ノナン酸 化学特性,用途語,生産方法
外観
無色～うすい黄色, 澄明の液体
溶解性
エタノール及びアセトンに極めて溶けやすく、水にほとんど溶けない。水に難溶。エタノール、エーテルに可溶。
解説
ノナン酸，ノナンサン，ペラルゴン酸(pelargonic acid)ともいう．天然には存在しない．ペラルゴニトリルを濃塩酸で加水分解するか，オレイン酸を過マンガン酸カリウムで酸化すると得られる．無色の油状液体．融点15 ℃，沸点255 ℃，121.4 ℃(533 Pa)，98.9 ℃(133 Pa)．d412.50.9109．nD1.43057．水に難溶，エタノール，エーテルに可溶．合成潤滑油のベースオイル，合成ゴム，ビニル用可塑剤に用いられる．
用途
有機合成原料、除草剤。
用途
塗料?潤滑油原料,除草剤(失効農薬)
説明
Nonanoic acid , also called pelargonic acid, is an organic compound composed of a nine - carbon chain terminating in a carboxylic acid with structural formula CH
3(CH
2)
7COOH. Nonanoic acid forms esters—nonanoates. It is a clear, oily liquid with an unpleasant, rancid odor. It is nearly insoluble in water, but very soluble in chloroform, ether, and hexane.
Its refractive index is 1.4322. Its critical point is at 712 K ( 439 °C ) and 2.35 MPa.
化学的特性
Nonanoic acid has a fatty, characteristic odor and a corresponding unpleasant taste. May be prepared by oxidation of methylnonyl ketone; by oxidation of oleic acid; or from heptyl iodide via malonic ester synthesis.
天然物の起源
Nonanoic acid is a fatty acid which occurs naturally as esters in the oil of pelargonium. Synthetic esters, such as methyl nonanoate, are used as flavorings.
Nonanoic acid is also used in the preparation of plasticizers and lacquers.
The derivative 4-nonanoylmorpholine is an ingredient in some pepper sprays.
The ammonium salt of nonanoic acid, ammonium nonanoate, is used as an herbicide.
使用
The primary uses of this acid are in organic synthesis and in
the manufacture of lacquers, plastics, pharmaceuticals, synthetic
odors and flavorings, gasoline additives, flotation
agents, lubricants, and vinyl plasticizers. Nonanoic acid
has found some use in pharmaceutical preparations and as
a topical bactericide and fungicide. It is also used in
herbicides.
定義
ChEBI: A C9 straight-chain saturated fatty acid which occurs naturally as esters of the oil of pelargonium. Has antifungal properties, and is also used as a herbicide as well as in the preparation of plasticisers and lacquers.
一般的な説明
Nonanoic acid occurs naturally in Pelargonium L′Her. It one of the flavor constituents of cooked rice, acerola fruit, licorice and yogurt.
农业用途
Herbicide, Fungicide: Pelargonic acid occurs naturally in many plants and
animals. It is used to control the growth of weeds and as a
blossom thinner for apple and pear trees. It is also used as
a food additive; as an ingredient in solutions used to commercially
peel fruits and vegetables
製品名
CIRRASOL®-185A; ECONOSAN®;
EMERY® 202 (mixture with n-octoic acid);
EMFAC®-1202; HEXACID® C-9; PELARGON®;
SCYTHE®; WEST AGRO ACID SANITIZER®
安全性プロファイル
Poison by intravenous
route. Moderately toxic by ingestion. A
severe skin and eye irritant. When heated to
decomposition it emits acrid smoke and
irritating fumes.
職業ばく露
Pelargonic acid, a naturally occurring
fatty acid herbicide/fungicide. It is used to control the
growth of weeds and as a blossom thinner for apple and
pear trees. It is also used as a food additive; as an ingredient
in solutions used to commercially peel fruits and
vegetables; in the manufacture of lacquers, plastics and
pharmaceuticals.
純化方法
Esterify the acid with ethylene glycol and distil the ester. (This removes dibasic acids as undistillable residues.) The acid is regenerated by hydrolysing the ester in the usual way and is distilled in vacuo. [Beilstein 2 IV 1018.]
不和合性
Heated vapors may form explosive mixture
with air. May react violently with strong oxidizers,
bromine, 90% hydrogen peroxide, phosphorus trichloride,
silver powders or dust. Incompatible with strong bases and
silver compounds; mixture with some silver compounds
may form explosive salts of silver oxalate.
廃棄物の処理
Do not discharge into drains
or sewers. Dispose of waste material as hazardous waste
using a licensed disposal contractor to an approved landfill.
Contact a licensed disposal facility about surplus and
non-recyclable solutions. Burn in a chemical incinerator
equipped with an afterburner and scrubber. Extra care must
be exercised as the material in an organic solvent is highly
flammable. Consult with environmental regulatory agencies
for guidance on acceptable disposal practices. Incineration
with effluent gas scrubbing is recommended. Containers
must be disposed of properly by following package label
directions or by contacting your local or federal environmental
control agency, or by contacting your regional EPA
office.
ノナン酸 上流と下流の製品情報
原材料
準備製品