Back to ChemicalBook Home--->CAS DataBase List--->122-97-4

122-97-4

122-97-4 Structure

122-97-4 Structure
IdentificationMore
[Name]

3-Phenyl-1-propanol
[CAS]

122-97-4
[Synonyms]

2-PHENYLETHYLCARBINOL
3-HYDROXY-1-PHENYLPROPANE
3-PHENYL-1-PROPANOL
3-PHENYLPROPANOL
3-PHENYLPROPANOL-1
3-PHENYLPROPYL ALCOHOL
FEMA 2885
GAMMA-PHENYLPROPYL ALCOHOL
HYDROCINNAMIC ALCOHOL
HYDROCINNAMYL ALCOHOL
PHENYL PROPYL ALCOHOL
RARECHEM AL BD 0160
(3-Hydroxypropyl)benzene
1-Hydroxy-3-phenylpropane
1-Propanol, 3-phenyl-
3-Phenylprophyl alcohol
3-Benzenepropanol
3-phenyl-1-propano
3-Phenyl-n-propanol
3-phenylpropan-
[EINECS(EC#)]

204-587-6
[Molecular Formula]

C9H12O
[MDL Number]

MFCD00002950
[Molecular Weight]

136.19
[MOL File]

122-97-4.mol
Chemical PropertiesBack Directory
[Appearance]

CLEAR COLOURLESS LIQUID
[mp ]

−18 °C(lit.)
[bp ]

119-121 °C12 mm Hg(lit.)
[density ]

1.001 g/mL at 20 °C(lit.)
[refractive index ]

n20/D 1.526(lit.)
[FEMA ]

2885
[Fp ]

229 °F
[Water Solubility ]

10.3 g/L (20 ºC)
[BRN ]

1857542
[CAS DataBase Reference]

122-97-4(CAS DataBase Reference)
[NIST Chemistry Reference]

3-Phenylpropanol(122-97-4)
[EPA Substance Registry System]

122-97-4(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R36/38:Irritating to eyes and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
[WGK Germany ]

1
[RTECS ]

UB8970000
[HS Code ]

29062900
Raw materials And Preparation ProductsBack Directory
[Raw materials]

trans-Cinnamaldehyde-->CINNAMIC ALCOHOL-->Ethyl cinnamate
[Preparation Products]

Phenprobamate-->3-PHENYLPROPYL ACETATE
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

3-Phenyl-1-propanol(122-97-4).msds
Questions And AnswerBack Directory
[Chemical properties]

Colorless viscous liquid with a sweet scent of flowers and sweetmeat and the flavor of fresh fruit after dilution. Its boiling point is at 236 °C, flash point at 109 °C. Soluble in ethanol, propylene glycol and most of the non-volatile oil, insoluble in glycerol and mineral oil, slightly soluble in water (1: 300).
Natural 3-Phenyl-1-propanol can be found in strawberries, Styrax cream, benzoin cream, tea, Peru Balsam, Cassia leaf oil, cinnamon oil and so on.
[Uses]

(1) Temporarily allowed as food flavouring agent in GB 2760-1996. Mainly used in the preparation of essence of peach, apricot, plum, watermelon, strawberry and nuts like walnut and hazel.
(2) Mainly used in the preparation of essence and medicine.
An intermediate of proformiphen (a central skeletal muscle relaxant)
Temporarily allowed as food flavouring agent in GB 2760-1996.
It has a sweet scent of flowers and sweetmeat and a pleasant flavor of fresh fruit after dilution
Natural 3-Phenyl-1-propanol can be found in strawberries, Styrax cream, benzoin cream, tea, Peru Balsam, Cassia leaf oil, cinnamon oil and so on.
(3) As a medicine, it can be applied to Cholecystitis, cholangitis, cholelithiasis, biliary postoperative syndrome, hypercholesterolemia, etc.
(4) Mainly used in the preparation of essence and medicine.
An intermediate of proformiphen, a central skeletal muscle relaxant.
As an antiputrefactiva in cosmetic in combination with piperonal or pepper, 3-Phenyl-1-propanol has a mold resistance on germ and mycete, along with a natural fragrance.
3-Phenyl-1-propanol or its ester derivatives can be used as flavor constituents of flowers such as lilac, hyacinth and keiskei for its aromatic vinegar.
[content analysis]

Total alcohol method (OT-5)Sample amount : l g,  Equivalent Factor (f) = 68.10.
nonpolar column method of gas chromatography (GT-10-4)
[toxicity]

GRAS(FEMA).
LD502300mg/kg (Rats oral).
[Security utilization limitation]

FEMA(mg/kg):0.73 in soft drinks; 1.4 in cold drink; 2.8 in sweets; 3.3 in  baked food; 4.3 in gum confection; 5.0 in liquor. WHO Class II /moderate toxicity
Moderate limit (FDA§172.515,2000).
[Production Method]

(1) the catalytic hydrogenation of ethyl cinnamate.
The hydrogenation reaction is conducted in autoclave with chromium-copper-barium catalyst at 200℃ and 20MPa for 5-9h. The filtrate obtained after cooling and filtration is extracted by diethyl ether.  After the recycling of diethyl ether, reduced pressure distillation of the extracting solution is conducted to collect the fraction of 110-112℃(1.06kPa), which is the finished product. The yield is about 85%.
Grignard reaction of benzyl chloride and oxirane, followed by the hydrolysis with sulfuric acid to obtain 3-Phenyl-1-propanol. The yield is about 65-70%。
(2) The hydrogenation of peruvin or cinnamaldehyde.
[Standard for Maximum Allowable Amount]

food additives: phenylpropanol
allowable usage:food
function of additives:Food flavouring
maximum allowable amount of usage (g/kg): The essence ingredients used in shall not exceed the maximum permissible usage and residues allowed in GB 2760.
maximum allowable amount of residue(g/kg): The essence ingredients used in shall not exceed the maximum permissible usage and residues allowed in GB 2760.
Spectrum DetailBack Directory
[Spectrum Detail]

3-Phenyl-1-propanol(122-97-4)MS
3-Phenyl-1-propanol(122-97-4)1HNMR
3-Phenyl-1-propanol(122-97-4)13CNMR
3-Phenyl-1-propanol(122-97-4)IR1
3-Phenyl-1-propanol(122-97-4)IR2
3-Phenyl-1-propanol(122-97-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

3-Phenyl-1-propanol, 98%(122-97-4)
[Alfa Aesar]

3-Phenyl-1-propanol, 99%(122-97-4)
[Sigma Aldrich]

122-97-4(sigmaaldrich)
[TCI AMERICA]

3-Phenyl-1-propanol,>98.0%(GC)(122-97-4)
122-97-4 suppliers list
Company Name: Capot Chemical Co.,Ltd.
Tel: +86 (0)571-855 867 18
Fax: +86 (0)571-858 647 95
Website: www.capotchem.com
Company Name: SHANDONG ZHI SHANG CHEMICAL CO.LTD
Tel: +86 18953170293
Fax: +86 0531-67809011
Website: www.chemicalbook.com/ShowSupplierProductsList31162/0.htm
Company Name: Chengdu Biopurify Phytochemicals Ltd.
Tel: 18080483897
Fax:
Website: www.chemicalbook.com/ShowSupplierProductsList31191/0.htm
Company Name: Standardpharm Co. Ltd.
Tel: 0714-3992388
Fax:
Website: www.standardpharm.com
Company Name: Chemwill Asia Co.,Ltd.
Tel: 86-21-51086038
Fax: 86-21-51861608
Website: www.chemwill.com
Company Name: Hubei Jusheng Technology Co.,Ltd.
Tel: 86-18871470254
Fax: 027-59599243
Website: www.chemicalbook.com/ShowSupplierProductsList31316/0.htm
Company Name: Haihang Industry Co.,Ltd
Tel: 86-531-88032799
Fax: +86 531 8582 1093
Website: www.haihangindustry.com
Company Name: career henan chemical co
Tel: +86-371-86658258
Fax:
Website: www.coreychem.com
Company Name: Henan DaKen Chemical CO.,LTD.
Tel: +86-371-55531817
Fax:
Website: www.dakentech.com
Company Name: Mainchem Co., Ltd.
Tel: +86-0592-6210733
Fax: +86-0592-6210733
Website: www.mainchem.com
Company Name: Henan Tianfu Chemical Co.,Ltd.
Tel: 0371-55170693
Fax: 0371-55170693
Website: www.tianfuchem.net
Company Name: Wuhan lenmaike Industrial Co., Ltd.  Gold
Tel:027-83916065,13396062449
Fax:027-83916065
Website:www.chemicalbook.com
Company Name: J & K SCIENTIFIC LTD.  
Tel:400-666-7788 +86-10-82848833
Fax:86-10-82849933
Website:www.jkchemical.com
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.  
Tel:+86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
Fax:+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing)
Website:www.meryer.com
Company Name: Alfa Aesar  
Tel:400-610-6006; 021-67582000
Fax:021-67582001/03/05
Website:www.chemicals.thermofisher.cn
Company Name: TCI (Shanghai) Development Co., Ltd.  
Tel:021-67121386 / 800-988-0390
Fax:021-67121385
Website:www.tcichemicals.com
Company Name: Energy Chemical  
Tel:021-58432009 / 400-005-6266
Fax:021-58436166-800
Website:www.energy-chemical.com
Company Name: Capot Chemical Co., Ltd  
Tel:+86 (0) 571 85 58 67 18
Fax:0086-571-85864795
Website:www.capotchem.com
Tags:122-97-4 Related Product Information
118-55-8 122-97-4 16721-80-5 16940-66-2 141-78-6 154-41-6 93-54-9 101-84-8 104-54-1 14898-87-4 103-82-2 67-63-0 1123-85-9 103-79-7 63131-29-3 939-90-2 501-52-0 603-35-0