1,2,3-트라이클로로벤젠
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1,2,3-트라이클로로벤젠 속성
- 녹는점
- 51-53 °C (lit.)
- 끓는 점
- 218-219 °C (lit.)
- 밀도
- 1,69 g/cm3
- 증기 밀도
- 6.25 (vs air)
- 증기압
- 0.07 mm Hg ( 25 °C)
- 굴절률
- 1.5693 (estimate)
- 인화점
- 260 °F
- 저장 조건
- 2-8°C
- 용해도
- 0.02g/L
- 색상
- 백색 결정 또는 혈소판
- 폭발한계
- 2.5-6.6%(V)
- 수용성
- 불용성
- Merck
- 14,9630
- BRN
- 956882
- Henry's Law Constant
- 8.36, 10.3, 13.2, 20.6, and 26.5 at 2.0, 6.0, 10.0, 18.0, and 25.0 °C, respectively (EPICS-SPME, Dewulf et al., 1999)
- LogP
- 4.139 at 25℃
- CAS 데이터베이스
- 87-61-6(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
위험품 표기 | Xn,T,N | ||
---|---|---|---|
위험 카페고리 넘버 | 22-36/37/38-38-39/23/24/25-23/24/25-52/53-51/53 | ||
안전지침서 | 36/37-26-45-61-36 | ||
유엔번호(UN No.) | UN 3077 9/PG 3 | ||
WGK 독일 | 3 | ||
RTECS 번호 | DC2095000 | ||
자연 발화 온도 | 1059 °F | ||
TSCA | Yes | ||
위험 등급 | 9 | ||
포장분류 | III | ||
HS 번호 | 29036990 | ||
유해 물질 데이터 | 87-61-6(Hazardous Substances Data) | ||
독성 | LC50 2,177 to 3,084 μg/L (soil porewater concentration) for earthworm (Eisenia andrei) and 2,540 to 3,084 μg/L (soil porewater concentration) for earthworm (Lumbricus rubellus) (Van Gestel and Ma, 1993). | ||
기존화학 물질 | 99-3-1181 |
1,2,3-트라이클로로벤젠 C화학적 특성, 용도, 생산
개요
Trichlorobenzenes (TCBs) are synthetic chemicals that occur in three different isomeric forms. The three chlorinated cyclic aromatic isomers are 1,2,3-trichlorobenzene (1,2,3-TCB), 1,2,4-trichlorobenzene (1,2,4-TCB), and 1,3,5-trichlorobenzene (1,3,5-TCB). 1,2,4-TCB is one of the 188 chemicals designated as a hazardous air pollutant under the Clean Air Act.화학적 성질
1,2,3-Trichlorobenzene and 1,3,5-trichlorobenzene are colorless solids, while 1,2,4-trichlorobenzene is a colorless liquid. Although the three isomers of trichlorobenzenes have the same molecular weight and formula, they each may have different chemical and toxicological properties. One of the isomers (1,2,4-trichlorobenzene) is produced in large quantities and is used as a solvent to dissolve such special materials as oils, waxes, resins, greases, and rubber. It is also frequently used to produce dyes and textiles. The other two isomers, 1,2,3-trichlorobenzene and 1,3,5-trichlorobenzene, are produced in lower quantities and have fewer uses.용도
Detoxification by catalytic hydrotreatment of 1,2,3-Trichlorobenzene is used for the disposal of hazardous organic waste liquids. As constituent of trichlorobenzene mixt used for termite control. As transformer fluid, dye carrier & solvent. Solvent for high melting products, Coolant in electrical installations and glass tempering. In polyester dyeing, lubricants, Heat transfer medium. As chemical intermediate for 2,3-dichlorophenol.일반 설명
A white solid with a sharp chlorobenzene odor. Insoluble in water and denser than water. Hence sinks in water. Melting point 63-64°C (145-147°F).공기와 물의 반응
Insoluble in water.반응 프로필
1,2,3-Trichlorobenzene can react with oxidizing agents. . May emit toxic hydrogen chloride and phosgene gases in fire.건강위험
Inhalation may cause irritation of respiratory tract. Irritating to the eyes. May redden skin on contact. Ingestion may cause liver damage.환경귀착
Biological. Under aerobic conditions, soil microbes are capable of degrading 1,2,3- trichlorobenzene to 1,2- and 1,3-dichlorobenzene and carbon dioxide (Kobayashi and Rittman, 1982). A mixed culture of soil bacteria or a Pseudomonas sp. transformed 1,2,3-trichlorobenzene to 2,3,4-, 3,4,5-, and 2,3,6-trichlorophenol (Ballschiter and Scholz, 1980).In an enrichment culture derived from a contaminated site in Bayou d’Inde, LA, 1,2,3- trichlorobenzene underwent reductive dechlorination to 1,2- and 1,3-dichlorobenzene at relative molar yields of 1 and 99%, respectively. The maximum dechlorination rate, based on the recommended Michaelis-Menten model, was 60 nM/d (Pavlostathis and Prytula, 2000).
Photolytic. The sunlight irradiation of 1,2,3-trichlorobenzene (20 g) in a 100-mL borosilicate glass-stoppered Erlenmeyer flask for 56 d yielded 32 ppm pentachlorobiphenyl (Uyeta et al., 1976).
Chemical/Physical. At 70.0 °C and pH values of 3.07, 7.13, and 9.80, the hydrolysis half-lives were calculated to be 19.2, 15.0, and 34.4 d, respectively (Ellington et al., 1986). Emits toxic chloride fumes when heated to decomposition.
Purification Methods
Crystallise it from EtOH. [Beilstein 5 IV 664.]1,2,3-트라이클로로벤젠 준비 용품 및 원자재
원자재
준비 용품
나트륨2,3,4-트리클로로벤젠술폰산염
2,3-Dichlorophenol
3,4-디클로로-2-하이드록시벤젠풀폰산
1,3,5-트리클로로벤젠
1,2,4-트라이클로로벤젠
1-(2,3-디클로로페닐)-피페라진염산염
2,3.4-트리클로로벤젠술폰산
2,3,4-트리클로로메탄산
2,3-디클로로벤조익산
3,4,5-트리클로로-벤조이산
2,3-DICHLOROTHIOPHENOL
2,2',3,3',4,4',6-HEPTACHLOROBIPHENYL
1,2,4,5-벤젠테트라마인
1,3-Dichloro-2-fluorobenzene
1,2,3-Trifluorobenzene
아세트산,(2,3-디클로로페녹시)-,에틸에스테르
1,2,3-트라이클로로벤젠 공급 업체
글로벌( 267)공급 업체
공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
---|---|---|---|---|---|
HUAIAN DCHEN CHEM CO LTD | +86-57-80696996 +86-19816093969 |
dchenchem@gmail.com | China | 16 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 |
info@fdachem.com | China | 20293 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 |
sales@capotchem.com | China | 29798 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 |
info@dakenam.com | China | 18629 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21667 | 55 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 |
ivan@atkchemical.com | China | 32836 | 60 |
Speranza Chemical Co., Ltd. | +86-86-075521030354 +8618688942810 |
sophieliu@speranzachem.com | China | 801 | 55 |
career henan chemical co | +86-0371-86658258 +8613203830695 |
sales@coreychem.com | China | 29888 | 58 |
Hubei Jusheng Technology Co.,Ltd. | 18871490254 |
linda@hubeijusheng.com | CHINA | 28180 | 58 |
Xi'an Kono chem co., Ltd., | 029-86107037 13289246953 |
info@konochemical.com | China | 2995 | 58 |
1,2,3-트라이클로로벤젠 관련 검색:
말레인산클로로페니라민 1,2-디클로로벤젠 m-디클로로벨젠 1,3,5-트리클로로벤젠 1,2,4-트라이클로로벤젠 프로클로라즈 나트륨 2,4,5-트리클로로벤젠설폰산염 2,4,6-트라이클로로아닐린 C.I. 색소 적색 112 2,4,5-트리클로로페놀 2,4,5-트리클로로페녹시아세트산 (Z)-2-클로로-1-(2,4,5-트리클로로페닐)비닐 디메틸 인산염 트라이클로르메틸실레인과 트라이크로로페닐실레인이 함유된 다이클로로다이메틸실레인 중합체 다이클로로다이메틸실레인 중합체, 다이클로로다이페닐실레인, 트라이클로로에틸실레인, 트라이클로로페닐실레인 함유 1,2,3-트라이클로로벤젠
2,4-Dichlorobenzyl chloride
Triclabendazole
2 4 6-TRICHLORBENZENESULFONAMIDE 97