Triisobutyl phosphate C화학적 특성, 용도, 생산
개요
Advances in technological development over the last couple of
centuries have led to the use of synthetic carbon-based polymers
for everyday household and office items, where once
wood or metal were desired. The high fuel values for some of
these materials could pose danger where risk of combustion is
high; therefore, flame retardants have been introduced into and coating for electronic devices. These substances have
a broad application field and good fire safety performance.
용도
Phosphoric Acid Tris(2-?methylpropyl) Ester is found in the groundwater downgradient of a landfill (Grindsted, Denmark). It is also a flame retardant and plasticizer.
환경귀착
Routes and pathways relevant physicochemical properties
(e.g., solubility, Pow, Henry constant.)consumer and industrial items and play an important role in
safeguarding life and property. A large and diverse group of
anthropogenic compounds constitute flame retardants, which
are added to combustible materials to render them more
resistant to ignition. They are designed to minimize the risk of
a fire in the event of contact with a small heat source such as
a cigarette. A wide range of different flame retardants is
produced, because many materials and products that are to be
rendered fire safe are very different in nature and composition.
Therefore, having variety in flame retardant products is necessary
so as to retain key material functionality. For example,
plastics have a wide range of mechanical and chemical properties
and differ in combustion behavior. These materials in
particular are the main focus of phosphate ester flame
retardants.
Phosphate esters are derivatives of tri protic acid, phosphoric
acid, with a general formula of RxH3°xPO4. Flame retardants are
composed of a group of chemicals with similar properties but
slightly different structures. They are typically liquids and some
are solids at room temperature. Some examples of the phosphate
ester flame retardants include: tris(2-chloroethyl)phosphate
(TCEP), tributyl phosphate (TnBP), tris(2-butoxyethyl)
phosphate (TBEP), tris(1,3-dichloro-2-propyl) phosphate
(TDCP), triphenyl phosphate (TPP), tris(2-chloro-isopropyl)
phosphate (TCPP), and triisobutyl phosphate (TiBP). These
compounds are trisubstituted and categorized as alkyl (TnBP,
TiBP), alkyl ether (TBEP), chloroalkyl (TCEP, TCPP, TDCP),
and aryl (TPP) phosphate esters.
Purification Methods
Purify it by repeated crystallisation, from hexane, of its addition compound with uranyl nitrate. (see tributyl phosphate.) [Siddall J Am Chem Soc 81 4176 1959; see Cherbuliez in Organo Phosphorus Compounds (Kosolapoff & Maier eds) Wiley Vol 6 pp 211-577 1973.]
Triisobutyl phosphate 준비 용품 및 원자재
원자재
준비 용품
