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542-75-6

542-75-6 Structure

542-75-6 Structure
IdentificationMore
[Name]

1,3-Dichloropropene
[CAS]

542-75-6
[Synonyms]

1,3-DICHLORO-1-PROPENE
1,3-DICHLOROPENE
1,3-DICHLOROPROPENE
1,3-DICHLOROPROPENE-1
1,3-DICHLOROPROPYLENE
3-CHLOROALLYL CHLORIDE
A-CHLOROALLYL CHLORIDE
D-D
D-D mixture
Dichloropropene,Dichloropropane
DICHLOROPROPYLENE
NEMATOX
TELONE
TELONE(R)
TRANS-1,3-DICHLORO-1-PROPENE
TRANS-1,3-DICHLOROPENE
TRANS-1,3-DICHLOROPROPENE
TRANS-1,3-DICHLOROPROPYLENE
(1E)-1,3-Dichloro-1-propene
1,3-D
[EINECS(EC#)]

208-826-5
[Molecular Formula]

C3H4Cl2
[MDL Number]

MFCD00000985
[Molecular Weight]

110.97
[MOL File]

542-75-6.mol
Chemical PropertiesBack Directory
[Appearance]

1,3-Dichloropropene is a colorless to strawcolored liquid. Sharp, sweet, irritating, chloroform-like odor.
[Appearance]

clear yellowish to brownish liquid
[Melting point ]

-60 °C
[mp ]

-60 °C
[Boiling point ]

97-112 °C(lit.)
[bp ]

97-112 °C(lit.)
[density ]

1.2
[refractive index ]

n20/D 1.472(lit.)
[Fp ]

78 °F
[storage temp. ]

2-8°C
[Water Solubility ]

<0.01 g/100 mL at 16.5 ºC
[Merck ]

14,3075
[BRN ]

1719556
[Contact allergens]

This nematocide is used as a soil fumigant prior to crop cultivation. Farmers and process operators employed at pesticide plants are mainly exposed
[InChIKey]

UOORRWUZONOOLO-OWOJBTEDSA-N
[CAS DataBase Reference]

542-75-6(CAS DataBase Reference)
[NIST Chemistry Reference]

1-Propene, 1,3-dichloro-(542-75-6)
[EPA Substance Registry System]

542-75-6(EPA Substance)
Hazard InformationBack Directory
[Chemical Properties]

clear yellowish to brownish liquid
[General Description]

A clear colorless liquid. Flash point 95°F. Denser (at 10.2 lb/gal) than water and insoluble in water. Vapors are heavier than air. Used to make other chemicals and as soil fumigant.
[Reactivity Profile]

1,3-DICHLOROPROPENE(542-75-6) reacts vigorously with oxidizing materials. Reacts with aluminum, active metals, and halogenated compounds. Also reacts with acids and thiocyanates. Corrosive to magnesium, magnesium alloys and aluminum alloys. Incompatible with some metal salts .
[Air & Water Reactions]

Highly flammable. Insoluble in water.
[Health Hazard]

VAPOR: Irritating to eyes, nose and throat. LIQUID: Will burn skin and eyes. Harmful if swallowed.
[Potential Exposure]

Used as a soil fumigant prior to planting crops, such as cotton, sugar beet, potatoes; used in combinations with dichloropropanes as a soil fumigant. Workers engaged in manufacture, formulation and application of this soil fumigant and nematocide.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Fire Hazard]

FLAMMABLE. POISONOUS GASES ARE PRODUCED IN FIRE. Flashback along vapor trail may occur. Vapor may explode if ignited in an enclosed area. Toxic and irritating gases may be generated.
[Shipping]

UN2047 Dichloropropene, Hazard Class: 3; Labels: 3-Flammable liquid.
[Incompatibilities]

Vapor may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. May accumulate static electrical charges, and may cause ignition of its vapors. Incompatible with strong acids; oxidizers, aluminum or magnesium compounds; aliphatic amines; alkanolamines, alkaline materials; halogens, or corrosives. Note: Epichlorohydrin may be added as a stabilizer.
[Waste Disposal]

Incineration, preferably after mixing with another combustible fuel. Care must be exercised to assure complete combustion to prevent the formation of phosgene. An acid scrubber is necessary to remove the halo acids produced. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≧100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal.
Safety DataBack Directory
[Hazard Codes ]

T,N
[Risk Statements ]

R10:Flammable.
R20/21:Harmful by inhalation and in contact with skin .
R25:Toxic if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R43:May cause sensitization by skin contact.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
[Safety Statements ]

S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

UN 1992 3/PG 3
[WGK Germany ]

3
[RTECS ]

UC8310000
[TSCA ]

Yes
[HazardClass ]

3
[PackingGroup ]

II
[HS Code ]

29032990
[Safety Profile]

Confirmed carcinogen with experimental carcinogenic data. Poison by ingestion and intraperitoneal routes. Moderately toxic by skin contact. Mildly toxic by inhalation. A strong irritant. Mutation data reported. A pesticide. A flammable liquid and dangerous fire hazard when exposed to heat, flame, or oxidzers. Reacts vigorously with oxidizing materials. To fight fire, use water, foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of Cl-. See also ALLYL COMPOUNDS and CHLORIDES.
[Hazardous Substances Data]

542-75-6(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Chlorine-->Epichlorohydrin-->Allyl chloride-->N,N-Dimethylacetamide-->1,2-Dichloropropane-->1.3-Dichloropropene
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1,3-Dichloropropene(542-75-6).msds
Spectrum DetailBack Directory
[Spectrum Detail]

1,3-Dichloropropene(542-75-6)MS
1,3-Dichloropropene(542-75-6)IR1
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

1,3-Dichloropropene, mixture of isomers, 96%(542-75-6)
[Alfa Aesar]

1,3-Dichloropropene, cis + trans, tech. 90%(542-75-6)
[Sigma Aldrich]

542-75-6(sigmaaldrich)
[TCI AMERICA]

1,3-Dichloropropene  (cis-and trans-mixture),>92.0%(GC)(542-75-6)
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