ChemicalBook Chinese  Japanese  Germany

ChemicalBook >> CAS DataBase List >> Methyl formate

Methyl formate

CAS No. 107-31-3
Chemical Name: Methyl formate
Synonyms: Metil;HCOOCH3;acid-Me;Methylformiat;Methylformiaat;METHYL FORMATE;methylformiaate;formiatedemethyle;metil(formiatodi);METHYL METHANOATE
CBNumber: CB9106448
Molecular Formula: C2H4O2
Formula Weight: 60.05
MOL File: 107-31-3.mol
Methyl formate Property
Melting point : -100 °C
Boiling point : 32-34 °C(lit.)
density : 0.974 g/mL at 20 °C(lit.)
vapor density : 2.1 (vs air)
vapor pressure : 32.91 psi ( 55 °C)
refractive index : n20/D 1.343(lit.)
Fp : −16 °F
storage temp. : Flammables area
solubility : 300g/l
PH: 4-5 (200g/l, H2O, 20℃)
explosive limit: 5-23%(V)
Water Solubility : 300 G/L (20 ºC)
Merck : 14,6077
BRN : 1734623
Stability:: Stable. Extremely flammable. Readily forms explosive mixtures with air. Note low flash point and very wide explosion limits. Incompatible with oxidizing agents.
CAS DataBase Reference: 107-31-3(CAS DataBase Reference)
NIST Chemistry Reference: Methyl formate(107-31-3)
EPA Substance Registry System: Formic acid, methyl ester(107-31-3)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes : F+,Xn
Risk Statements : 12-20/22-36/37
Safety Statements : 9-16-24-26-33
RIDADR : UN 1243 3/PG 1
WGK Germany : 1
RTECS : LQ8925000
TSCA : Yes
HazardClass : 3
PackingGroup : I
Hazardous Substances Data: 107-31-3(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H224 Extremely flammable liquid and vapour Flammable liquids Category 1 Danger
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H371 May cause damage to organs Specific target organ toxicity, single exposure Category 2 Warning P260, P264, P270, P309+P311, P405,P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Methyl formate Chemical Properties,Usage,Production

Chemical Properties
colourless liquid
General Description
A clear colorless liquid with an agreeable odor. Flash point -27°F. Less dense than water Vapors heavier than air.
Air & Water Reactions
Highly flammable. Water soluble. Reacts slowly with water to give formic acid, a corrosive material, and methanol, a flammable liquid. Both products are dissolved in the water.
Reactivity Profile
Methyl formate reacts with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated with caustic solutions. Flammable hydrogen is generated by mixing with alkali metals and hydrides.
Health Hazard
Inhalation causes irritation of mucous membranes. Prolonged inhalation can produce narcosis and central nervous symptoms, including some temporary visual disturbance. Contact with liquid irritates eyes and may irritate skin if allowed to remain. Ingestion causes irritation of mouth and stomach and central nervous system depression, including visual disturbances.
Fire Hazard
Behavior in Fire: Vapor is heavier than air and may travel considerable distance to a source of ignition and flash back.
Methyl formate Preparation Products And Raw materials
Raw materials
Iridium
Preparation Products
Methyl 2-amino-3,5-dibromobenzoate 2-Fluoropyridine-5-carboxaldehyde Ethametsulfuron-methyl Imidazole-2-carboxaldehyde 1,2,4-Triazole Bensulfuron methyl Olaquindox DPX-T5648 N,N-Dimethylformamide pyrante 2,3-Quinoline dicarboxylic acid 2-[2-[4-[(4-ethoxyphenyl)methylamino]phenyl]vinyl]-5-(methoxycarbonyl)-1,3,3-trimethyl-3H-indolium chloride Nicarbazin Formic acid Tribenuron methyl 5-methoxy-2-(methylthio)pyrimidin-4-ol ,97% 2,4-Dichloro-5-methoxypyrimidine 1-Formylhomopiperazine Methyl 4-acetamido-5-chloro-2-methoxybenzoate Procymidone 3,4-DIMETHYL-1H-PYRAZOLIUM DIHYDROGEN PHOSPHATE 1,4-DIFORMYLPIPERAZINE 4(1H)-Pyrimidinone, 2-methyl- (8CI,9CI) 2-Bromo-5-fomylthiazole 1,1-Dichlorodimethyl ether 4-CHLORO-5-METHOXY-2-(METHYLSULFANYL)PYRIMIDINE 5-METHOXY-2-SULFANYL-4-PYRIMIDINOL N-Formylmorpholine N-Methylformamide 2-[[[[(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]benzoic acid methyl ester 3,5-DIFLUOROPYRIDINE-4-CARBALDEHYDE 5-ETHYL-2-THIOURACIL Formamide
Methyl formate Suppliers      Global( 152)Suppliers     
Supplier Tel Fax Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96832 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40403 62
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30315 84
TCI (Shanghai) Development Co., Ltd. 800-988-0390
021-67121385 sales@tcishanghai.com.cn China 22833 81
ShangHai DEMO Chemical Co.,Ltd 400-021-7337 qq:2355568890
0086-21-50182339 sales@demochem.com; export1@demochem.com China 2610 57
Beijing dtftchem Technology Co., Ltd. 13651141086; 86(10)60275028、60275820
86 (10) 60270825 dtftchem@sina.com China 1443 62
Energy Chemical 021-58432009 / 400-005-6266
021-58436166-800 info@energy-chemical.com China 44198 61
Beijing Ouhe Technology Co., Ltd +86-10-4006331231;+86-10-51280831;+86-10-82967028
+86-10-82967029 sales@ouhechem.com China 10814 60
JinYan Chemicals(ShangHai) Co.,Ltd. 13817811078,021-50426030
86-021-50426522,50426273 sales@jingyan-chemical.com China 10094 60
Jia Xing Isenchem Co.,Ltd 0573-85280080,15157346371
0573-85285100 isenchem@163.com,QQ:2446116053 China 9796 66
 
107-31-3(Methyl formate)Related Search:
FORMATE ION CHROMATOGRAPHY STANDARD METHYL ISOCYANOACETATE ZINC FORMATE Methyl bromide 2-[[[[(4-Methoxy-6-methyl-1,3,5-triazin-2-yl)amino]carbonyl]amino]sulfonyl]benzoic acid methyl ester Tribenuron methyl Sodium formate Methyl acrylate Thiophanate-methyl Methyl chloroformate Methylparaben Methyl acetate Calcium formate Methyl benzoate Ammonium formate Ethyl formate Pirimiphos-methyl Methyl
Formiate de methyle formiatedemethyle formiatedemethyle(french) HCOOCH3 Methyl ester of formic acid methyle(formiatede) methyle(formiatede)(french) Methylester kyseliny mravenci methylesterkyselinymravenci Methylformiaat Methylformiat Metil metil(formiatodi) Mravencan methylnaty mravencanmethylnaty Standard Materials for GC Solvents for HPLC & Spectrophotometry Fatty Acid Methyl Esters (GC Standard) Solvents for Spectrophotometry METHANOIC ACID-METHYL ESTER METHYL METHANOATE METHYL FORMATE FORMIC ACID METHYL ESTER Building Blocks Analytical Standards Anhydrous Grade Solvents Analytical Chromatography Product Catalog BioChemical Carbonyl Compounds C2 to C5 107-31-3 Chromatography Esters FA/FAME, Lipids/Sterols FAMEs Food & Beverage Standards Organic Building Blocks Neats & Single Component Solutions Reagent Grade Solvents Solvents Spectrophotometric Grade Solvents methyl form(I)ate METHYL FORMATE, 99%, SPECTROPHOTOMETRIC GRADE METHYL FORMATE, ABSOLUTE METHYL FORMATE, STANDARD FOR GC METHYL FORMATE, FOR UV-SPECTROSCOPY METHYL FORMATE 95+% MethylFormate,Certified Methyl formate, extra pure, 97% Methyl formate, for spectroscopy, 98% METHYLFORMATE,HPLCGRADE Ameisensuremethylester methylformiaate 107313 refrigerants Organics Methyl formate, 97%, cont. ca 3% methanol Analytical Chemistry
Copyright 2016 © ChemicalBook. All rights reserved