| Identification | More | [Name]
Methyl anisate | [CAS]
121-98-2 | [Synonyms]
4-METHOXYBENZOIC ACID METHYL ESTER
ANISIC ACID METHYL ESTER
FEMA 2679
METHYL 4-ANISATE
METHYL 4-METHOXYBENZOATE
METHYL ANISATE
METHYL P-ANISATE
METHYL PARA-ANISATE
METHYL P-METHOXYBENZOATE
P-ANISIC ACID METHYL ESTER
RARECHEM AL BF 0083
4-methoxy-benzoicacimethylester
Benzoic acid, p-methoxy-, methyl ester
Benzoicacid,4-methoxy-,methylester
Methyl ester of p-Methoxybenzoic acid
p-Methoxybenzoic acid methyl ester
p-methoxy-benzoicacimethylester
METHYL P-ANISATE 99+%
4-Methoxybenzoicacidmethylester~Methylp-anisate
4-METHOXYLBENZOICACIDMETHYLESTER | [EINECS(EC#)]
204-513-2 | [Molecular Formula]
C9H10O3 | [MDL Number]
MFCD00008437 | [Molecular Weight]
166.17 | [MOL File]
121-98-2.mol |
| Chemical Properties | Back Directory | [Appearance]
white crystalline mass | [Melting point ]
47-51 °C (lit.) | [Boiling point ]
244-245 °C (lit.) | [density ]
1.1708 (rough estimate) | [FEMA ]
2679 | [refractive index ]
1.5224 (estimate) | [Fp ]
>230 °F
| [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
Chloroform, Methanol (Slightly) | [form ]
Solid | [color ]
Plates from alcohol. Flakes from EtOH or Et2O | [Odor]
at 100.00 %. herbal anise sweet | [biological source]
synthetic | [Odor Type]
anisic | [Water Solubility ]
643.1mg/L(20 ºC) | [JECFA Number]
884 | [BRN ]
2208571 | [Dielectric constant]
4.3（33℃） | [Major Application]
flavors and fragrances | [Cosmetics Ingredients Functions]
PERFUMING | [InChI]
1S/C9H10O3/c1-11-8-5-3-7(4-6-8)9(10)12-2/h3-6H,1-2H3 | [InChIKey]
DDIZAANNODHTRB-UHFFFAOYSA-N | [SMILES]
COC(=O)c1ccc(OC)cc1 | [LogP]
2.27 | [CAS DataBase Reference]
121-98-2(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzoic acid, 4-methoxy-, methyl ester(121-98-2) | [EPA Substance Registry System]
121-98-2(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
2
| [RTECS ]
BZ4925000
| [TSCA ]
Yes | [HS Code ]
29189900 | [Storage Class]
11 - Combustible Solids | [Toxicity]
LD50 orl-rat: >5 g/kg FCTXAV 14,481,76 |
| Hazard Information | Back Directory | [Description]
Methyl anisate is the methyl ester of p-anisic acid. | [Chemical Properties]
Methyl anisate has a herbaceous, anise-like odor and a sweet taste
similar to melon. | [Chemical Properties]
Methyl anisate has an herbaceous, anise-like odor and a sweet taste similar to melon. | [Chemical Properties]
white crystalline mass | [Occurrence]
Reported found in the mushroom variety Trametes graveolens, feyoa fruit and peel (Feijoa sellowiana), white
wine, cocoa, tea, guava, starfruit, Bourbon vanilla, Tahiti vanilla, mountain papaya, sapodilla fruit and Illicium verum. | [Uses]
Methyl p-anisate has been used as a standard for the quantification of odorant compounds in French mimosa absolute oil by GC-Sniffing. | [Definition]
ChEBI: A benzoate ester obtained by the formal condensation of the carboy group of 4-methoxybenzoic acid with methanol. | [Preparation]
By esterification of anisic acid with methanol or from sodium anisate, dimethyl sulfate and small amounts of methanol. | [Aroma threshold values]
Aroma characteristics at 10.0%: sweet, creamy, anisic vanillalike, slightly spicy, woody and powdery
heliotropine-like. | [Taste threshold values]
Taste characteristics at 10 ppm: spicy, sweet, anisic-like with a woody vanilla, licorice and methyl salicylate
nuances and with a lingering sweet coumarin vanilla aftertaste. | [Synthesis Reference(s)]
Tetrahedron Letters, 33, p. 1959, 1992 DOI: 10.1016/0040-4039(92)88113-J | [General Description]
Methyl p-anisate is a volatile compound released from Mycobacterium tuberculosis and is detected in the breath of tuberculosis patients. It is a potential biomarker for mycobacteria. | [Biochem/physiol Actions]
Taste at 10 ppm | [Safety Profile]
Low toxicity by ingestion and skincontact. A skin irritant. When heated todecomposition it emits acrid smoke and irritating fumes. | [Solubility in organics]
Soluble in alcohol and oils. Poorly soluble in Propylene glycol.
| [Purification Methods]
Distil the ester and/or crystallise it from EtOH. [Beilstein 10 H 159, 10 III 297, 10 IV 360.] |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|