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tert-Butyl hydroperoxide

CAS No.75-91-2
Chemical Name:tert-Butyl hydroperoxide
Synonyms:TBHP;Tbhp-70;T-Hydro;cadoxtbh;Trigonox;USP -800;Cadox TBH;perbutylh;tertiary-;Perbutyl H
CBNumber:CB3854248
Molecular Formula:C4H10O2
Formula Weight:90.12
MOL File:75-91-2.mol
tert-Butyl hydroperoxide Property
Melting point : -2.8 °C
Boiling point : 37 °C (15 mmHg)
density : 0.937 g/mL at 20 °C
refractive index : n20/D 1.403
Fp : 85 °F
storage temp. : 2-8°C
Water Solubility : Miscible
Merck : 14,1570
BRN : 1098280
Stability:: Stable, but may explode if heated under confinement. Decomposition may be accelerated by traces of metals, molecular sieve or other contaminants. Incompatible with reducing agents, combustible material, acids.
CAS DataBase Reference: 75-91-2(CAS DataBase Reference)
NIST Chemistry Reference: Tert-butyl hydroperoxide(75-91-2)
EPA Substance Registry System: Hydroperoxide, 1,1-dimethylethyl(75-91-2)
Safety
Hazard Codes : O,C,N,T
Risk Statements : 7-10-20/21/22-34-65-52/53-43-67-53-68-51/53-23-21/22
Safety Statements : 14-3/7-61-45-36/37/39-24-17-16-14A-26-62-47-43
RIDADR : UN 3109 5.2
WGK Germany : 3
RTECS : EQ4900000
F : 3-21
TSCA : Yes
HazardClass : 5.2
PackingGroup : II
Hazardous Substances Data: 75-91-2(Hazardous Substances Data)

tert-Butyl hydroperoxide Chemical Properties,Usage,Production

Chemical Properties
colourless liquid (as an aqueous solution) with a sweet smell
Definition
ChEBI: An alkyl hydroperoxide in which the alkyl group is tert-butyl. It is widely used in a variety of oxidation processes.
General Description
Watery odorless colorless liquid. Floats and mixes slowly with water.
Air & Water Reactions
Water soluble.
Reactivity Profile
Most alkyl monohydroperoxides are liquid. The explosivity of the lower members (e.g., methyl hydroperoxide, or possibly, traces of the dialkyl peroxides) decreasing with increasing chain length and branching [Bretherick 2nd ed. 1979 p. 10]. Though relatively stable, explosions have been caused by distillation to dryness [Milas, JACS 1946, 68, 205] or attempted distillation at atmospheric pressure [Castrantas 1965 p. 15].
tert-Butyl hydroperoxide Preparation Products And Raw materials
Raw materials
Hydrogen peroxide 4-NITRO-2-SULFOANILINE tert-Butanol
Preparation Products
2,4-DICHLORO-5-NITROPYRIDINE 1-FLUORO-4-(TRIFLUOROMETHYLTHIO)BENZENE 2-Quinolinecarboxaldehyde 5-NITRO-2-HYDROXY-4-METHOXYPYRIDINE Cinmethylin 4-(METHYLSULFINYL)PHENOL (+)-DISPARLURE tert-Butyl peroxypivalate 2-QUINOXALINECARBALDEHYDE tert-Butyl peroxyacetate tetrahydro-2-furyl acetate Di-tert-butyl peroxide Propylene oxide
tert-Butyl hydroperoxide Suppliers      Global( 161)Suppliers     
SupplierTelFaxEmailCountryProdListAdvantage
Shanghai Macklin Biochemical Co.,Ltd. 15221275939021-51821727shenlinxing@macklin.cnChina 13254 55
Sigma-Aldrich 021-61415566 800-819-3336(Tel) 400-620-3333(Mobile)021-61415567orderCN@sial.comChina 20171 80
Energy Chemical 021-58432009 / 400-005-6266021-58436166-800info@energy-chemical.comChina 44198 61
Tianjin Zhongxin Chemtech Co., Ltd. 86(0)22-8988073986(0)22-89880739 ext 8030 / 86-22-66880086sales@tjzxchem.comChina 553 60
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833+86-10-82849933jkinfo@jkchemical.com;market6@jkchemical.comChina 96832 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-59487313(Beijing)+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing)sh@meryer.comChina 40403 62
Alfa Aesar 400-610-6006; 021-67582000021-67582001/03/05saleschina@alfa-asia.comChina 30315 84
TCI (Shanghai) Development Co., Ltd. 800-988-0390021-67121385sales@tcishanghai.com.cnChina 22833 81
BeiJing Hwrk Chemicals Limted 4006990298;010-57411839;0757-86311057;021-51691807010-87653215;0757-86311057;021-55236763sales@hwrkchemical.comChina 16340 55
Beijing Ouhe Technology Co., Ltd +86-10-4006331231;+86-10-51280831;+86-10-82967028+86-10-82967029sales@ouhechem.comChina 10813 60
 
75-91-2(tert-Butyl hydroperoxide)Related Search:
tert-Butyl peroxybenzoate tert-Butyl methyl ether ALUMINUM TERT-BUTOXIDE 4-tert-Butylcatechol TERT-BUTYLLITHIUM tert-Butyldimethylsilyl chloride Ethambutol Hydrogen peroxide EXXON BUTYL RUBBER 065 Butyl acrylate Buprofezin tert-Butylperoxide 1-Butanol 2-Methyl-1-propanol tert-Butanol 2-Butoxyethanol Di-tert-butyl peroxide tert-Butyl hydroperoxide
75-91-2 75-9l-2 Butylhydroperoxid 1,1-Dimethylethyl hydroperoxide 1,1-dimethylethyl-hydroperoxid 1,1-dimethylethylhydroperoxide 1,1-dimethylethyl-Hydroperoxide 2-Hydroperoxy-2-methylpropane 2-Methyl-prop-2-yl-hydroperoxide Aztec t-butyl Hydroperoxide-70, Aq Butyl hydroperoxide butylhydroperoxide Cadox TBH cadoxtbh Dimethylethyl hydroperoxide Ethyldiethylperoxide Hydroperoxide, 1,1-dimethylethyl Hydroperoxide, tert-butyl hydroperoxide,1,1-dimethylethyl Hydroperoxide,1,1-dimethylethyl- hydroperoxide,tert-butyl Hydroperoxyde de butyle tertiaire hydroperoxydedebutyletertiaire hydroperoxydedebutyletertiaire(french) Perbutyl H perbutylh Slimicide DE-488 Tbhp-70 Terc. butylhydroperoxid terc.butylhydroperoxid tercbutylhydroperoxid(czech) tert-Butyl hydrogen peroxide tert-Butylhydrogenperoxide tert-butylhydroperoxide(70%aqueous tert-butylhydroperoxide(70%aqueoussolution) tert-butylhydroperoxide,notmorethan80%indi-tert-butylperoxideand/orsolvent tert-C4H9OOH T-Hydro Trigonox Trigonox a-75 Trigonox A-80 Trigonox A-W70 trigonoxa-75 trigonoxa-75(czech) trigonoxa-w70 USP -800 Peroxides Oxidation Synthetic Reagents T-HYDRO(R) TERT-BUTYL HYDROPEROXIDE tert-Butyl hydroperoxide(content≤80%,with di-tert-butyl hydroperoxide and/or type A thinner)tert-Butyl hydrogen peroxide TBHP T-BUTYL HYDROPEROXIDE tert-Butanol peroxide tert-Butyl hydroperoxide, 70% solution in water TERT-BUTYL HYDROPEROXIDE SOL,~80% IN DI- TERT-BUTYLPEROXIDE TERT-BUTYL HYDROPEROXIDE SOLUTION, ~70% IN WATER
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