| Identification | More | [Name]
Solketal | [CAS]
100-79-8 | [Synonyms]
1,2-ISOPROPYLIDENEGLYCEROL
1,2-ISOPROPYLIDENE-RAC-GLYCEROL
1,2-O-ISOPROPYLIDENEGLYCEROL
(+/-)-2,2-DIMETHYL-1,3-DIOXOLANE-4-METHANOL
2,2-DIMETHYL-1,3-DIOXOLANE-4-METHANOL
(+/-)-2,2-DIMETHYL-4-HYDROXYMETHYL-1,3-DIOXOLANE
2,2-DIMETHYL-4-HYDROXYMETHYL-1,3-DIOXOLANE
2,3-O-ISOPROPYLIDENEGLYCEROL
ACETONE GLYCERINE KETAL
ACETONE KETAL OF GLYCERINE
DL-ALPHA,BETA-ISOPROPYLIDENEGLYCEROL
GLYCEROL DIMETHYLKETAL
ISOPROPYLIDENEGLYCEROL
ISOPROPYLIDENGLYCEROL
LABOTEST-BB LT00233172
(R,S)-ISOPROPYLIDENE GLYCEROL
SOLKETAL
SOLKETAL(R)
1,2-Isopropylideneglycerin
1,2-O,O-Isopropylideneglycerin | [EINECS(EC#)]
202-888-7 | [Molecular Formula]
C6H12O3 | [MDL Number]
MFCD00063238 | [Molecular Weight]
132.16 | [MOL File]
100-79-8.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colourless liquid | [Melting point ]
-27℃ | [Boiling point ]
189-191 °C
| [density ]
1.066 g/mL at 20 °C(lit.)
| [vapor pressure ]
34Pa at 20℃ | [refractive index ]
n20/D 1.434
| [Fp ]
176 °F
| [storage temp. ]
2-8°C | [solubility ]
172g/l soluble | [form ]
Liquid | [pka]
14.20±0.10(Predicted) | [color ]
Clear colorless | [PH]
4.0-7.5 (H2O) | [Optical Rotation]
4.1°(C=1.00 g/100mL, ETOH, 20°C, 589nm) | [Water Solubility ]
miscible | [Merck ]
14,5213 | [BRN ]
104465 | [Cosmetics Ingredients Functions]
HAIR CONDITIONING | [InChI]
1S/C6H12O3/c1-6(2)8-4-5(3-7)9-6/h5,7H,3-4H2,1-2H3 | [InChIKey]
RNVYQYLELCKWAN-UHFFFAOYSA-N | [SMILES]
CC1(C)OCC(CO)O1 | [LogP]
0.3 at 20℃ | [CAS DataBase Reference]
100-79-8(CAS DataBase Reference) | [NIST Chemistry Reference]
1,3-Dioxolane-4-methanol, 2,2-dimethyl-(100-79-8) | [EPA Substance Registry System]
100-79-8(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H319 | [Precautionary statements ]
P264-P280-P305+P351+P338-P337+P313 | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S24/25:Avoid contact with skin and eyes .
S36:Wear suitable protective clothing .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [WGK Germany ]
2
| [RTECS ]
JI0400000
| [F ]
10 | [TSCA ]
Yes | [REACH Registrations]
Active | [HS Code ]
29329970 | [Storage Class]
10 - Combustible liquids | [Hazard Classifications]
Eye Irrit. 2
Repr. 2 | [Safety Profile]
A poison by
intravenous route. An eye irritant. Mutation
data reported. A very dangerous fire hazard
when exposed to heat or flame; can react
vigorously with oxidizing materials. To fight
fire, use alcohol foam, CO2, dry chemical.
When heated to decomposition it emits
acrid smoke and fumes. | [Toxicity]
LD50 in rats (g/kg): 7 orally; 3 i.p. (Perez) |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
Glycerol-->Hydrogen cyanide | [Preparation Products]
Dropropizine-->3-Ethoxy-1,2-propanediol-->Benzyl glycidyl ether-->2,3-Dihydroxypropyl methacrylate-->1,3-Dioxan-5-ol, 2,2-dimethyl--->2,2-Dimethyl-1,3-dioxolan-4-ylmethyl p-toluenesulfonate-->4-[(2,3-Epoxypropoxy)methyl]-2,2-dimethyl-1,3-dioxolane-->(R)-4-Benzyloxymethyl-2,2-dimethyl-1,3-dioxolane-->SELACHYL ALCOHOL-->(2,2-Dimethyl-[1,3]-dioxolan-4-yl)-methylamine-->3-Bromo-1,2-propanediol-->4-(Chloromethyl)-2,2-dimethyl-1,3-dioxolane-->1,3-Dioxolane-4-carboxylicacid,2,2-dimethyl-,methylester(9CI) |
| Hazard Information | Back Directory | [Chemical Properties]
clear colourless liquid | [Uses]
A MEK inhibitor | [Synthesis Reference(s)]
Tetrahedron, 52, p. 9387, 1996 DOI: 10.1016/0040-4020(96)00501-7
The Journal of Organic Chemistry, 53, p. 2859, 1988 DOI: 10.1021/jo00247a043 | [General Description]
DL-1,2-Isopropylideneglycerol undergoes effective isopropylidenation and deprotection reaction catalyzed by phosphotungstic acid. |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|