ChemicalBook--->CAS DataBase List--->428-59-1

428-59-1

428-59-1 Structure

428-59-1 Structure
IdentificationMore
[Name]

Hexafluoropropylene oxide
[CAS]

428-59-1
[Synonyms]

1,2-epoxy-1,1,2,3,3,3-hexafluoropropane
HEXAFLUORO-1,2-EPOXYPROPANE
HEXAFLUOROEPOXYPROPANE
HEXAFLUOROPROPENE OXIDE
HEXAFLUOROPROPYLENE OXIDE
HFPO
trifluoro(trifluoromethyl)oxirane
(Trifluoromethyl)trifluorooxirane
1,2-epoxy-1,1,2,3,3,3-hexafluoro-propan
2,2,3-Trifluoro-3-(trifluoromethyl)oxirane
Hexafluoropropene epoxide
hexafluoropropeneepoxide
Hexafluoropropylene epoxide
hexafluoropropyleneepoxide
hexafluoropropyleneoxide(hfpo)
NA 1956
Perfluoro(methyloxirane)
Perfluoropropylene oxide
perfluoropropyleneoxide
Propane, 1,2-epoxy-1,1,2,3,3,3-hexafluoro-
[EINECS(EC#)]

207-050-4
[Molecular Formula]

C3F6O
[MDL Number]

MFCD00005125
[Molecular Weight]

166.02
[MOL File]

428-59-1.mol
Chemical PropertiesBack Directory
[Melting point ]

-129°C
[Boiling point ]

−42 °C(lit.)
[density ]

1.67±0.1 g/cm3(Predicted)
[vapor pressure ]

680.85kPa at 25℃
[Water Solubility ]

16.3μg/L at 22.7℃
[Henry's Law Constant]

9.3×10-6 mol/(m3Pa) at 25℃, Clever et al. (2005)
[InChI]

InChI=1S/C3F6O/c4-1(2(5,6)7)3(8,9)10-1
[InChIKey]

PGFXOWRDDHCDTE-UHFFFAOYSA-N
[SMILES]

O1C(F)(C(F)(F)F)C1(F)F
[LogP]

1.72 at 25℃
[CAS DataBase Reference]

428-59-1(CAS DataBase Reference)
[NIST Chemistry Reference]

Oxirane, trifluoro(trifluoromethyl)-(428-59-1)
[EPA Substance Registry System]

428-59-1(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Flame (GHS02)
GHS05,GHS02
[Signal word ]

Danger
[Hazard statements ]

H314-H225-H290
[Precautionary statements ]

P501-P240-P210-P233-P234-P243-P241-P242-P264-P280-P370+P378-P390-P303+P361+P353-P301+P330+P331-P363-P304+P340+P310-P305+P351+P338+P310-P403+P235-P406-P405
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R44:Risk of explosion if heated under confinement.
[Safety Statements ]

S7:Keep container tightly closed .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
S38:In case of insufficient ventilation, wear suitable respiratory equipment .
[RIDADR ]

UN 1956 2.2
[WGK Germany ]

3
[Hazard Note ]

Irritant
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[HazardClass ]

2.2
[Hazardous Substances Data]

428-59-1(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

PERFLUOROPROPANE-->Hexafluoropropylene
[Preparation Products]

Hexafluoroacetone-->METHYL PERFLUORO(2-METHYL-3-OXAHEXANOATE)-->HEPTAFLUORO-1-METHOXYPROPANE-->2,2-Bis(4-methylphenyl)hexafluoropropane
Hazard InformationBack Directory
[General Description]

HEXAFLUOROPROPYLENE OXIDE(428-59-1) is a colorless odorless gas. HEXAFLUOROPROPYLENE OXIDE(428-59-1) is shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. Its vapors are heavier than air. HEXAFLUOROPROPYLENE OXIDE(428-59-1) can cause asphyxiation by the displacement of air. Exposure of the container to prolonged heat or fire may cause HEXAFLUOROPROPYLENE OXIDE(428-59-1) to rupture violently and rocket.
[Reactivity Profile]

HEXAFLUOROPROPYLENE OXIDE is a chlorinated epoxide. Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.
[Health Hazard]

Vapors may cause dizziness or asphyxiation without warning. Vapors from liquefied gas are initially heavier than air and spread along ground. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Fire may produce irritating, corrosive and/or toxic gases.
[Fire Hazard]

Some may burn but none ignite readily. Containers may explode when heated. Ruptured cylinders may rocket.
[Uses]

Hexafluoropropylene oxide is an important intermediate of organic fluorine material.HFPO is mainly used in the manufacture of high-quality fluorinated compounds.It is the main component of perfluor-vinyl ether(PPVE,PSVE,PFVE,PMVE) and the monomer of fluorinated surfactants and fluorinated ether oil.
[Flammability and Explosibility]

Nonflammable
[Synthesis]

There are various methods for the production of Hexafluoropropylene oxide, mainly including organic peroxide oxidation, electrochemical oxidation, molecular oxygen direct oxidation, carbonate-chlorine oxidation, nucleophilic oxidation and so on. Among the
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Hexafluoropropylene oxide(428-59-1).msds
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

428-59-1(sigmaaldrich)
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