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Methyl formate

CAS No.107-31-3
Chemical Name:Methyl formate
Synonyms:Metil;HCOOCH3;acid-Me;Methylformiat;Methylformiaat;METHYL FORMATE;methylformiaate;formiatedemethyle;metil(formiatodi);METHYL METHANOATE
CBNumber:CB9106448
Molecular Formula:C2H4O2
Formula Weight:60.05
MOL File:107-31-3.mol
Methyl formate Property
Melting point : -100 °C
Boiling point : 32-34 °C(lit.)
density : 0.974 g/mL at 20 °C(lit.)
vapor density : 2.1 (vs air)
vapor pressure : 32.91 psi ( 55 °C)
refractive index : n20/D 1.343(lit.)
Fp : −16 °F
storage temp. : Flammables area
Water Solubility : 300 G/L (20 ºC)
Merck : 14,6077
BRN : 1734623
Stability:: Stable. Extremely flammable. Readily forms explosive mixtures with air. Note low flash point and very wide explosion limits. Incompatible with oxidizing agents.
CAS DataBase Reference: 107-31-3(CAS DataBase Reference)
NIST Chemistry Reference: Methyl formate(107-31-3)
EPA Substance Registry System: Formic acid, methyl ester(107-31-3)
Safety
Hazard Codes : F+,Xn
Risk Statements : 12-20/22-36/37
Safety Statements : 9-16-24-26-33
RIDADR : UN 1243 3/PG 1
WGK Germany : 1
RTECS : LQ8925000
HazardClass : 3
PackingGroup : I
Hazardous Substances Data: 107-31-3(Hazardous Substances Data)

Methyl formate Chemical Properties,Usage,Production

Chemical Properties
colourless liquid
General Description
A clear colorless liquid with an agreeable odor. Flash point -27°F. Less dense than water Vapors heavier than air.
Air & Water Reactions
Highly flammable. Water soluble. Reacts slowly with water to give formic acid, a corrosive material, and methanol, a flammable liquid. Both products are dissolved in the water.
Reactivity Profile
Methyl formate reacts with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated with caustic solutions. Flammable hydrogen is generated by mixing with alkali metals and hydrides.
Health Hazard
Inhalation causes irritation of mucous membranes. Prolonged inhalation can produce narcosis and central nervous symptoms, including some temporary visual disturbance. Contact with liquid irritates eyes and may irritate skin if allowed to remain. Ingestion causes irritation of mouth and stomach and central nervous system depression, including visual disturbances.
Fire Hazard
Behavior in Fire: Vapor is heavier than air and may travel considerable distance to a source of ignition and flash back.
Methyl formate Preparation Products And Raw materials
Raw materials
Iridium
Preparation Products
Methyl 2-amino-3,5-dibromobenzoate 2-Fluoropyridine-5-carboxaldehyde Ethametsulfuron-methyl Imidazole-2-carboxaldehyde 1,2,4-Triazole Bensulfuron methyl Olaquindox DPX-T5648 N,N-Dimethylformamide pyrante 2,3-Quinoline dicarboxylic acid 2-[2-[4-[(4-ethoxyphenyl)methylamino]phenyl]vinyl]-5-(methoxycarbonyl)-1,3,3-trimethyl-3H-indolium chloride Nicarbazin Formic acid Tribenuron methyl 5-methoxy-2-(methylthio)pyrimidin-4-ol ,97% 2,4-Dichloro-5-methoxypyrimidine 1-Formylhomopiperazine Methyl 4-acetamido-5-chloro-2-methoxybenzoate Procymidone 3,4-DIMETHYL-1H-PYRAZOLIUM DIHYDROGEN PHOSPHATE 1,4-DIFORMYLPIPERAZINE 4(1H)-Pyrimidinone, 2-methyl- (8CI,9CI) 2-Bromo-5-fomylthiazole 1,1-Dichlorodimethyl ether 4-CHLORO-5-METHOXY-2-(METHYLSULFANYL)PYRIMIDINE 5-METHOXY-2-SULFANYL-4-PYRIMIDINOL N-Formylmorpholine N-Methylformamide 2-[[[[(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]benzoic acid methyl ester 3,5-DIFLUOROPYRIDINE-4-CARBALDEHYDE 5-ETHYL-2-THIOURACIL Formamide
Methyl formate Suppliers      Global( 143)Suppliers     
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J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833+86-10-82849933jkinfo@jkchemical.com;market6@jkchemical.comCHINA 96839 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-59487313(Beijing)+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing)sh@meryer.comCHINA 40406 62
Alfa Aesar 400-610-6006; 021-67582000021-67582001/03/05saleschina@alfa-asia.comCHINA 30330 84
TCI (Shanghai) Development Co., Ltd. 800-988-0390021-67121385sales@tcishanghai.com.cnCHINA 22834 81
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BeiJing Hwrk Chemicals Limted 4006990298;010-57411839;0757-86311057;021-51691807010-87653215;0757-86311057;021-55236763sales@hwrkchemical.comCHINA 12647 55
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