| Identification | More | [Name]
Ethyl 2-chloropropionate | [CAS]
535-13-7 | [Synonyms]
2-CHLOROPROPIONIC ACID ETHYL ESTER
ETHYL 2-CHLOROPROPIONATE
ETHYL ALPHA-CHLOROPROPIONATE
2-chloropropanoicacid,ethylester
2-chloro-propanoicaciethylester
Ethyl 2-chloropropanoate
ethyl2-chloropropanoate
Propanoic acid, 2-chloro-, ethyl ester
Propanoicacid,2-chloro-,ethylester
Propionic acid, 2-chloro-, ethyl ester
propionicacid,2-chloro-,ethylester
3-Nitrosalicyclic Acid
ethyl-2-chloropropionic acid
Ethyl 2-Chloropropionate 2-
ETHYL 2-CHLOROPROPIONATE pract
2-Chloropropionic acid ethyl
NSC-522671 | [EINECS(EC#)]
208-610-0 | [Molecular Formula]
C5H9ClO2 | [MDL Number]
MFCD00000864 | [Molecular Weight]
136.58 | [MOL File]
535-13-7.mol |
| Chemical Properties | Back Directory | [Appearance]
Ethyl-2-chloropropionate is a liquid with a
pleasant odor | [Boiling point ]
146-149 °C (lit.) | [density ]
1.072 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.417(lit.)
| [Fp ]
101 °F
| [storage temp. ]
Flammables area | [solubility ]
alcohol: miscible | [form ]
clear liquid | [color ]
Colorless to Light yellow | [Specific Gravity]
1.085 (20/4℃) | [Water Solubility ]
immiscible | [Merck ]
14,3785 | [BRN ]
773906 | [Dielectric constant]
10.1 | [LogP]
1.382 (est) | [CAS DataBase Reference]
535-13-7(CAS DataBase Reference) | [NIST Chemistry Reference]
Ethyl 2-chloropropionate(535-13-7) | [EPA Substance Registry System]
535-13-7(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection .
S16:Keep away from sources of ignition-No smoking . | [RIDADR ]
UN 2935 3/PG 3
| [WGK Germany ]
3
| [TSCA ]
Yes | [HazardClass ]
3 | [PackingGroup ]
III | [HS Code ]
29159000 |
| Hazard Information | Back Directory | [General Description]
A clear colorless liquid with a pungent odor. Flash point of 100°F. Denser than water and insoluble in water. Vapors are heavier than air. | [Reactivity Profile]
ETHYL 2-CHLOROPROPIONATE(535-13-7) is a halogenated ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. | [Air & Water Reactions]
Highly flammable. Insoluble in water. | [Health Hazard]
May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. | [Potential Exposure]
This material is used in organic
synthesis. | [Fire Hazard]
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water. | [First aid]
If this chemical gets into the eyes, remove any
contact lenses at once and irrigate immediately for at least
15 minutes, occasionally lifting upper and lower lids. Seek
medical attention immediately. If this chemical contacts the
skin, remove contaminated clothing and wash immediately
with soap and water. Seek medical attention immediately.
If this chemical has been inhaled, remove from exposure,
begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if
heart action has stopped. Transfer promptly to a medical
facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce
vomiting. Do not make an unconscious person vomit.
Medical observation is recommended for 24 to 48 hours
after breathing overexposure, as pulmonary edema may be
delayed. As first aid for pulmonary edema, a doctor or
authorized paramedic may consider administering a drug or
other inhalation therapy. | [Shipping]
UN2935 Ethyl 2-chloropropionate, Hazard
Class: 3; Labels: 3-Flammable liquid. | [Incompatibilities]
Flammable liquid; forms explosive mixture with air. Incompatible with oxidizers (chlorates,
nitrates, peroxides, permanganates, perchlorates, chlorine,
bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases,
strong acids, oxoacids, epoxides, and reducing agents.
Esters are generally incompatible with nitrates. Moisture
may cause hydrolysis or other forms of decomposition.
Esters react with acids releasing heat in addition to alcohols
and acids. Contact with caustic solutions generate heat.
Contact with esters with alkali metals and hydrides releases
flammable hydrogen. | [Description]
Ethyl-2-chloropropionate is a liquid with apleasant odor. Molecular weight = 136.8; Boilingpoint = 147℃; Flash point = 41.8℃ | [Chemical Properties]
clear colorless liquid | [Chemical Properties]
Ethyl-2-chloropropionate is a liquid with a
pleasant odor | [Uses]
Ethyl 2-chloropropionate was used as initiator during the synthesis of poly(2-(diethylamino)ethyl methacrylate) and poly(N-isopropylacrylamide) via atom transfer radical polymerization. It was also used in the synthesis of end-functionalized poly(N-isopropylacrylamide) with pyrenyl group. | [storage]
Color Code—Red: Flammability Hazard: Store in aflammable liquid storage area or approved cabinet awayfrom ignition sources and corrosive and reactive materials.Prior to working with this chemical you should be trained onits proper handling and storage. Store in tightly closed containers in a cool, well-ventilated area away from acids, bases,oxidizing and reducing agents. Sources of ignition, such assmoking and open flames, are prohibited where ethyl-2-chloropropionate is used, handled, or stored in a manner thatcould create a potential fire or explosion hazard |
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