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D-Tartaric acid

Chemical properties Application Preparation

CAS No. 147-71-7
Chemical Name: D-Tartaric acid
Synonyms: D-TA;d-tartaric;Tartarieacid;TARTARIC ACID;Metataric Acid;D(+)-MALICACID;D-THREARIC ACID;D-tartatic acid;D-Tartaric acid;LD-TARTARIC ACID
CBNumber: CB3693922
Molecular Formula: C4H6O6
Formula Weight: 150.09
MOL File: 147-71-7.mol
D-Tartaric acid Property
Melting point : 172-174 °C(lit.)
alpha : -12.1 º (c=20, H2O)
density : 1,8 g/cm3
refractive index : -12.5 ° (C=5, H2O)
Fp : 210 °C
storage temp. : Store below +30°C.
solubility : water: soluble100mg/mL, clear, colorless
form : Crystals or Crystalline Powder
color : White
Water Solubility : 1394 g/L (20 ºC)
Sensitive : Light Sensitive
Merck : 14,9068
BRN : 1725145
Stability:: Stable. Incompatible with oxidizing agents, bases, reducing agents. Combustible.
CAS DataBase Reference: 147-71-7(CAS DataBase Reference)
NIST Chemistry Reference: D-Tartaric acid(147-71-7)
EPA Substance Registry System: Butanedioic acid, 2,3-dihydroxy-, (2S,3S)-(147-71-7)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes : Xi
Risk Statements : 36/37/38
Safety Statements : 26-36/37-37/39-36
WGK Germany : 3
RTECS : WW7875000
Hazard Note : Light Sensitive
TSCA : Yes
HS Code : 29181200
Symbol(GHS):
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

D-Tartaric acid Chemical Properties,Usage,Production

Chemical properties
There are three stereoisomers of tartaric acid: dextrose tartaric acid, levophyllic acid and meso tartaric acid. The optical rotation of the mixture of the same amount of dextrorotatory and levorotism is mutually offset, known as racemic tartaric acid. The mesomer does not exist in nature and can be synthesized chemically. Various tartaric acids are colorless crystals that are easily soluble in water.
Application
D-(-)-tartaric acid is widely used as an acidizing agent for beverages and other foods, and this use is similar to citric acid. Tartaric acid can be used as an acid dye mordant when it is combined with tannin. It is also used for some development and fixing operations in the photographic industry. Its iron salts are photosensitive and therefore they can be used to make blueprints. Tartaric acid could complex with a variety of metal ions, and it could be used for cleaning agent and polishing agent of metal surface. Potassium tartrate (Rochelle salt) can be used to prepare Fehling reagent, and it is also used as as laxatives and diuretics in medicine. In addition, it is also used as an intermediate of quinophan. The crystal has piezoelectric properties, so it could be used for the electronics industry.
It is used as a chromatographic reagent and masking agent.
It is used as resolving agent of medicine and as biochemical reagent. This product is widely used in food industry, such as beer foaming agent, food sour agent, flavoring agent. And it is also used for refreshing drinks, candy, fruit juice, sauce, cold dishes and baking powder. This product is in line with the Japanese food additives certificate.
It is used as chiral source and resolving agent for chiral synthesis.
Preparation
D-(-)-tartaric acid is mainly present in the form of potassium salt in the fruit of a variety of plants, and a small amount of it exists in free form. We produce dextrose tartaric acid through glucose fermentation industrially. The racemate can be prepared by fumaric acid with potassium permanganate as oxidant. The mesomer can be prepared by maleic acid with potassium permanganate as oxidant. L-lactic acid can be obtained by resolution of racemates. In the practical application of tartaric acid, the main application is dextrose tartaric acid or its complex salt. The by-product tartra of brewing grape is the main raw material of actual production of tartaric acid, and the all tartaric acids are dextrose tartaric acids.
Chemical Properties
white crystals
Uses
D-(-)-Tartaric Acid the synthetic enantiomer of L-(+)-Tartaric Acid (T007630), used in the preparation of synthetic analgesics.
D-Tartaric acid Preparation Products And Raw materials
Raw materials
Maleic acid Calcium chloride Fumaric acid D(-)-Tartaric acid Hydrochloric acid Sodium hydroxide L(+)-Tartaric acid Calcium chloride hexahydrate
Preparation Products
(1R,2R)-(-)-1,2-Diaminocyclohexane (-)-Taddol (R)-1-Boc-3-(hyroxymethyl)piperidine (-)-(1S,4R)-4-AMINOCYCLOPENT-2-ENECARBOXYLIC ACID (R)-(-)-3-Quinuclidinol (-)-DIOP trans-2,5-Dimethylpiperazine (1R,2R)-(+)-1,2-Diphenylethylenediamine (R,R)-(+)-BIS(ALPHA-METHYLBENZYL)AMINE HYDROCHLORIDE (S)-(+)-3-Quinuclidinol 1H-Azepine-4-carboxylicacid,hexahydro-,methylester,(4S)-(9CI) (S)-3-Aminoquinuclidine dihydrochloride (R)-(+)-BORNYLAMINE (3S,4S)-(-)-1-BENZYL-3,4-BIS(DIPHENYLPHOSPHINO)PYRROLIDINE (S)-1-Boc-3-(hyroxymethyl)piperidine
D-Tartaric acid Suppliers      Global( 335)Suppliers     
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(S,S)-TARTARIC ACID TARTARIC ACID TARTARIC ACID, D-(-)- TARTARIC ACID [DEXTRO (+)] TARTARIC ACID UNNATURAL TARTARIC(D-) ACID UNNATURAL TARTARIC ACID Chiral Resolution Reagents Chiral Resolving Reagents D-TA D-THREARIC ACID D(-)-DIHYDROXYSUCCINIC ACID D(-)-2,3-DIHYDROXYBUTANEDIONIC ACID D-2,3-DIHYDROXYBUTANEDIOIC ACID (2S,3S)-D-(-)-TARTARIC ACID (2S,3S)-(-)-TARTARIC ACID (2S,3S)-2,3-DIHYDROXYSUCCINIC ACID Asymmetric Synthesis 147-71-7 2,3-dihydroxy-,[S-(R*,R*)]-Butanedioicacid 2,3-dihydroxy-,[s-(theta,theta)]-butanedioicaci Butanedioic acid, 2,3-dihydroxy-, [S-(R*,R*)]- Butanedioicacid,2,3-dihydroxy-[R-(R*,R*)]- d(-)-tartaricacid(unnaturaltartaricacid) d-tartaric tartaricacidd-minus Tartarieacid for Resolution of Bases Carboxylic Acids (Chiral) Chiral Building Blocks Optical Resolution D-(−)-Tartaric acid D-tartatic acid D-TARTARIC ACID, 99% (99% EE/GLC) D-TARTARIC ACID, 99% (97% EE/GLC) D-(-)TartaricAcid-((S,S)-TartaricAcid,D-ThrearicAcid) D-(-)-Tartaric acid, 99.5% Butanedioic acid, 2,3-dihydroxy-, (2S,3S)- TARTARIC ACID, D-(-)-(RG) D-(-)-WEINSURE(UNNATRLICH) Metataric Acid FINE Chemical & INTERMEDIATES Chiral Compounds LD-TARTARIC ACID D-Tartaric acid (-)-D-Tartaric acid (synthetic) D(+)-MALICACID Carboxylic Acids (Chiral) Chiral Building Blocks for Resolution of Bases Optical Resolution Synthetic Organic Chemistry Chiral chemicals D(-)TARTARIC ACID extrapure (2S,3S)-(-)-Tartaric acid, D-Threaric acid (2S,3S)-2,3-Dihydroxybutanedioic acid 2,3-Dihydroxybutanedioic acid, [S-(R*,R*)]- D(-)-Tartaric acid,99%
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