ChemicalBook--->CAS DataBase List--->127-90-2

127-90-2

127-90-2 Structure

127-90-2 Structure
IdentificationMore
[Name]

Bis(2,3,3,3-tetrachloropropyl) ether
[CAS]

127-90-2
[Synonyms]

2,3,3,3,2',3',3',3'-OCTACHLORO DIPROPYL ETHER
BIS(2,3,3,3-TETRACHLOROPROPYL)ETHER
OCTACHLORODIPROPYL ETHER
S 421
1,1’-oxybis(2,3,3,3-tetrachloro-Propane
ENT 25,456
ent25,456
Ether, bis(2,3,3,3-tetrachloropropyl)
ether,bis(2,3,3,3-tetrachloropropyl)
Monsanto 16226
Monsanto cp-16226
monsantocp-16226
Octachloro-di-n-propyl ether
Propane, 1,1'-oxybis*2,3,3,3-tetrachloro-
Propane, 1,1'-oxybis[2,3,3,3-tetrachloro-
S 421 PESTANAL (1,1'-OXYBIS-(2,3,3,3-TE
2,3,3,3,2',3',3',3'-Octachloro
TETRACHLOROPROPYLETHER
Dipropyl octachloro ether
3-Methyl-1H-quinoxalin-2-one
[EINECS(EC#)]

204-870-4
[Molecular Formula]

C6H6Cl8O
[MDL Number]

MFCD00078679
[Molecular Weight]

377.74
[MOL File]

127-90-2.mol
Chemical PropertiesBack Directory
[Melting point ]

-49.9°C
[Boiling point ]

147 °C
[density ]

1.6352 (estimate)
[Fp ]

177 °C
[storage temp. ]

0-6°C
[form ]

neat
[Major Application]

agriculture
environmental
[InChI]

InChI=1S/C6H6Cl8O/c7-3(5(9,10)11)1-15-2-4(8)6(12,13)14/h3-4H,1-2H2
[InChIKey]

LNJXZKBHJZAIKQ-UHFFFAOYSA-N
[SMILES]

O(CC(Cl)C(Cl)(Cl)Cl)CC(Cl)C(Cl)(Cl)Cl
[CAS DataBase Reference]

127-90-2(CAS DataBase Reference)
[NIST Chemistry Reference]

Propane, 1,1'-oxybis[2,3,3,3-tetrachloro-(127-90-2)
Safety DataBack Directory
[WGK Germany ]

2
[RTECS ]

KN3600000
[Storage Class]

10 - Combustible liquids
[Toxicity]

LD50 orl-rat: 3630 mg/kg ARSIM* 20,15,66C
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Hydrochloric acid-->Sulfuric acid-->Aluminum chloride-->Trichloroethylene-->1,3,5-trioxane
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Bis(2,3,3,3-tetrachloropropyl) ether(127-90-2).msds
Hazard InformationBack Directory
[Description]

Bis(2,3,3,3-tetrachloropropyl) ether is a type of ether compound that is used as a solvent, flame retardant, and plasticizer in various industrial applications.It is also used as a pesticide and fumigant, as well as a component in some transformer oils.
[Uses]

Bis(2,3,3,3-tetrachloropropyl) ether is an effective synergizing agent which is used in pesticide production.
[Uses]

S 421 is an effective synergizing agent which is used in pesticide production.
[Production Methods]

Octachlorodipropyl ether was manufactured through a high temperature electrophilic chlorination process applied to dipropyl ether or, more commonly, to a pre chlorinated phenyl ether precursor. Industrial producers typically began with a phenoxy phenyl framework and subjected it to exhaustive chlorination in the liquid phase using chlorine gas and a Lewis acid catalyst, driving substitution to the fully chlorinated 2,3,4,5 positions on both rings. The reaction mixture, containing various partially chlorinated congeners, was then distilled or crystallised to isolate the octachloro derivative. This route was favoured because it allowed stepwise control of chlorination and produced the high purity technical material required for its historical use as a synergist.
[Synthesis Reference(s)]

Journal of Medicinal Chemistry, 44, p. 594, 2001 DOI: 10.1021/jm000282d
Tetrahedron Letters, 14, p. 1105, 1973
[Mechanism of action]

Hinders metabolic resistance by inhibiting detoxification enzymes
[Safety Profile]

Moderately toxic by ingestion.When heated to decomposition it emits toxic fumes ofClí. See also ETHERS and CHLORINATEDHYDROCARBONS, ALIPHATIC
[Pesticide Type]

Insecticide
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