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(S)-(+)-alpha-Methoxyphenylacetic acid

CAS No.
26164-26-1
Chemical Name:
(S)-(+)-alpha-Methoxyphenylacetic acid
Synonyms
O-METHYL-L-MANDELIC ACID;O-Methyl-(S)-mandelicacid;L-α-Methoxyphenylacetic Acid;(+)-Methoxyphenylacetic acid;(S)-(+)-O-MethylMandelic Acid;(S)-α-Methoxybenzeneacetic acid;(S)-(+)-METHOXYPHENYLACETIC ACID;(αS)-α-Methoxybenzeneacetic acid;Acetic acid, Methoxyphenyl-, (S)-;(s)-(+)-à-methoxyphenylacetic acid
CBNumber:
CB1742293
Molecular Formula:
C9H10O3
Molecular Weight:
166.17
MDL Number:
MFCD00064216
MOL File:
26164-26-1.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

(S)-(+)-alpha-Methoxyphenylacetic acid Properties

Melting point 64-66 °C(lit.)
Boiling point 164-166°C 18mm
alpha 160 º (C=1, MEOH)
Density 1.1708 (rough estimate)
refractive index 147 ° (C=0.5, EtOH)
Flash point 164-166°C/18mm
storage temp. Sealed in dry,Room Temperature
solubility Chloroform (Slightly), Ethanol (Slightly)
pka 3.10±0.10(Predicted)
form Fine Crystalline Powder or Crystals
color White
optical activity [α]17/D +150°, c = 1 in ethanol
Water Solubility Soluble
BRN 2361718
CAS DataBase Reference 26164-26-1(CAS DataBase Reference)
FDA UNII VL35DS7HGX
NIST Chemistry Reference Benzeneacetic acid, «alpha»-methoxy-, (s)-(26164-26-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
HS Code  29189900
NFPA 704
0
0 0

(S)-(+)-alpha-Methoxyphenylacetic acid price More Price(26)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 248983 (S)-(+)-α-Methoxyphenylacetic acid 99% 26164-26-1 1g $296 2024-03-01 Buy
TCI Chemical M0829 (S)-(+)-α-Methoxyphenylacetic Acid >98.0%(GC)(T) 26164-26-1 1g $102 2024-03-01 Buy
TCI Chemical M0829 (S)-(+)-α-Methoxyphenylacetic Acid >98.0%(GC)(T) 26164-26-1 5g $309 2024-03-01 Buy
Alfa Aesar L08748 (S)-(+)-alpha-Methoxyphenylacetic acid, 99% 26164-26-1 250mg $42.65 2024-03-01 Buy
Alfa Aesar L08748 (S)-(+)-alpha-Methoxyphenylacetic acid, 99% 26164-26-1 1g $104.65 2024-03-01 Buy
Product number Packaging Price Buy
248983 1g $296 Buy
M0829 1g $102 Buy
M0829 5g $309 Buy
L08748 250mg $42.65 Buy
L08748 1g $104.65 Buy

(S)-(+)-alpha-Methoxyphenylacetic acid Chemical Properties,Uses,Production

Chemical Properties

White Solid

Uses

Reactant involved in the synthesis of biologically active molecules including:

  • Acyclonucleoside phosphonates structural analogs of adefovir
  • Labeled discodermolide for studying binding to tubulin
  • 10-Isocyano-4-cadinene used for antifouling activity

Reactant involved in studies of immunostimulating chromanones gonytolides A-C

Reactant involved in:
  • Hydroxylations and epoxidations
  • Hydrogenations

Uses

(S)-(+)-α-Methoxyphenylacetic Acid (cas# 26164-26-1) is a compound useful in organic synthesis.

Purification Methods

Purify the acids by recrystallising from *C6H6/pet ether (b 80-100o). [Neilson & Peters J Chem Soc 1519 1962, Weizmann et al. J Am Chem Soc 70 1153 1948, Pirie & Smith J Chem Soc 338 1932, NMR: Dale & Mosher J Am Chem Soc 9 5 512 1973, for resolution: Roy & Deslongchamps Can J Chem 63 651 1985, Trost et al. J Am Chem Soc 1 0 8 4974 1986.] The racemic mixture has m 72o, b 121-122o/0.4mm, 165o/18mm (from pet ether) [Braun et al. Chem Ber 6 3 2847 1930]. [Beilstein 10 IV 566.]

(S)-(+)-alpha-Methoxyphenylacetic acid Preparation Products And Raw materials

Global( 178)Suppliers
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View Lastest Price from (S)-(+)-alpha-Methoxyphenylacetic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(S)-(+)-alpha-Methoxyphenylacetic acid pictures 2022-09-28 (S)-(+)-alpha-Methoxyphenylacetic acid
26164-26-1
US $0.00-0.00 / kg 1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
(S)-(+)-alpha-Methoxyphenylacetic acid pictures 2020-02-01 (S)-(+)-alpha-Methoxyphenylacetic acid
26164-26-1
US $1.00 / KG 1KG 99% 200kgs Career Henan Chemical Co
(S)-(+)-METHOXYPHENYLACETIC ACID (S)-(+)-A-METHOXYPHENYLACETIC ACID (S)-(+)-ALPHA-METHOXYPHENYLACETIC ACID (S)-ALPHA-METHOXYPHENYLACETIC ACID (S)-(+)-A-METHOXYPHENYLACETIC ACID FLU& O-Methyl-(S)-mandelicacid (s)-(+)-à-methoxyphenylacetic acid (S)-(+)-ALPHA-METHOXYPHENYLACETIC ACID 99% (2S)-2-Methoxy-2-phenylacetic acid (S)-α-Methoxybenzeneacetic acid (αS)-α-Methoxybenzeneacetic acid [S,(+)]-α-Methoxybenzeneacetic acid (S)-(+)-ɑ-Methoxyphenylacetic acid, 99% O-METHYL-L-MANDELIC ACID (S)-(+)-alpha-Methoxyphenylacetic acid,99% Acetic acid, Methoxyphenyl-, (S)- (S)-(+)-alpha-Methoxyphenylacetic acid, 99% 1GR (S)-(+)-O-MethylMandelic Acid (S)-2-Methoxy-2-(phenyl)ethanoic Acid L-α-Methoxyphenylacetic Acid (S)-(+)-α-Methoxyphenylacetic acid, for chiral derivatization (S)-(+)-α-Methoxyphenylacetic acid, 99%, for chiral derivatization (S)-(+)-α-MethoxyphenylaceticAcid> Benzeneacetic acid, α-methoxy-, (αS)- (S)-(-)-α-methoxyphenylacetic acid (+)-Methoxyphenylacetic acid 26164-26-1 C6H5CHOCH3CO2H CARBOXYLIC ACID Chiral Derivatization Chiral Resolution Reagents Asymmetric Synthesis Analytical Chromatography Product Catalog Chiral Building Blocks Carboxylic Acids (Chiral) e.e. / Absolute Conefiguration Determination (NMR) Enantiomer Excess & Absolute Conefiguration Determination Chiral Resolving Reagents Derivatization Reagents Analytical Chemistry Carboxylic Acids (Chiral) Chiral Building Blocks e.e. / Absolute Configuration Determination (NMR) Enantiomer Excess & Absolute Configuration Determination Synthetic Organic Chemistry Chiral Reagents