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Isocyanic acid 3,4-dichlorophenyl ester

Isocyanic acid 3,4-dichlorophenyl ester
Isocyanic acid 3,4-dichlorophenyl ester
CAS No.
102-36-3
Chemical Name:
Isocyanic acid 3,4-dichlorophenyl ester
Synonyms
dcpi;3,4-DCPI;Isocyanic acid 3,4-d;3,4-Dichlorfenylisokyanat;Dichloroisocyanatobenzene;DICHLOROPHENYL ISOCYANATES;Phenylisocyanate,dichloro-;3,4-Dichlorphenylisocyanat;3,4-Dichlorphenylisocyanate;3,4-DICHLOROPHENYLCARBIMIDE
CBNumber:
CB9761511
Molecular Formula:
C7H3Cl2NO
Formula Weight:
188.01
MOL File:
102-36-3.mol

Isocyanic acid 3,4-dichlorophenyl ester Properties

Melting point:
41-43 °C(lit.)
Boiling point:
118-120 °C18 mm Hg(lit.)
Density 
1.3256 (rough estimate)
vapor pressure 
0.2 mm Hg ( 20 °C)
refractive index 
1.5750 (estimate)
Flash point:
>230 °F
Water Solubility 
decomposes
Sensitive 
Moisture Sensitive
BRN 
608325
CAS DataBase Reference
102-36-3(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1,2-dichloro-4-isocyanato-(102-36-3)
EPA Substance Registry System
Benzene, 1,2-dichloro-4-isocyanato- (102-36-3)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T
Risk Statements  23-36/37/38-42
Safety Statements  22-26-36/37/39-45
RIDADR  UN 2250 6.1/PG 2
WGK Germany  2
RTECS  NQ8760000
1-8-10-19
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29291090
Hazardous Substances Data 102-36-3(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H300 Fatal if swallowed Acute toxicity,oral Category 1, 2 Danger P264, P270, P301+P310, P321, P330,P405, P501
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning P261, P271, P304+P340, P312
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Sensitisation, respiratory Category 1 Danger P261, P285, P304+P341, P342+P311,P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P342+P311 IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P405 Store locked up.

Isocyanic acid 3,4-dichlorophenyl ester price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 245607 3,4-Dichlorophenyl isocyanate 97% 102-36-3 10g $70.1 2018-11-13 Buy
TCI Chemical I0092 3,4-Dichlorophenyl Isocyanate >98.0%(GC)(T) 102-36-3 25g $60 2018-11-22 Buy
TCI Chemical I0092 3,4-Dichlorophenyl Isocyanate >98.0%(GC)(T) 102-36-3 500g $498 2018-11-22 Buy
Alfa Aesar A16298 3,4-Dichlorophenyl isocyanate, 97% 102-36-3 5g $32.6 2018-11-15 Buy
Alfa Aesar A16298 3,4-Dichlorophenyl isocyanate, 97% 102-36-3 25g $110 2018-11-15 Buy

Isocyanic acid 3,4-dichlorophenyl ester Chemical Properties,Uses,Production

Chemical Properties

White low melting solid

Chemical Properties

The dichlorophenyl isocyanates are combustible, crystalline (sugar or sand-like) solids. In general, they are white to yellow in color, but the 1,4-dichloro-2-phenyl isomer is white to light green. Their flash points are generally .113C but that of the 1,3-dichloro-2-phenyl isomer is reported as 77C. These chemicals are insoluble in water, and some may be reactive. 1,2-dichloro-4-isomer (CAS 102-36-3) is the isomer of regulatory focus

General Description

White to yellow solid. Used as a chemical intermediate and in organic synthesis.

Reactivity Profile

Isocyanates and thioisocyanates, such as Isocyanic acid 3,4-dichlorophenyl ester, are incompatible with many classes of compounds, reacting exothermically to release toxic gases. Reactions with amines, aldehydes, alcohols, alkali metals, ketones, mercaptans, strong oxidizers, hydrides, phenols, and peroxides can cause vigorous releases of heat. Acids and bases initiate polymerization reactions in these materials. Some isocyanates react with water to form amines and liberate carbon dioxide.

Health Hazard

Strong irritant to tissue, especially eyes and mucous membranes

Fire Hazard

Inhalation of dust is poisonous; fire may produce irritating or poisonous gases.

Potential Exposure

Those materials used as chemical intermediates

First aid

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposurebegin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.

Shipping

UN2250 Dichlorophenyl isocyanates, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Incompatibilities

May form explosive mixture with air. Isocyanates are highly flammable and reactive with many compounds, even with themselves. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Reaction with moist air, water or alcohols may form amines and insoluble polyureas and react exothermically, releasing toxic, corrosive or flammable gases, including carbon dioxide; and, at the same time, may generate a violent release of heat increasing theconcentration of fumes in the air. Incompatible with amines, aldehydes, alkali metals, ammonia, carboxylic acids, caprolactum, alkaline materials, glycols, ketones, mercaptans, hydrides, organotin catalysts, phenols, strong acids, strong bases, strong reducing agents such as hydrides, urethanes, and ureas. Elevated temperatures or contact with acids, bases, tertiary amines, and acylchlorides may cause explosive polymerization. Contact with metals may evolve flammable hydrogen gas. Attacks some plastics, rubber, and coatings.

Waste Disposal

Combustion in an incinerator equipped with afterburner and fume scrubber

Isocyanic acid 3,4-dichlorophenyl ester Preparation Products And Raw materials

Raw materials

Preparation Products


Isocyanic acid 3,4-dichlorophenyl ester Suppliers

Global( 161)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Mainchem Co., Ltd.
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+86-0592-6210733 sales@mainchem.com CHINA 32651 55
Zjartschem
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Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 10967 58
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 19990 58
Beijing Taiya Jie Technology Development Co., Ltd. 13552411790、010-56275498
010-84817120 E-mail:postmaster@tyjchem.cn China 1542 55
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30291 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 / 800-988-0390
021-67121385 Sales-CN@TCIchemicals.com China 24648 81
Energy Chemical 021-58432009 / 400-005-6266
021-58436166-800 info@energy-chemical.com China 44187 61
JinYan Chemicals(ShangHai) Co.,Ltd. 13817811078,021-50426030
86-021-50426522,50426273 sales@jingyan-chemical.com China 10073 60

View Lastest Price from Isocyanic acid 3,4-dichlorophenyl ester manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-18 Isocyanic acid 3,4-dichlorophenyl ester
102-36-3
US $7.00 / kg 1kg 99% 100KG career henan chemical co

Isocyanic acid 3,4-dichlorophenyl ester Spectrum


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