| Identification | Back Directory | [Name]
2,5-Furandimethanol | [CAS]
1883-75-6 | [Synonyms]
NSC 40737
NSC 524614
FaRez 6305
RARECHEM AL BD 0012
2,5-FURANDIMETHANOL
2,5-Furanbismethanol
Furan-2,5-dimethanol
(Fur-2,5-diyl)dimethanol
2,5-Furandiylbismethanol
2,5-dihydroxymethylfuran
furan-2,5-diyldimethanol
BIS (HYDROXYMETHYL)FURAN
2,5-DihydroxyMethyl-furane
2,5-BIS(HYDROXYMETHYL)FURAN
(5-methylol-2-furyl)methanol
2,5-Bis(hydroxymethyl)furan 98+%
5-(HYDROXYMETHYL)FURFURYL ALCOHOL
[5-(Hydroxymethyl)-2-furyl]methanol
[5-(hydroxymethyl)furan-2-yl]methanol
2,5-Bis(hydroxymethyl)furan,2,5-Furandimethanol | [EINECS(EC#)]
217-544-1 | [Molecular Formula]
C6H8O3 | [MDL Number]
MFCD00003253 | [MOL File]
1883-75-6.mol | [Molecular Weight]
128.13 |
| Questions And Answer | Back Directory | [Description]
2,5-Furandimethanol is white or internally white solid in appearance, soluble in water, ethanol, acetone, pyridine, tetrahydrofuran, but insoluble in ethane, toluene, and dichloroethane. | [Chemical Properties]
It has the properties of dihydric alcohol. It can be esterified, alkoxylated, glycidyl etherification, cyanoethylation, etherification, urea alkylation, resination, etc. | [Preparation]
1. Preparation of adsorbent:
Add 100Kg of ADS-17 medium polar adsorption resin, 5Kg of diethyl maleate, 0.5Kg of 2-methyl-4- (2,2,3-trimethyl-3-cyclopentene into the 2000L reactor -1-yl)-2-buten-1-ol, 700Kg water, 2Kg polyvinyl alcohol, 1Kg benzoyl peroxide, reacted at 80°C for 6h and then heated to 85°C for 2h, then heated to 95° C react for 6h, filter and dry to obtain adsorbent;
2 ·Adsorption purification of 2,5-furandimethanol:
Mix 100Kg of technical grade 2,5-furandimethanol and 1000Kg of deionized water at 90°C for 3 hours, and then pass through a chromatography column equipped with adsorbent for adsorption at a temperature of 90°C and a flow rate of 3BV/h. After dehydration, a purified product of 2,5-furandimethanol can be obtained. |
| Chemical Properties | Back Directory | [Appearance]
Off-White to Pale Yellow Solid | [Melting point ]
74-77 °C | [Boiling point ]
275 °C | [density ]
1.283 | [Fp ]
120 °C | [storage temp. ]
Refrigerator | [solubility ]
Acetonitrile (Slightly), DMSO (Slightly) | [form ]
Solid | [pka]
13.74±0.10(Predicted) | [color ]
Off-White to Light Yellow | [InChI]
InChI=1S/C6H8O3/c7-3-5-1-2-6(4-8)9-5/h1-2,7-8H,3-4H2 | [InChIKey]
DSLRVRBSNLHVBH-UHFFFAOYSA-N | [SMILES]
O1C(CO)=CC=C1CO | [LogP]
-1.326 (est) | [EPA Substance Registry System]
2,5-Furandimethanol(1883-75-6) |
| Hazard Information | Back Directory | [Chemical Properties]
Off-White to Pale Yellow Solid | [Uses]
5-(Hydroxymethyl)furfuryl Alcohol is a secondary metabolite of Xylaramide, a new antifungal compound. | [Definition]
ChEBI: A furan carrying two hydroxymethyl substituents at the 2- and 5-positions. | [Biological Activity]
5-(Hydroxymethyl)furfuryl alcohol is a heterocyclic organic compound that is naturally produced by certain wood-inhabiting fungi. It can be derived by the reduction of the formyl group of 5-hydroxymethylfurfural. 5-(Hydroxymethyl)furfuryl alcohol can be used as a building block in the enzymatic synthesis of biobased polyesters. | [References]
[1] G SCHNEIDER O S H Anke. Xylaramide, a new antifungal compound, and other secondary metabolites from Xylaria longipes.[J]. Zeitschrift Fur Naturforschung Section C-A Journal of Biosciences, 1996, 51 11-12: 802-806. DOI: 10.1515/znc-1996-11-1206
[2] Z L LIU. Adaptive response of yeasts to furfural and 5-hydroxymethylfurfural and new chemical evidence for HMF conversion to 2,5-bis-hydroxymethylfuran.[J]. Journal of Industrial Microbiology & Biotechnology, 2004, 31 8: 345-352. DOI: 10.1007/s10295-004-0148-3
[3] YAN ZHANG Thaddeus C E Bei Han. Biotransformation of furfural and 5-hydroxymethyl furfural (HMF) by Clostridium acetobutylicum ATCC 824 during butanol fermentation[J]. New biotechnology, 2012, 29 3: Pages 345-351. DOI: 10.1016/j.nbt.2011.09.001
[4] YI JIANG. Enzymatic Synthesis of Biobased Polyesters Using 2,5-Bis(hydroxymethyl)furan as the Building Block[J]. Biomacromolecules, 2014, 15 7: 2482-2493. DOI: 10.1021/bm500340w |
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