ChemicalBook--->CAS DataBase List--->26412-87-3

26412-87-3

26412-87-3 Structure

26412-87-3 Structure
IdentificationMore
[Name]

Pyridine sulfur trioxide
[CAS]

26412-87-3
[Synonyms]

(DIMETHYLAMINOMETHYL)STYRENE
N-(4-VINYLBENZYL)-N,N-DIMETHYL AMINE
N,N-DIMETHYLVINYLBENZYLAMINE
POLY(4-VINYLPYRIDINE) SULFUR TRIOXIDE COMPLEX
PYRIDINE SULFUR TRIOXIDE
PYRIDINE SULFUR TRIOXIDE COMPLEX
PYRIDINE SULFUR TRIOXIDE COMPLEX POLYMER BOUND
PYRIDINE-SULPHURTRIOXIDECOMPLEX
SULFUR TRIOXIDE PYRIDINE COMPLEX
SULFUR TRIOXIDE PYRIDINE COMPLEX POLYMER BOUND
SULPHUR TRIOXIDE-PYRIDINE COMPLEX
VINYLBENZYLDIMETHYLAMINE
Pyridine,compd.withsulfurtrioxide(1:1)
Salfurtrioxidepyri-dinecomplex
Sulfurtrioxide,compd.withpyridine(1:1)
sulphur trioxide--pyridine (1:1)
Sulfur trioxide-pyridine complex, tech., 80%
Sulfurtrioxide-pyridinecomplex,98%
Sulfur trioxide pyridine complex, tech. (48.8-50.3% active SO3)
Pyridine, compd. with sulfur trioxide
[EINECS(EC#)]

247-683-3
[Molecular Formula]

C5H6NO3S
[MDL Number]

MFCD00078270
[Molecular Weight]

160.17
[MOL File]

26412-87-3.mol
Chemical PropertiesBack Directory
[Appearance]

white solid
[Melting point ]

~160 °C
[bulk density]

600kg/m3
[storage temp. ]

Store below +30°C.
[solubility ]

Soluble in polar organic solvents.
[form ]

Powder
[color ]

White to beige
[Water Solubility ]

reacts
[Sensitive ]

Moisture Sensitive
[BRN ]

3704116
[InChI]

InChI=1S/C5H5N.O3S/c1-2-4-6-5-3-1;1-4(2)3/h1-5H;
[InChIKey]

UDYFLDICVHJSOY-UHFFFAOYSA-N
[SMILES]

C1=CC=NC=C1.S(=O)(=O)=O
[CAS DataBase Reference]

26412-87-3(CAS DataBase Reference)
[Storage Precautions]

Moisture sensitive
[EPA Substance Registry System]

26412-87-3(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319
[Precautionary statements ]

P264-P270-P280-P301+P312-P302+P352-P305+P351+P338
[Hazard Codes ]

C
[Risk Statements ]

R22:Harmful if swallowed.
R34:Causes burns.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 3261 8/PG 2
[WGK Germany ]

3
[F ]

3-10-21
[Autoignition Temperature]

>350 °C
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29420000
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Acute Tox. 4 Oral
Eye Dam. 1
Skin Corr. 1B
[Toxicity]

LD50 orally in Rabbit: 500 - 2000 mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethyl acetate-->Sulfuric acid-->Pyridine-->Chlorosulfonic acid-->Chlorotrimethylsilane
[Preparation Products]

3-(pyridin-3-yl)propanal-->3-(3-Chloro-phenyl)-propionaldehyde-->3-(4-Chloro-phenyl)-propionaldehyde-->3-o-Tolyl-propionaldehyde-->3-(4-Nitro-phenyl)-propionaldehyde-->alpha-Ketobutyric acid sodium salt-->Sulfuric acid, anhydride with acetic acid-->4-Methylumbelliferyl sulfate potassium salt-->Dextran Sulfate Sodium Salt
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Pyridine sulfur trioxide(26412-87-3).msds
Hazard InformationBack Directory
[Description]

Pyridine sulphur trioxide is an important reaction reagent that can react with various compounds such as aldehydes, anthracenes and pyrroles to produce other heterocyclic compounds. Pyridine sulphur trioxide is primarily used in addition reactions or sulphonation processes.
[Chemical Properties]

white solid
[Uses]

Pyridine-Sulfur Trioxide Complex is used in the sulfation of squid ink polysaccharides (SIPs) as a potential candidate compound for the prevention of tumor metastasis. Pyridine-Sulfur Trioxide Complex is also used in the preparation and anticoagulation test of sulfated silk fibroin.
[Uses]

Usually used for sulfations of alcohols, sulfonations, deoxygenations and other reductions, oxidations with DMSO.
[reaction suitability]

reagent type: oxidant
[Purification Methods]

Wash the solid with a little CCl4, then H2O to remove traces of pyridine sulfate, and dry it over P2O5. [Baumgarten Chem Ber 59 1166 1926, Olah et al. Synthesis 59 1979, Beilstein 20/5 V 184].
Spectrum DetailBack Directory
[Spectrum Detail]

Pyridine sulfur trioxide(26412-87-3)MS
Pyridine sulfur trioxide(26412-87-3)13CNMR
Pyridine sulfur trioxide(26412-87-3)Raman
Pyridine sulfur trioxide(26412-87-3)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Sulfur trioxide pyridine complex, tech. (48.8-50.3% active SO3)(26412-87-3)
[Alfa Aesar]

Sulfur trioxide-pyridine complex, 98%, active SO3 ca 48-50%(26412-87-3)
[Sigma Aldrich]

26412-87-3(sigmaaldrich)
[TCI AMERICA]

Pyridine-Sulfur Trioxide Complex,>92.0%(T)(26412-87-3)
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