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Methylcyclopentadienyl manganese tricarbonyl

CAS No.
12108-13-3
Chemical Name:
Methylcyclopentadienyl manganese tricarbonyl
Synonyms
carbon monoxide,manganese,5-methylcyclopenta-1,3-diene;CI-2;MCMT;Ak-33x;mmt[qr];ci-2[qr];EthylMMT;NSC22316;Hitec3000;ak-33x[qr]
CBNumber:
CB9231289
Molecular Formula:
C9H7MnO35*
Molecular Weight:
218.09
MDL Number:
MFCD00001426
MOL File:
12108-13-3.mol
MSDS File:
SDS
Last updated:2024-05-23 18:06:45

Methylcyclopentadienyl manganese tricarbonyl Properties

Melting point -1 °C (lit.)
Boiling point 232-233 °C (lit.)
Density 1.38 g/mL at 25 °C (lit.)
vapor density >1 (vs air)
vapor pressure 0.05 mm Hg ( 20 °C)
refractive index n20/D 1.584(lit.)
Flash point 205 °F
storage temp. Poison room
form liquid
color yellow
Specific Gravity 1.388
Water Solubility Insoluble in water. Soluble in hydrocarbon solvents, alcohols, ether, acetone
Sensitive Air Sensitive
Merck 14,6223
Exposure limits ACGIH: TWA 0.2 mg/m3 (Skin)
OSHA: Ceiling 5 mg/m3
NIOSH: IDLH 500 mg/m3; TWA 0.2 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3
Stability Stable. Incompatible with strong oxidizing agents.
InChIKey LYHJNAIHGFWRKM-UHFFFAOYSA-N
LogP 3.4 at 26℃
CAS DataBase Reference 12108-13-3(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 1E52JN2L3I
EPA Substance Registry System Methylcyclopentadienyl manganese tricarbonyl (12108-13-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H301-H310+H330-H315-H372-H410
Precautionary statements  P262-P273-P280-P301+P310+P330-P302+P352+P310-P304+P340+P310
Hazard Codes  T,N,T+
Risk Statements  23/24/25-40-50/53-48/23-38-26-24/25
Safety Statements  23-26-36/37/39-45-61-60-36/37-28
RIDADR  UN 3281 6.1/PG 2
WGK Germany  3
RTECS  OP1450000
TSCA  Yes
HazardClass  6.1
PackingGroup  II
Toxicity LD50 orally in mice, guinea pig, rabbit: 352; 905; 95 mg/kg; orally in male, female rats: 175 ±33; 89 ±14; LC50 inhalation in rat: 0.22 mg/l (Stara)
NFPA 704
0
4 0

Methylcyclopentadienyl manganese tricarbonyl price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 317632 (Methylcyclopentadienyl)manganese(I) tricarbonyl 12108-13-3 1g $24.3 2024-03-01 Buy
Sigma-Aldrich 317632 (Methylcyclopentadienyl)manganese(I) tricarbonyl 12108-13-3 50g $608 2024-03-01 Buy
Alfa Aesar 047125 Methylcyclopentadienylmanganese tricarbonyl, 97% 12108-13-3 1g $20.65 2024-03-01 Buy
Alfa Aesar 047125 Methylcyclopentadienylmanganese tricarbonyl, 97% 12108-13-3 5g $72.65 2024-03-01 Buy
Strem Chemicals 25-1550 Methylcyclopentadienylmanganese tricarbonyl, min. 97% 12108-13-3 5g $75 2024-03-01 Buy
Product number Packaging Price Buy
317632 1g $24.3 Buy
317632 50g $608 Buy
047125 1g $20.65 Buy
047125 5g $72.65 Buy
25-1550 5g $75 Buy

Methylcyclopentadienyl manganese tricarbonyl Chemical Properties,Uses,Production

Description

Manganese, tricarbonyl methylcyclopentadienyl is a dark orange liquid. Faintly pleasant, herb-like odor. Molecular weight= 218.10;Boiling point=232℃; Freezing/Melting point=18℃; Flash point=74℃; 96℃. Hazard Identification (based on NFPA-704 M Rating System): Health 3, Flammability 0, Reactivity 0. Practically insoluble in water.

Chemical Properties

An orange liquid with a pleasant odor. Slightly soluble in water and denser than water. May be toxic by inhalation, ingestion and/or skin absorption. Faintly pleasant, herb-like odor.

Uses

Methylcyclopentadienyl manganese tricarbonyl is used for doping of ZnSe nanocrystals
It can also be used as a reactant for:
Aldol addition reactions
Preparation of homo- and heteronuclear mixed biscarbene complexes with conjugated bithiophene units
Molecular fragmentation using shaped femtosecond laser pulses
Preparation of MnAs thin films grown on GaAs(001) by metalorganic vapour phase epitaxy (MOVPE)

Uses

Antiknock fuel additive; dopant for Mn.

Uses

Octane enhancer in gasoline; reduces smoke emissions from home, commercial, industrial, and marine burners

Definition

Methylcyclopentadienyl Manganese Tricarbonyl is a dark orange liquid with a faintly pleasant odor. It is used as a fuel additive to abate smoke and as a gasolinc additive in antiknock mixes.

Preparation

Into a reaction flask under nitrogen was placed 1.26 parts bis(methylcyclopentadienyl) manganese (91.8% pure), 0.93 parts manganous acetate, 0.78 parts tetrahydrofuran (THF) and 17.31 parts toluene. Over a period of 15 minutes, a solution of 1.24 parts triethyl aluminum (TEA) in 8.70 parts of toluene was added to the above mixture with a vigorous stirring (Al/Mn atom ratio 1/1, TEA/THF mole ratio 1/1). The solution darkened slightly. This solution of the intermediate complex was transferred under nitrogen to a stainless steel autoclave. The autoclave was sealed, pressurized twice to 300 psig with carbon monoxide and vented and finally pressurized with carbon monoxide to 600 psig and heated while stirring to 100° C. Carbon monoxide was added as needed to maintain 600 psig. After two hours at 100° C., the temperature was raised to 150° C. for 30 minutes. The autoclave was then cooled, vented and discharged. The mixture was hydrolyzed with 10% aqueous HCl. An equal volume of pentane was added to extract the MMT. The pentane phase was analyzed by gas chromoatograph (GC) using a pentadecane internal standard to show a yield of Methylcyclopentadienyl manganese tricarbonyl(MMT) based on manganese of 84% and, based on MCP, of 89%.

General Description

Methylcyclopentadienyl manganese tricarbonyl (hereinafter "MMT") is an antiknock agent for gasoline discovered in the fifties and sold commercially by Ethyl Corporation. It can be made by the reaction of carbon monoxide with bis(methylcyclopentadienyl) manganese referred to as "carbonylation". 

Air & Water Reactions

Slightly soluble in water.

Reactivity Profile

METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL decomposes when exposed to light. METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL is stable in water.

Hazard

Toxic by ingestion, inhalation, and skinabsorption. Central nervous system impairment;lung, liver and kidney damage.

Health Hazard

In concentrated form METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL is highly toxic by all routes of exposure. Approximately 5-15 ml, when spilled on the hand and wrist of a worker, produced toxic effects within 3-5 minutes.

Fire Hazard

When heated to decomposition, METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL emits toxic fumes of carbon monoxide. Hazardous polymerization may not occur.

Flammability and Explosibility

Non flammable

Safety Profile

Poison by ingestion, inhalation, skin contact, intravenous, and intraperitoneal routes. A slimn irritant. When heated to decomposition it emits toxic fumes of CO. See also MANGANESE COMPOUNDS and CARBONYLS.

Potential Exposure

MMT is used as an octane improver in unleaded gasoline, other distillate fuels, and fuel oils; as a smoke abater in fuels.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.

storage

Color Code—Blue: Health Hazard/Poison: Store in a secure poison location. Prior to working with this chemical you should be trained on its proper handling and storage. Store in tightly closed containers in a cool, well-ventilated area away from oxidizers. Where possible, automatically pump liquid from drums or other storage containers to process containers.

Shipping

UN3281 Metal carbonyls, liquid n.o.s. Hazard class 6.1. Technical name required, Potential Inhalation Hazard (Special Provision 5).

Incompatibilities

Light causes decomposition. May be air-reactive. A strong reducing agent. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, halogens.

Waste Disposal

Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number N450, must conform to USEPA regulations for storage, transportation, treatment, and disposal of waste. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Dispose of contents and container to an approved waste disposal plant. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. All federal, state, and local environmental regulations must be observed. Do not discharge into drains or sewers.

Methylcyclopentadienyl manganese tricarbonyl Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 178)Suppliers
Supplier Tel Email Country ProdList Advantage
SIMAGCHEM CORP
+86-13806087780 sale@simagchem.com China 17367 58
Tianjin Zhongxin Chemtech Co., Ltd.
+86-022-66880623 +8618622897568 sales@tjzxchem.com China 559 58
Xiamen AmoyChem Co., Ltd
+86-592-6051114 +8618959220845 sales@amoychem.com China 6387 58
Jinan Qinmu Fine Chemical Co.,Ltd.
+8618660799346 sales@qinmuchem.com China 1009 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8822 58
Hebei Guanlang Biotechnology Co,.LTD
+8619930503252 daisy@crovellbio.com China 5961 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503259 +86-19930503259 cherry@crovellbio.com China 18449 58
Hebei Yanxi Chemical Co., Ltd.
+8617531190177 peter@yan-xi.com China 6011 58
airuikechemical co., ltd.
+undefined86-15315557071 sales05@airuikechemical.com China 994 58
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12470 58

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View Lastest Price from Methylcyclopentadienyl manganese tricarbonyl manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methylcyclopentadienylmanganese Tricarbonyl Mmt pictures 2024-05-24 Methylcyclopentadienylmanganese Tricarbonyl Mmt
12108-13-3
US $30.00-17.00 / kg 1kg 62% 300tons Hebei Dangtong Import and export Co LTD
Methylcyclopentadienylmanganese tricarbonyl pictures 2024-05-24 Methylcyclopentadienylmanganese tricarbonyl
12108-13-3
US $1.00 / KG 1KG 99% 1000mt/year Jinan Finer Chemical Co., Ltd
Methylcyclopentadienyl manganese tricarbonyl  pictures 2024-05-23 Methylcyclopentadienyl manganese tricarbonyl
12108-13-3
US $6.00 / kg 1kg More than 99% 2000KG/Month Hebei Longbang Technology Co., Ltd
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