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101-80-4

101-80-4 Structure

101-80-4 Structure
IdentificationMore
[Name]

4,4'-Oxydianiline
[CAS]

101-80-4
[Synonyms]

4,4'-DADPE
4,4'-DIAMINODIPHENYL ETHER
4,4-DIAMINODIPHENYL ETHER
4,4'-DIAMINODIPHENYL OXIDE
4,4'-DIAMINOPHENYL ETHER
4,4'-DPE
4,4'-ODA
4,4'-Oxybisbenzenamine
4,4'-OXYDIANILINE
4,4-OXYDIANILINE
4-AMINOPHENYL ETHER
BIO-FARMA BF003088
BIS(4-AMINOPHENYL) ETHER
BIS(P-AMINOPHENYL)ETHER
ODA
TIMTEC-BB SBB003546
ZERENEX ZX004984
4-(4-Aminophenoxy)phenylamine
4,4’-biaminodiphenylether
4,4’-diaminobiphenyloxide
[EINECS(EC#)]

202-977-0
[Molecular Formula]

C12H12N2O
[MDL Number]

MFCD00007863
[Molecular Weight]

200.24
[MOL File]

101-80-4.mol
Chemical PropertiesBack Directory
[Appearance]

4,40′-Oxydianiline is a white crystalline solid, or a beige powder.
[Appearance]

Colorless crystalline
[mp ]

188-192 °C(lit.)
[bp ]

190 °C (0.1 mmHg)
[vapor pressure ]

10 mm Hg ( 240 °C)
[Fp ]

426 °F
[Stability:]

Stable. Combustible. Incompatible with strong oxidizing agents. Hygroscopic.
[Water Solubility ]

Insoluble. <0.01 g/100 mL at 15 ºC
[BRN ]

475735
[CAS DataBase Reference]

101-80-4(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzenamine, 4,4'-oxybis-(101-80-4)
[EPA Substance Registry System]

101-80-4(EPA Substance)
Hazard InformationBack Directory
[Chemical Properties]

4-Aminophenyl ether is a resin used in the manufacture of a variety of industrial products. For example as, insulating varnishes, flame-retardant fi bers, wire enamels, coatings, and fi lms. It is also used for the manufacture of other fi re-resistant products.
[General Description]

Odorless colorless crystals or an odorless fine, beige powder.
[Reactivity Profile]

4,4'-DIAMINODIPHENYL ETHER(101-80-4) oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154, 164]. A mixture of liquid air and diethyl ether exploded spontaneously [MCA Case History 616(1960)].
[Air & Water Reactions]

Insoluble in water.
[Health Hazard]

4-Aminophenyl ether is highly toxic to animals. There is suffi cient evidence as a carcinogenicity and has caused adenomas and carcinomas in the thyroid and liver of experimental rats.
[Potential Exposure]

Intermediate in the manufacture of high-temperature-resistant, straight polyimide and poly (esterimide) resins capable of withstanding temperatures of Up to 480°C for short periods or 260°C for prolonged periods of time. Some p-phenylenediamine compounds have been used as rubber components, and DFG warns of danger of skin sensitization.
[First aid]

Move victim to fresh air. Call 911 or emergency medical service. Give artificial respiration if victim is not breathing. Do not use mouth-to-mouth methods if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device? Administer oxygen if breathing is difficult. Remove and isolate contaminated clothing and shoes. In the case of contact with substance, immediately flush skin or eyes with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin. Keep victim warm and quiet. Effects of exposure (inhalation, ingestion, or skin contact) to substance may be delayed.
Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Medical observation is recommended for 24-48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy.
[Fire Hazard]

This chemical is combustible.
[Shipping]

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.
[Incompatibilities]

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. Slowly hydrolyzes in water, releasing ammonia, and forming acetate salts. Decomposes at 265C releasing toxic oxides of nitrogen, sulfur, and carbon. Decomposed by strong ultraviolet light.
[Waste Disposal]

Incineration with provision for nitrogen oxides removal from flue gases.
Safety DataBack Directory
[Hazard Codes ]

T,N
[Risk Statements ]

R45:May cause cancer.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R62:Possible risk of impaired fertility.
R36/37/38:Irritating to eyes, respiratory system and skin .
R22:Harmful if swallowed.
[Safety Statements ]

S53:Avoid exposure-obtain special instruction before use .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S36/37:Wear suitable protective clothing and gloves .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S20:When using, do not eat or drink .
[RIDADR ]

UN 3077 9/PG 3
[WGK Germany ]

3
[RTECS ]

BY7900000
[HazardClass ]

6.1
[PackingGroup ]

III
[HS Code ]

29222900
[Safety Profile]

Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Poison by intraperitoneal route. Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx
[Hazardous Substances Data]

101-80-4(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Hydrochloric acid-->Sodium carbonate-->Sodium nitrite-->Ammonium hydroxide-->Ammonium chloride -->Iron-->Activated carbon-->Potassium chloride -->EMULSIFIER-->Citric acid-->Nitrobenzene-->Sodium formate-->4-Nitrophenol
[Preparation Products]

Polyimide film
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

4,4'-Diaminodiphenyl ether(101-80-4).msds
Spectrum DetailBack Directory
[Spectrum Detail]

4,4'-Oxydianiline(101-80-4)IR1
4,4'-Oxydianiline(101-80-4)MS
4,4'-Oxydianiline(101-80-4)IR2
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

4-Aminophenyl ether, 98%(101-80-4)
[Alfa Aesar]

Bis(4-aminophenyl) ether, 98%(101-80-4)
[Sigma Aldrich]

101-80-4(sigmaaldrich)
[TCI AMERICA]

4,4'-Diaminodiphenyl Ether,>98.0%(GC)(T)(101-80-4)
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