| Identification | More | [Name]
Isocyanatocyclohexane | [CAS]
3173-53-3 | [Synonyms]
CYCLOHEXYL ISOCYANATE
Isocyanatocyclohexane
ISOCYANIC ACID CYCLOHEXYL ESTER
Isocyanic acid，cyelohexyl ester
chi
Cyclohexane, isocyanato-
cyclohexane,isocyanato-
cyclohexyl
Cyclohexyl ester of isocyanic acid
cyclohexylisocyanate(isocyanatocyclohexane)
isocyanato-cyclohexan
NSC 87419
nsc87419
Cyclohexyl #niso-cyanate
Cyclohexylisocyanate,98%
CYCLOHEXYL ISOCYANATE 98%
Isocyanatocyclohexane Isocyanic acid cyclohexyl ester CHI | [EINECS(EC#)]
221-639-3 | [Molecular Formula]
C7H11NO | [MDL Number]
MFCD00003840 | [Molecular Weight]
125.17 | [MOL File]
3173-53-3.mol |
| Chemical Properties | Back Directory | [Appearance]
Cyclohexyl isocyanate is a clear, flammable
liquid. It has a sharp, pungent odor. | [Melting point ]
-80 °C
| [Boiling point ]
168-170 °C(lit.)
| [density ]
0.98 g/mL at 25 °C(lit.)
| [vapor pressure ]
1.83 psi ( 20 °C)
| [refractive index ]
n20/D 1.455(lit.)
| [Fp ]
120 °F
| [storage temp. ]
Flammables area | [solubility ]
Chloroform (Sparingly) | [form ]
Liquid | [color ]
Clear colorless to light amber | [Odor]
sharp pungent odor | [Stability:]
Stability Flammable. Incompatible with water, strong oxidizing agents, alcohols, strong bases, amines, acids, copper alloys, aluminium. May polymerize if exposed to moisture. | [Water Solubility ]
decomposes | [Sensitive ]
Moisture Sensitive | [BRN ]
507983 | [Henry's Law Constant]
5.8×10-3 mol/(m3Pa) at 25℃, HSDB (2015) | [Exposure limits]
ACGIH: TWA 25 ppm; STEL 50 ppm
OSHA: Ceiling 50 ppm(300 mg/m3)
NIOSH: IDLH 200 ppm; Ceiling 50 ppm(300 mg/m3) | [InChI]
1S/C7H11NO/c9-6-8-7-4-2-1-3-5-7/h7H,1-5H2 | [InChIKey]
KQWGXHWJMSMDJJ-UHFFFAOYSA-N | [SMILES]
O=C=NC1CCCCC1 | [CAS DataBase Reference]
3173-53-3(CAS DataBase Reference) | [NIST Chemistry Reference]
Cyclohexylisocyanate(3173-53-3) | [EPA Substance Registry System]
Cyclohexyl isocyanate (3173-53-3) |
| Safety Data | Back Directory | [Symbol(GHS) ]
  
GHS02,GHS06,GHS08 | [Signal word ]
Danger | [Hazard statements ]
H226-H302+H312-H315-H317-H319-H330-H334-H335 | [Precautionary statements ]
P210-P280-P301+P312+P330-P302+P352+P312-P304+P340+P310-P305+P351+P338 | [Hazard Codes ]
T+,N | [Risk Statements ]
R10:Flammable.
R21/22:Harmful in contact with skin and if swallowed .
R26:Very Toxic by inhalation.
R36/37/38:Irritating to eyes, respiratory system and skin .
R42:May cause sensitization by inhalation.
R50:Very Toxic to aquatic organisms.
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37:Wear suitable protective clothing and gloves .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S57:Use appropriate container to avoid environmental contamination .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S29:Do not empty into drains .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S16:Keep away from sources of ignition-No smoking . | [RIDADR ]
UN 2488 6.1/PG 1
| [WGK Germany ]
2
| [RTECS ]
NQ8650000
| [F ]
10-19-21 | [TSCA ]
Yes | [REACH Registrations]
Active | [HazardClass ]
6.1 | [PackingGroup ]
I | [HS Code ]
29291090 | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Acute Tox. 2 Inhalation
Acute Tox. 4 Dermal
Acute Tox. 4 Oral
Eye Irrit. 2
Flam. Liq. 3
Resp. Sens. 1
Skin Irrit. 2
Skin Sens. 1
STOT SE 3 | [Safety Profile]
Poison by intravenous
and intraperitoneal routes. Mutation data
reported. A flammable liquid when exposed
to heat or flame. When heated to
decomposition it emits toxic fumes of NOx.
See also CYANATES and ESTERS.
| [Hazardous Substances Data]
3173-53-3(Hazardous Substances Data) |
| Hazard Information | Back Directory | [General Description]
A yellowish liquid with an irritating odor. Insoluble in water. Flash point 127°F. Very toxic by inhalation, skin absorption and ingestion. Used to make pharmaceuticals and agricultural chemicals. | [Reactivity Profile]
Isocyanates and thioisocyanates are incompatible with many classes of compounds, reacting exothermically to release toxic gases. Reactions with amines, aldehydes, alcohols, alkali metals, ketones, mercaptans, strong oxidizers, hydrides, phenols, and peroxides can cause vigorous releases of heat. Acids and bases initiate polymerization reactions in these materials. Some isocyanates react with water to form amines and liberate carbon dioxide. Base-catalysed reactions of isocyanates with alcohols should be carried out in inert solvents. Such reactions in the absence of solvents often occur with explosive violence [Wischmeyer 1969]. | [Air & Water Reactions]
Flammable. Insoluble in water. Reacts slowly with water to form the amine and CO2. | [Health Hazard]
TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Bromoacetates and chloroacetates are extremely irritating/lachrymators. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. | [Potential Exposure]
The material is used in the synthesis
of agricultural chemicals. | [Fire Hazard]
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water. | [Shipping]
UN2488 Cyclohexyl isocyanate, Hazard class:
6.1; Labels: 6.1-Poison Inhalation Hazard, 3-Flammable
liquid, Inhalation Hazard Zone B. | [Description]
Cyclohexyl isocyanate is a clear, flammableliquid. It has a sharp, pungent odor. Molecularweight=125.19; Specific gravity (H2O:1): 0.98; Boilingpoint=168℃; Flash point=48℃ (cc). HazardIdentification (based on NFPA-704 M Rating System):Health 2, Flammability 2, Reactivity 0. Soluble in water(reaction). | [Chemical Properties]
colourless or light yellow liquid | [Chemical Properties]
Cyclohexyl isocyanate is a clear, flammable
liquid. It has a sharp, pungent odor. | [Uses]
Cyclohexyl Isocyanate reacts with isoquinoline to prepare of Gliquidone through condensation reaction in a solvent under the action of base. | [Definition]
ChEBI: An isocyanate comprising a cyclohexane core with a single isocyanato substituent. | [First aid]
If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least30 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.Medical observation is recommended for 24-48 h afterbreathing overexposure, as pulmonary edema may bedelayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a corticosteroid spray. | [storage]
Color Code—Red: Flammability Hazard: Store ina flammable liquid storage area or approved cabinet awayfrom ignition sources and corrosive and reactive materials.Color Code—Blue: Health Hazard/Poison: Store in a securepoison location. Prior to working with cyclohexyl isocyanate you should be trained on its proper handling and storage. Cyclohexyl isocyanate must be stored to avoid contactwith moisture and temperatures above 93℃, since violentreactions occur. Store in tightly closed containers in a cool,well-ventilated area away from water, strong bases, alcohol,metal compounds, or surface-active materials. Use onlynonsparking tools and equipment, especially when openingand closing containers of this chemical. Sources of ignition,such as smoking and open flames, are prohibited where thischemical is used, handled, or stored in a manner that couldcreate a potential fire or explosion hazard | [Incompatibilities]
Cyclohexyl isocyanate polymerize due toheating above 93℃/200°F and under the influence of various chemicals including organometallic compounds.Cyclohexyl isocyanate decomposes in fire, forming toxichydrogen cyanide and nitrogen oxides fumes. Reacts withoxidizers, strong bases, water, alcohol, acids, amines, metalcompounds, surface-active materials |
|
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Jia Xing Isenchem Co.,Ltd
|
| Telephone: |
0573-85285100 18627885956 |
| Website: |
https://www.chemicalbook.com/ShowSupplierProductsList14265/0_EN.htm |
| Company Name: |
China Langchem Inc.
|
| Telephone: |
0086-21-58956006 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList19141/0_EN.htm |
| Company Name: |
Maya High Purity Chemicals
|
| Telephone: |
+86 (573) 82222445 (0)18006601000 452520369 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList15221/0_EN.htm |
| Company Name: |
T&W GROUP
|
| Telephone: |
021-61551611 13296011611 |
| Website: |
www.trustwe.com/ |
|