| Identification | More | [Name]
3-Bromo-2-(bromomethyl)propionic acid | [CAS]
41459-42-1 | [Synonyms]
3-BROMO-2-(BROMOMETHYL)PROPANOIC ACID
3-BROMO-2-(BROMOMETHYL)PROPIONIC ACID
BETA,BETA'-DIBROMOISOBUTYRIC ACID
Propanoic acid, 3-bromo-2-(bromomethyl)-
3-BROMO-2-(BROMOMETHYL)PROPIONIC ACID, 9 7%
bis(bromomethyl)acetic acid
β,β'-dibromoisobutyric acid
3-BROMO-2-(BROMOMETHYL)PROPIONIC ACID (KG LEVEL) | [Molecular Formula]
C4H6Br2O2 | [MDL Number]
MFCD00010643 | [Molecular Weight]
245.9 | [MOL File]
41459-42-1.mol |
| Chemical Properties | Back Directory | [Appearance]
off-white to brown crystalline powder | [Melting point ]
98-101 °C(lit.) | [Boiling point ]
286.7±30.0 °C(Predicted) | [density ]
2.121±0.06 g/cm3(Predicted) | [storage temp. ]
2-8°C
| [solubility ]
Soluble in acetic acid. | [form ]
Crystalline Powder | [pka]
3.33±0.11(Predicted) | [color ]
Off-white to brown | [BRN ]
1752505 | [InChI]
InChI=1S/C4H6Br2O2/c5-1-3(2-6)4(7)8/h3H,1-2H2,(H,7,8) | [InChIKey]
QQZJWQCLWOQDQV-UHFFFAOYSA-N | [SMILES]
C(O)(=O)C(CBr)CBr | [CAS DataBase Reference]
41459-42-1(CAS DataBase Reference) | [NIST Chemistry Reference]
Propionic acid, 3-bromo-2-(bromomethyl)-(41459-42-1) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3261 8/PG 2
| [WGK Germany ]
3
| [F ]
8 | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29159000 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Skin Corr. 1B |
| Hazard Information | Back Directory | [Chemical Properties]
off-white to brown crystalline powder | [Uses]
3-Bromo-2-(bromomethyl)propionic acid acts as an organic building block for the preparation of beta-substituted acrylates. It is used in the preparation of t-butyl 2-(phenylthiomethyl) propenoate, t-butyl 3-(phenylthio)-2-(phenylthiomethyl)propenoate and 3-(phenylthio)-2-(phenyl-sulfinylmethyl)propenoate. Further, it plays an important role in the synthesis of beta-lactams by cyclization of the corresponding amide. | [General Description]
3-Bromo-2-(bromomethyl)propionic acid reacts with alkaline arsenite to yield (RS)-3-arsono-2-(hydroxymethyl)propionic acid. | [Synthesis]
A mixture of commercially available diethyl bis(hydroxymethyl)malonate (25 g., 0.11 mol.) and a 48%
aqueous hydrogen bromide solution (192 cm3, 1.70 mol) was heated until the ethyl bromide liquid began to evaporate from the mixture and then vigorously di |
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