ChemicalBook--->CAS DataBase List--->112-60-7

112-60-7

112-60-7 Structure

112-60-7 Structure
IdentificationMore
[Name]

Bis[2-(2-hydroxyethoxy)ethyl] ether
[CAS]

112-60-7
[Synonyms]

BIS[2-(2-HYDROXYETHOXY)ETHYL]ETHER
TETRAETHYLENE GLYCOL
TETRAGLYCOL
2-(2-(2-(2-hydroxy-ethoxy)-ethoxy)-ethoxy)-ethanol
2-(2-[2-(2-Hydroxyethoxy)ethoxy]ethoxy)ethanol
2,2'-(Oxybis(ethyleneoxy))diethanol
2,2’-(oxybis(2,1-ethanediyloxy))bis-ethano
2,2’-(oxybis(ethyleneoxy))di-ethano
2,2’-[oxybis(2,1-ethanediyloxy)]bis-ethano
2,2’-[oxybis(2,1-ethanediyloxy)]bis-Ethanol
25322-68-3
25322-68-33,6,9-
25322-68-33,6,9-trioxaundecane-1,11-
25322-68-33,6,9-trioxaundecane-1,11-diol
3,6,9-trioxa-undecan-1,11-diol
3,6,9-Trioxaundecan-1,11-diol
Ethanol, 2,2'-(oxybis(ethyleneoxy))di-
Hi-Dry
Tetracthyleneglycol
tetraethylenegylcol
[EINECS(EC#)]

203-989-9
[Molecular Formula]

C8H18O5
[MDL Number]

MFCD00002879
[Molecular Weight]

194.23
[MOL File]

112-60-7.mol
Chemical PropertiesBack Directory
[Appearance]

liquid
[Melting point ]

-5.6 °C (lit.)
[Boiling point ]

314 °C (lit.)
[density ]

1.125 g/mL at 25 °C(lit.)
[vapor density ]

6.7 (vs air)
[vapor pressure ]

<0.01 mm Hg
[refractive index ]

n20/D 1.459(lit.)
[Fp ]

400 °F
[storage temp. ]

Store below +30°C.
[solubility ]

1000g/l
[form ]

Liquid
[pka]

14.06±0.10(Predicted)
[color ]

Clear slightly yellow
[PH]

8.5-9.0 (500g/l, H2O, 20℃)
[Stability:]

Stable. Incompatible with strong oxidizing agents, strong bases.
[explosive limit]

0.5-3.4%(V)
[Water Solubility ]

soluble
[Specific Heat Capacity]

Cp(liquid):428.8J/(g·K),at 25℃
[Thermal Conductivity]

0.187 W/(m·K) at 25 ℃
[α-end]

hydroxyl
[Ω-end]

hydroxyl
[BRN ]

1634320
[Henry's Law Constant]

1.8×1013 mol/(m3Pa) at 25℃, HSDB (2015)
[InChI]

1S/C8H18O5/c9-1-3-11-5-7-13-8-6-12-4-2-10/h9-10H,1-8H2
[InChIKey]

UWHCKJMYHZGTIT-UHFFFAOYSA-N
[SMILES]

OCCOCCOCCOCCO
[LogP]

-2 at 25℃
[Surface tension]

44.72 mN/m at 303.15K
[Uses]

Solvent for nitrocellulose, plasticizer, lacquers, coating compositions.
[CAS DataBase Reference]

112-60-7(CAS DataBase Reference)
[NIST Chemistry Reference]

Ethanol, 2,2'-[oxybis(2,1-ethanediyloxy)]bis-(112-60-7)
[EPA Substance Registry System]

112-60-7(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)
GHS05
[Signal word ]

Warning
[Hazard statements ]

H320
[Precautionary statements ]

P264-P337+P313-P305+P351+P338
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

2
[RTECS ]

XC2100000
[Autoignition Temperature]

340 °C DIN 51794
[TSCA ]

Yes
[REACH Registrations]

Active
[HS Code ]

29094919
[Storage Class]

10 - Combustible liquids
[Safety Profile]

Mildly toxic by ingestion. A sktn and eye irritant. Combustible when exposed to heat or flame; can react with oxidzing materials. To fight fire, use alcohol foam, water, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
[Hazardous Substances Data]

112-60-7(Hazardous Substances Data)
[Toxicity]

LD50 orally in Rabbit: > 18056 mg/kg LD50 dermal Rabbit > 18056 mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethylene oxide
[Preparation Products]

4'-Formylbenzo-15-crown 5-ether-->Heptaethylene glycol-->3,6,9,12-tetraoxahexadecan-1-ol-->Diglycolic acid-->mPEG6-CH2COOH-->S-Acetyl-PEG3-Azido-->1-mercapto-11-hydroxy-3,6,9-trioxaundecane-->2,5,8,11,14-pentaoxahexadecan-16-oic acid-->3,6,9,12,15,18,21,24,27,30,33,36-dodecaoxaoctatriacontane-1,38-diol-->Acetic acid, [2-[2-(2-aminoethoxy)ethoxy]ethoxy]--->Bromo-PEG4-t-butyl ester-->Amino-PEG8-azide-->1,4,7,10,13-Pentaoxa-16-azacyclooctadecane-->FMoc-NH-8(ethylene glycol)-acetic acid-->m-PEG7-CH2COOH-->N-Biotinyl-3,6,9-trioxaundecane-1,11-diamine-->O-(2-Aminoethyl)-O-(2-(Boc-amino)ethyl)octaethylene glycol-->Dodecaethylene glycol monomethyl ether-->Tetraethyleneglycol monododecyl ether
Hazard InformationBack Directory
[General Description]

Colorless to straw-colored liquid with a mild odor. Sinks and mixes with water.
[Reactivity Profile]

TETRAETHYLENE GLYCOL(112-60-7) is a ether-alcohol derivative. The ether being relatively unreactive. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. They react with oxoacids and carboxylic acids to form esters plus water. Oxidizing agents convert alcohols to aldehydes or ketones. Alcohols exhibit both weak acid and weak base behavior. They may initiate the polymerization of isocyanates and epoxides. May attack some forms of plastics [USCG, 1999].
[Air & Water Reactions]

Water soluble.
[Health Hazard]

Compound is nonirritating. No symptoms observed by any exposure route.
[Description]

Tetraethylene glycol is a polymer consisting of ethylene glycol monomer units and two terminal hydroxyl groups. The hydroxyl groups can react to further derivatize the compound. Ethylene glycol compounds have hydrophilic characteristics. The solubility of the polymer increases as the number of ethylene glycol groups increase.
[Chemical Properties]

Tetraethylene glycol is a high-boiling, clear liquid of low volatility. hygroscopic. It is completely miscible with water and a wide variety of organic solvents. insoluble in benzene, toluene, or gasoline. Combustible. For certain aliphatic hydrocarbons, it has a very slight affinity. Tetraethylene glycol is used as a coupling agent for blending water-soluble and water-insoluble compounds in such formulations as lubricants, glues, cork and textile products, etc.
[Definition]

ChEBI: Tetraethylene glycol is a poly(ethylene glycol).
[Production Methods]

Tetraethylene glycol is prepared commercially by adding ethylene oxide to ethylene glycol, diethylene glycol, or water in the presence of a suitable catalyst.
[Flammability and Explosibility]

Nonflammable
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Bis[2-(2-hydroxyethoxy)ethyl] ether(112-60-7).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Bis[2-(2-hydroxyethoxy)ethyl] ether(112-60-7)MS
Bis[2-(2-hydroxyethoxy)ethyl] ether(112-60-7)1HNMR
Bis[2-(2-hydroxyethoxy)ethyl] ether(112-60-7)13CNMR
Bis[2-(2-hydroxyethoxy)ethyl] ether(112-60-7)IR1
Bis[2-(2-hydroxyethoxy)ethyl] ether(112-60-7)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Tetraethylene glycol, 99.50%(112-60-7)
[Alfa Aesar]

Tetraethylene glycol, 99%(112-60-7)
[Sigma Aldrich]

112-60-7(sigmaaldrich)
[TCI AMERICA]

Tetraethylene Glycol,>95.0%(GC)(112-60-7)
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