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METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL

METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL
METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL structure
CAS No.
12108-13-3
Chemical Name:
METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL
Synonyms
MCMT;CI-2;Ak-33x;mmt[qr];ci-2[qr];EthylMMT;NSC22316;Hitec3000;ak-33x[qr];Antiknock-33
CBNumber:
CB9231289
Molecular Formula:
C9H7MnO3 5*
Formula Weight:
218.09
MOL File:
12108-13-3.mol

METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL Properties

Melting point:
−1 °C(lit.)
Boiling point:
232-233 °C(lit.)
Density 
1.38 g/mL at 25 °C(lit.)
vapor density 
>1 (vs air)
vapor pressure 
0.05 mm Hg ( 20 °C)
refractive index 
n20/D 1.584(lit.)
Flash point:
205 °F
storage temp. 
Poison room
form 
liquid
color 
yellow
Specific Gravity
1.388
Water Solubility 
Insoluble in water. Soluble in hydrocarbon solvents, alcohols, ether, acetone
Sensitive 
Air Sensitive
Merck 
14,6223
Stability:
Stable. Incompatible with strong oxidizing agents.
InChIKey
LYHJNAIHGFWRKM-UHFFFAOYSA-N
CAS DataBase Reference
12108-13-3(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T,N,T+
Risk Statements  23/24/25-40-50/53-48/23-38-26-24/25
Safety Statements  23-26-36/37/39-45-61-60-36/37-28
RIDADR  UN 3281 6.1/PG 2
WGK Germany  3
RTECS  OP1450000
TSCA  Yes
HazardClass  6.1
PackingGroup  II
Toxicity LD50 orally in mice, guinea pig, rabbit: 352; 905; 95 mg/kg; orally in male, female rats: 175 ±33; 89 ±14; LC50 inhalation in rat: 0.22 mg/l (Stara)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H300 Fatal if swallowed Acute toxicity,oral Category 1, 2 Danger P264, P270, P301+P310, P321, P330,P405, P501
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H310 Fatal in contact with skin Acute toxicity,dermal Category 1, 2 Danger P262, P264, P270, P280, P302+P350,P310, P322, P361, P363, P405, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger P260, P264, P270, P314, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P320 Specific treatment is urgent (see … on this label).
P330 Rinse mouth.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P405 Store locked up.

METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 317632 (Methylcyclopentadienyl)manganese(I) tricarbonyl 12108-13-3 1g $19.9 2018-11-13 Buy
Sigma-Aldrich 317632 (Methylcyclopentadienyl)manganese(I) tricarbonyl 12108-13-3 50g $447 2018-11-13 Buy
Alfa Aesar 047125 Methylcyclopentadienylmanganese tricarbonyl, 97% 12108-13-3 1g $18.6 2018-11-16 Buy
Alfa Aesar 047125 Methylcyclopentadienylmanganese tricarbonyl, 97% 12108-13-3 5g $69.3 2018-11-16 Buy
Strem Chemicals 25-1550 Methylcyclopentadienylmanganese tricarbonyl, min. 97% 12108-13-3 25g $234 2018-11-13 Buy

METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL Chemical Properties,Uses,Production

Chemical Properties

Manganese, tricarbonyl methylcyclo-pentadienyl is a dark orange liquid. Faintly pleasant, herb-like odor.

Uses

Used for doping of ZnSe nanocrystals 1 Reactant for: Aldol addition reactions 2 Preparation of homo- and heteronuclear mixed biscarbene complexes with conjugated bithiophene units 3 Molecular fragmentation using shaped femtosecond laser pulses 4 Preparation of MnAs thin films grown on GaAs(001) by metalorganic vapour phase epitaxy (MOVPE) 5

Uses

Antiknock fuel additive; dopant for Mn.

General Description

An orange liquid with a pleasant odor. Slightly soluble in water and denser than water. May be toxic by inhalation, ingestion and/or skin absorption.

Air & Water Reactions

Slightly soluble in water.

Reactivity Profile

METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL decomposes when exposed to light. METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL is stable in water.

Hazard

Toxic by ingestion, inhalation, and skinabsorption. Central nervous system impairment;lung, liver and kidney damage.

Health Hazard

In concentrated form METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL is highly toxic by all routes of exposure. Approximately 5-15 ml, when spilled on the hand and wrist of a worker, produced toxic effects within 3-5 minutes.

Fire Hazard

When heated to decomposition, METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL emits toxic fumes of carbon monoxide. Hazardous polymerization may not occur.

Safety Profile

Poison by ingestion, inhalation, skin contact, intravenous, and intraperitoneal routes. A slimn irritant. When heated to decomposition it emits toxic fumes of CO. See also MANGANESE COMPOUNDS and CARBONYLS.

Potential Exposure

MMT is used as an octane improver in unleaded gasoline, other distillate fuels, and fuel oils; as a smoke abater in fuels.

Shipping

UN3281 Metal carbonyls, liquid n.o.s. Hazard class 6.1. Technical name required, Potential Inhalation Hazard (Special Provision 5).

Incompatibilities

Light causes decomposition. May be air-reactive. A strong reducing agent. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, halogens.

Waste Disposal

Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number N450, must conform to USEPA regulations for storage, transportation, treatment, and disposal of waste. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Dispose of contents and container to an approved waste disposal plant. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. All federal, state, and local environmental regulations must be observed. Do not discharge into drains or sewers.

METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL Preparation Products And Raw materials

Raw materials

Preparation Products


METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL Suppliers

Global( 71)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Tianjin Zhongxin Chemtech Co., Ltd.
022-89880739
022-66880086 sales@tjzxchem.com CHINA 575 58
Xiamen AmoyChem Co., Ltd
+86 (0)592-605 1114
sales@amoychem.com CHINA 6374 58
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32452 55
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 23959 58
Capot Chemical Co.,Ltd.
+86 (0)571-855 867 18
+86 (0)571-858 647 95 sales@capotchem.com China 19918 60
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 21935 58
Dalian Richfortune Chemicals Co., Ltd
86-411-84820922, 84821539
86-411-84821380 sales@richfortunechem.com China 360 57
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20676 55
Hubei Jusheng Technology Co.,Ltd.
86-188-71490254
peter@hubeijusheng.com CHINA 20084 58
Haihang Industry Co.,Ltd
86-531-88032799
+86 531 8582 1093 export@haihangchem.com CHINA 8266 58

View Lastest Price from METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2019-04-05 METHYLCYCLOPENTADIENYLMANGANESE TRICARBONYL
12108-13-3
US $1.00 / kg 1kg 99% 1000MT Chemwill Asia Co.,Ltd.

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