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535-13-7

535-13-7 Structure

535-13-7 Structure
IdentificationMore
[Name]

Ethyl 2-chloropropionate
[CAS]

535-13-7
[Synonyms]

2-CHLOROPROPIONIC ACID ETHYL ESTER
ETHYL 2-CHLOROPROPIONATE
ETHYL ALPHA-CHLOROPROPIONATE
2-chloropropanoicacid,ethylester
2-chloro-propanoicaciethylester
Ethyl 2-chloropropanoate
ethyl2-chloropropanoate
Propanoic acid, 2-chloro-, ethyl ester
Propanoicacid,2-chloro-,ethylester
Propionic acid, 2-chloro-, ethyl ester
propionicacid,2-chloro-,ethylester
3-Nitrosalicyclic Acid
ethyl-2-chloropropionic acid
Ethyl 2-Chloropropionate 2-
ETHYL 2-CHLOROPROPIONATE pract
2-Chloropropionic acid ethyl
NSC-522671
[EINECS(EC#)]

208-610-0
[Molecular Formula]

C5H9ClO2
[MDL Number]

MFCD00000864
[Molecular Weight]

136.58
[MOL File]

535-13-7.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless liquid
[Appearance]

Ethyl-2-chloropropionate is a liquid with a pleasant odor
[bp ]

146-149 °C(lit.)
[density ]

1.072 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.417(lit.)
[Fp ]

101 °F
[storage temp. ]

Flammables area
[Water Solubility ]

immiscible
[Merck ]

14,3785
[BRN ]

773906
[CAS DataBase Reference]

535-13-7(CAS DataBase Reference)
[NIST Chemistry Reference]

Ethyl 2-chloropropionate(535-13-7)
[EPA Substance Registry System]

535-13-7(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
S16:Keep away from sources of ignition-No smoking .
[RIDADR ]

UN 2935 3/PG 3
[WGK Germany ]

3
[HazardClass ]

3
[PackingGroup ]

III
[HS Code ]

29159000
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Propionic acid-->Methyl propionate
[Preparation Products]

FENOXAPROP-P-ETHYL-->2-METHYLBENZOFURAN-->2-(2-FORMYL-PHENOXY)-PROPIONIC ACID
Hazard InformationBack Directory
[General Description]

A clear colorless liquid with a pungent odor. Flash point of 100°F. Denser than water and insoluble in water. Vapors are heavier than air.
[Reactivity Profile]

ETHYL 2-CHLOROPROPIONATE(535-13-7) is a halogenated ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
[Air & Water Reactions]

Highly flammable. Insoluble in water.
[Health Hazard]

May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
[Potential Exposure]

This material is used in organic synthesis.
[Fire Hazard]

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. As first aid for pulmonary edema, a doctor or authorized paramedic may consider administering a drug or other inhalation therapy.
[Shipping]

UN2935 Ethyl 2-chloropropionate, Hazard Class: 3; Labels: 3-Flammable liquid.
[Incompatibilities]

Flammable liquid; forms explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, and reducing agents. Esters are generally incompatible with nitrates. Moisture may cause hydrolysis or other forms of decomposition. Esters react with acids releasing heat in addition to alcohols and acids. Contact with caustic solutions generate heat. Contact with esters with alkali metals and hydrides releases flammable hydrogen.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

ethyl-2-chloropropionate(535-13-7).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Ethyl 2-chloropropionate(535-13-7)IR1
Ethyl 2-chloropropionate(535-13-7)Raman
Ethyl 2-chloropropionate(535-13-7)1HNMR
Ethyl 2-chloropropionate(535-13-7)IR2
Ethyl 2-chloropropionate(535-13-7)MS
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Ethyl 2-chloropropionate, 97%(535-13-7)
[Alfa Aesar]

Ethyl 2-chloropropionate, 97%(535-13-7)
[Sigma Aldrich]

535-13-7(sigmaaldrich)
[TCI AMERICA]

Ethyl 2-Chloropropionate,>95.0%(GC)(535-13-7)
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