| Identification | More | [Name]
Thiobencarb | [CAS]
28249-77-6 | [Synonyms]
4-chlorobenzyl diethylthiolcarbamate
4-Chlorobenzyl N,N-diethylthiocarbamate
BENTHIOCARB
Benthiocarb granulesBenthiocarb
BIGTURN
BOLERO
Bolero Hydram
BOLERO(R)
Molinate(content>25%)
Morinate
S-(4-CHLOROBENZYL)-N,N-(DIETHYL)-THIOCARBAMATE
S-(4-CHLOROPHENYL)METHYL DIETHYL-CARBAMOTHIOATE
SATURN
SATURN 90
Saturn granules
SATURNO(R)
SATURN(R)
SIACARB
THIOBENCARB
Thiobencarb granules | [EINECS(EC#)]
248-924-5 | [Molecular Formula]
C12H16ClNOS | [MDL Number]
MFCD00055475 | [Molecular Weight]
257.78 | [MOL File]
28249-77-6.mol |
| Chemical Properties | Back Directory | [Appearance]
Amber-colored, slightly water-soluble,
liquid.
| [Melting point ]
1.7°C | [Boiling point ]
126-129°C | [density ]
1.0756 (rough estimate) | [refractive index ]
1.5630 (estimate) | [storage temp. ]
APPROX 4°C
| [solubility ]
Chloroform (Slightly), DMSO (Slightly), Methanol (Slightly) | [form ]
Liquid | [pka]
-1.26±0.70(Predicted) | [color ]
Pale yellow | [Water Solubility ]
30mg/L(22 ºC) | [BRN ]
1968440 | [Henry's Law Constant]
1.9×101 mol/(m3Pa) at 25℃, Watanabe (1993) | [Major Application]
agriculture
environmental | [InChI]
InChI=1S/C12H16ClNOS/c1-3-14(4-2)12(15)16-9-10-5-7-11(13)8-6-10/h5-8H,3-4,9H2,1-2H3 | [InChIKey]
QHTQREMOGMZHJV-UHFFFAOYSA-N | [SMILES]
C(SCC1=CC=C(Cl)C=C1)(=O)N(CC)CC | [Uses]
Thiocarbamate herbicide used to control sedges
and grasses in rice paddies.
| [CAS DataBase Reference]
28249-77-6(CAS DataBase Reference) | [NIST Chemistry Reference]
Benthiocarb(28249-77-6) | [EPA Substance Registry System]
28249-77-6(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,N,Xn | [Risk Statements ]
R22:Harmful if swallowed.
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 3082 | [WGK Germany ]
3 | [RTECS ]
EZ7260000 | [HS Code ]
29302000 | [Storage Class]
10 - Combustible liquids | [Hazard Classifications]
Acute Tox. 4 Oral
Aquatic Acute 1
Aquatic Chronic 1 | [Hazardous Substances Data]
28249-77-6(Hazardous Substances Data) | [Toxicity]
chicken,LD50,oral,673mg/kg (673mg/kg),Japan Pesticide Information. Vol. (19), Pg. 21, 1974. |
| Hazard Information | Back Directory | [General Description]
Pale yellow to brownish yellow liquid. Non corrosive. Used as an herbicide. | [Reactivity Profile]
THIOBENCARB(28249-77-6) is a thiocarbamate. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides. | [Air & Water Reactions]
Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. | [Hazard]
Toxic. | [Chemical Properties]
Amber-colored, slightly water-soluble,
liquid.
| [Definition]
ChEBI: Thiobencarb is a member of monochlorobenzenes and a monothiocarbamic ester. | [Production Methods]
Thiobencarb is produced commercially through a multi-step synthesis that constructs its thiocarbamate herbicidal structure. The process begins with the preparation of diethylthiocarbamic acid, which is then esterified with 4-chlorobenzyl chloride to form S-(4-chlorobenzyl) diethylthiocarbamate, the active thiobencarb molecule. This reaction is typically carried out under controlled temperature and pH conditions to ensure high yield and purity. The final product is then purified and formulated. | [Mechanism of action]
Selective. Acetyl CoA carboxylase inhibitor (ACCase) - distrupts fatty acid biosynthesis and lipid formation. | [Pesticide Type]
Herbicide |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Spectrum Chemical Manufacturing Corp.
|
| Telephone: |
021-021-021-67601398-809-809-809 15221380277 |
| Website: |
www.spectrumchemical.com/oa_html/index.jsp?minisite=10020&respid=22372&language=us |
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