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BISMUTH TELLURIDE

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BISMUTH TELLURIDE Basic information
Product Name:BISMUTH TELLURIDE
Synonyms:bismuthsesquitelluride;BISMUTH TELLURIDE, 99.99%;Bismuth telluride, se-doped;Bismuth(3 ) telluride;Einecs 215-135-2;BisMuth(III) telluride powder, -325 Mesh, 99.99% trace Metals basis;Bismuth(III) telluride beads, 99.995% trace metals basis;Bismuth(III) telluride (Bi2Te3)
CAS:1304-82-1
MF:Bi2Te3
MW:800.76
EINECS:215-135-2
Product Categories:Ceramic Science;Chalcogenides;Materials Science;Metal &;Metal and Ceramic Science;New Products for Materials Research and Engineering
Mol File:1304-82-1.mol
BISMUTH TELLURIDE Structure
BISMUTH TELLURIDE Chemical Properties
Melting point 585 °C(lit.)
Boiling point 1172 °C
density 7.642 g/mL at 25 °C(lit.)
solubility insoluble in H2O; soluble in ethanol
form Powder
color Gray
Water Solubility Insoluble in water.
Sensitive Moisture Sensitive
Crystal StructureCubic, Halite Structure - Space Group Fm3m
Exposure limitsACGIH: TWA 10 mg/m3; TWA 5 mg/m3; TWA 0.1 mg/m3
OSHA: TWA 15 mg/m3; TWA 5 mg/m3
NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; TWA 10 mg/m3; TWA 0.1 mg/m3
InChI1S/2Bi.3Te
InChIKeyGUYIRKJSQUOSJV-UHFFFAOYSA-N
SMILES[Te]=[Bi][Te][Bi]=[Te]
Hardness, Mohs1.8
Knoop Microhardness155, N/mm2
CAS DataBase Reference1304-82-1(CAS DataBase Reference)
EPA Substance Registry SystemDibismuth tritelluride (1304-82-1)
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 26-36
RIDADR UN 3284 6.1/PG 3
OEBB
OELTWA: 10 mg/m3 (total)
WGK Germany 3
RTECS EB3110000
TSCA TSCA listed
HazardClass 6.1
Storage Class6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
Hazard ClassificationsAcute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazardous Substances Data1304-82-1(Hazardous Substances Data)
MSDS Information
ProviderLanguage
SigmaAldrich English
ALFA English
BISMUTH TELLURIDE Usage And Synthesis
DescriptionBismuth telluride is a gray crystalline solid.Molecular weight=800.83; Specific gravity (H2O:1)=7.7;Freezing/Melting point=573℃; Vapor pressure=0 mmHgat 20℃. Hazard Identification (based on NFPA-704 MRating System): Health 2, Flammability 2, Reactivity 2.Note: Commercial mix of doped bismuth tritelluride maycontain 80% Bi2Te3, 20% stannous telluride, plus some tellurium. Insoluble in water. Doped and undoped have similarphysical properties.
Chemical PropertiesBismuth telluride is a gray or black crystalline solid or gray powder.
UsesBi2Te3, along with Sb2Te3 and other structurally analogous semiconductors, is widely regarded as one of the best materials for room-temperature thermoelectric devices. Bismuth(III) telluride is a key component of thermoelectric materials that have reached ZT values as high as 2.4 at room temperature.
UsesSemiconductors; thermoelectric cooling; power generation application; for commercial use, Bi2Te3 is “doped” with selenium sulfide to alter its conductivity.
UsesIn electronics as semiconductor.
General DescriptionGray or black hexagonal platelets with a metallic luster or gray powder. Mp: 586°C. Density: 7.8 g cm-3. An alloy of two metallic elements.
Reactivity ProfileBISMUTH TELLURIDE may emit toxic fumes of tellurium when heated to decomposition. Incompatible with strong oxidizing agents such as nitric acid or bromine, chlorine or fluorine. Moderate fire hazard by reaction with such materials. May react with strong acids to evolve toxic gases; may react slowly with water to evolve toxic gases. Slight explosion hazard with moisture.
HazardToxic.
Health HazardBismuth telluride, either alone or doped with selenium sulfide, is apparently of very low toxicity.
In limited industrial experimental work with bismuth telluride under controlled conditions (vacuum hoods), no adverse health effects were encountered other than tellurium breath.
Potential ExposureBismuth telluride is used in thermoelectric cooling, power generation, semiconductor manufacture; pharmaceuticals; medical therapy; cosmetics. Exposure involves those working in “Silicon Valley” and similar locations around the world. An alloy of two metallic elements that are sometimes doped with SeS. The SeS dopant alters the electrical properties, but has too low a concentration to affect the chemical properties.
First aidIf this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seekmedical attention immediately. If this chemical contactsthe skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately.If this chemical has been inhaled, remove fromexposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing hasstopped and CPR if heart action has stopped. Transferpromptly to a medical facility. When this chemical hasbeen swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make anunconscious person vomit.
Note to physician: For severe poisoning BAL [BritishAnti-Lewisite, dimercaprol, dithiopropanol (C3H8OS2)] hasbeen used to treat toxic symptoms of certain heavy metalspoisoning. In the case of bismuth poisoning it may haveSOME value. Although BAL is reported to have a largemargin of safety, caution must be exercised, because toxiceffects may be caused by excessive dosage. Most can beprevented by premedication with 1-ephedrine sulfate(CAS: 134-72-5).
storageColor Code—Blue: Health Hazard/Poison: Storein a secure poison location. Bismuth telluride must bestored to avoid contact with strong oxidizers (such as chlorine, bromine, and fluoride), since violent reactions occur.Store in tightly closed containers in a cool, well-ventilatedarea away from moisture.
ShippingUN3284 Tellurium compound, n.o.s., Hazard Class: 6.1; Labels: 6.1—Poisonous materials, Technical Name Required.
IncompatibilitiesReacts with acids forming toxic gases. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Toxic and flammable gas may slowly evolve from contact with moisture.
BISMUTH TELLURIDE Preparation Products And Raw materials
Tag:BISMUTH TELLURIDE(1304-82-1) Related Product Information
Bismuth (III) Bromide Silicon nitride Bismuth(III) trifluoromethanesulfonate BISMUTH 2-ETHYLHEXANOATE BISMUTH TITANATE Triphenylbismuth Bismuth nitrate pentahydrate Bismuth trioxide BISMUTH SULFIDE BISMUTH NEODECANOATE Bismuth trichloride BISMUTH(III) FLUORIDE BISMUTH ACETATE BISMUTH(III) IODIDE BISMUTH TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE) Bismuth Tellurium BISMUTH TELLURIDE

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