ChemicalBook CAS DataBase List 1-(4-Methoxyphenyl)-1-penten-3-one

1-(4-Methoxyphenyl)-1-penten-3-one synthesis

5synthesis methods

Product Name:1-(4-Methoxyphenyl)-1-penten-3-one
CAS Number:104-27-8
Molecular formula:C12H14O2
Molecular Weight:190.24

By saturation at room temperature of a mixture of anisaldehyde and methyl ethyl ketone with HCl, or by treating α-methyl- α-(4-hydroxy)benzylidene acetone with methyl iodide in alkaline solution.

1629-58-9 Synthesis

1629-58-9
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$44.79/5g

623-12-1 Synthesis

623-12-1
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$10.00/25g

104-27-8
77 suppliers
$52.00/100mg

Yield:-

Reaction Conditions:

with C₃₄H₂₇Cl₂NO₃P₂Pd;potassium carbonate in water;N,N-dimethyl-formamide for 6 h;Reflux;Heck Reaction;

Steps:

Mizoroki-Heck coupling reaction
General procedure: The reaction of styrene with chlorobenzene in DMF/H2O (1:1) at 110 °C in the presence of K3PO4(1 mmol) and 0.05 mmol of complexes C1 and C2 as catalyst was chosen as a model reaction, which led to related product in 61% and 18% yields for complexes C1 and C2 respectively.

References:

Yousefi, Abed;Sabounchei, Seyyed Javad;Moazzami Farida, Seyed Hamed;Karamian, Roya;Rahmani, Nosrat;Gable, Robert W. [Journal of Organometallic Chemistry,2019,vol. 890,p. 21 - 31]