy
B809128	500mg	$60	Buy
FB72074	25g	$70	Buy

TERT-BUTYL METHYL MALONATE Chemical Properties,Uses,Production

Chemical Properties

clear colorless to slightly yellow liquid

General Description

tert-Butyl methyl malonate is an ester. Stereospecific Pd(O)-catalyzed addition of tert-butyl methyl malonate to allylic carbonates is reported.

Synthesis

67-56-1

40052-13-9

42726-73-8

To a 200 mL round bottom flask equipped with a magnetic stirrer was added mono-tert-butyl malonate (3.0 g, 18.7 mmol) and methanol (70 mL). To this solution was added hafnium(IV) chloride tetrahydrofuran complex (1:2) (88 mg, 0.19 mmol). The reaction mixture was stirred at room temperature for 48 hours. After completion of the reaction, saturated saline was added to the mixture and extracted with dichloromethane (3 x 70 mL). The organic layers were combined, dried with anhydrous magnesium sulfate and concentrated under reduced pressure. The crude product was purified by silica gel column chromatography (eluent: n-hexane/ethyl acetate = 50:50) to afford the target compound tert-butyl methyl malonate (3.0 g, 91% yield) as a colorless oily liquid.1H NMR (400 MHz, CDCl3) δ 3.74 (s, 3H), 3.30 (s, 2H), 1.47 (s, 9H); 13C NMR ( 100 MHz, CDCl3) δ 167.5, 165.8, 82.1, 52.3, 42.7, 27.9; HR-FAB MS m/z calculated value C8H15O4 [M+H]+ 175.0883, measured value 175.0875.

References

[1] Tetrahedron Asymmetry, 2015, vol. 26, # 4, p. 214 - 218

TERT-BUTYL METHYL MALONATE Preparation Products And Raw materials

Raw materials

tert-Butyl methyl ether Potassium hydroxide Dimethyl malonate Sodium sulfate tert-Butanol

Diethyl ether Hydrochloric acid Sodium bicarbonate Dichloromethane Methanol

Dicyclohexylcarbodiimide 4-Dimethylaminopyridine

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Preparation Products

Tert-Butyl Methyl 2-(5-Bromopyrimidin-2-Yl)Malonate 1-tert-Butyl 3-methyl 2-methylmalonate 2-Pyridineacetic acid, 5-nitro-, methyl ester

TERT-BUTYL METHYL MALONATE Suppliers

Global( 183)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Chuanghai Biotechnology Co., Ltd	+8615350571055	Sibel@chuanghaibio.com	China	8770	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718; +8613336195806	sales@capot.com	China	29735	60
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29850	58
Accela ChemBio Inc.	+1-858-6993322	info@accelachem.com	United States	21193	58
Changzhou Ditong Chemical Co.,Ltd	+86-0519-88299272	info@edengenechem.com	China	2176	58
Hubei xin bonus chemical co. LTD	86-13657291602	linda@hubeijusheng.com	CHINA	22963	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49975	58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd	+8613580539051	joe@yuhengpharm.com	CHINA	21142	58
SIMAGCHEM CORP	+86-5922680277 +86-13806087780	sale@simagchem.com	China	17346	58

Supplier	Advantage
Hebei Chuanghai Biotechnology Co., Ltd	58
Capot Chemical Co.,Ltd.	60
career henan chemical co	58
Accela ChemBio Inc.	58
Changzhou Ditong Chemical Co.,Ltd	58
Hubei xin bonus chemical co. LTD	58
Alchem Pharmtech,Inc.	58
CONIER CHEM AND PHARMA LIMITED	58
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd	58
SIMAGCHEM CORP	58

View Lastest Price from TERT-BUTYL METHYL MALONATE manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2025-11-14	TERT-BUTYL METHYL MALONATE 42726-73-8	US $1.00 / KG	1KG	99%	10 mt	Hebei Chuanghai Biotechnology Co., Ltd
2025-04-04	tert-Butyl methyl malonate 42726-73-8	US $0.00-0.00 / kg	1kg	98%	1Ton	Henan Aochuang Chemical Co.,Ltd.
2019-07-06	TERT-BUTYL METHYL MALONATE 42726-73-8	US $1.00 / kg	1kg	99%	Customized	Career Henan Chemical Co

TERT-BUTYL METHYL MALONATE
42726-73-8
US $1.00 / KG
99%
Hebei Chuanghai Biotechnology Co., Ltd

tert-Butyl methyl malonate
42726-73-8
US $0.00-0.00 / kg
98%
Henan Aochuang Chemical Co.,Ltd.

TERT-BUTYL METHYL MALONATE
42726-73-8
US $1.00 / kg
99%
Career Henan Chemical Co

TERT-BUTYL METHYL MALONATE Spectrum

TERT-BUTYL METHYL MALONATE(42726-73-8)¹HNMR TERT-BUTYL METHYL MALONATE(42726-73-8)FT-IR TERT-BUTYL METHYL MALONATE(42726-73-8)Raman TERT-BUTYL METHYL MALONATE(42726-73-8)IR

42726-73-8(TERT-BUTYL METHYL MALONATE)Related Search:

BENZYL TERT-BUTYL MALONATE Di-tert-Butyl malonate TERT-BUTYL ETHYL MALONATE Diisopropyl malonate Ethyl potassium malonate

3-tert-Butoxy-3-oxopropanoic acid Dimethyl malonate Potassium 3-methoxy-3-oxopropanoate Ethyl hydrogen malonate Diethyl malonate

MONOMETHYL MALONATE Malonic acid tert-Butylhydrazine hydrochloride tert-Butyldimethylsilyl chloride tert-butyl((4-bromo-5-cyano-1-methyl-1H-pyrazol-3-yl)methyl)(methyl)carbamate

tert-Butyl nitrite tert-Butylchlorodiphenylsilane Coumarin 338

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T-BUTYL METHYL MALONATE TERT-BUTYL-(METHYLMALONAT) TERT-BUTYL METHYL MALONATE Methyl tert-butyl malonate Propanedioic acid 1,1-dimethylethyl methyl ester Malonic acid 1-methyl 3-tert-butyl ester Malonic acid 1-tert-butyl 3-methyl ester Propanedioic acid 1-(1,1-dimethylethyl)3-methyl ester tert.-Butyl methyl malonate,95% Malonic acid tert-butyl methyl ester TERT-BUTYL METHYL MALOTE tert.-Butyl methylemalonate TERT-BUTYL METHYL MA tert.-Butyl Methyl Malonate, 95% 5ML 1-tert-butyl 3-methyl propanedioate ert-ButylMethylMalonate TERT-BUTYL METHYL MALONATE 42726-73-8 3-O-tert-butyl 1-O-methyl propanedioate 3-tert-Butoxy-2-methyl-3-oxopropanoicacid propanedioic acid O3-tert-butyl ester O1-methyl ester tert-Butyl methyl malonate 42726-73-8 CH3OCOCH2COOCCH33 Esters Organic Building Blocks C8 to C9 Building Blocks Carbonyl Compounds Aromatic Esters C8 to C9 Carbonyl Compounds Esters