ChemicalBook--->CAS DataBase List--->56613-80-0

56613-80-0

56613-80-0 Structure

56613-80-0 Structure
IdentificationMore
[Name]

D-Plenylglycinol
[CAS]

56613-80-0
[Synonyms]

BENZENEETHANOL, B-AMINO-, (BR)-
BETA-(R)-AMINO-BENZENEETHANOL
D-(-)2-AMINO-2-PHENYLETHANOL
D(-)-ALPHA-PHENYLGLYCINOL
D-(-)-A-PHENYLGLYCINOL
(-)-D-PHENYLGLYCINOL
D-PHENYLGLYCINOL
D-PHG-OL
d-plenylglycinol
H-D-PHG-OL
(R)-(-)-2-AMINO-2-PHENYLETHANOL
(R)-2-AMINO-2-PHENYLETHANOL
(R)-(-)-2-PHENYLGLYCINOL
(R)-2-PHENYLGLYCINOL
(R)-(-)-ALPHA-PHENYLGLYCINOL
(R)-b-Aminophenethyl alcohol
(R)-(-)-PHENYLGLYCINOL
(R)-PHENYLGLYCINOL
Benzeneethanol, beta-amino-, (R)-
(R)-(-)-2-Amino-2-phenylethanol~H-D-Phg-ol
[EINECS(EC#)]

260-287-5
[Molecular Formula]

C8H11NO
[MDL Number]

MFCD00008062
[Molecular Weight]

137.18
[MOL File]

56613-80-0.mol
Chemical PropertiesBack Directory
[Appearance]

white to light yellow crystal powde
[Melting point ]

76-79 °C
[alpha ]

-25.5 º (c=6,MeOH)
[Boiling point ]

252.03°C (rough estimate)
[density ]

1.0630 (rough estimate)
[refractive index ]

-29.5 ° (C=1, EtOH)
[storage temp. ]

Store at 0-5°C
[solubility ]

Aqueous Acid (Slightly, Sonicated), Chloroform (Sparingly, Heated), Methanol (Slightly)
[form ]

Crystalline Powder
[pka]

12.51±0.10(Predicted)
[color ]

White to yellow
[Optical Rotation]

[α]24/D 31.7°, c = 0.76 in 1 M HCl
[Water Solubility ]

Slightly soluble in water.
[Sensitive ]

Air Sensitive
[Detection Methods]

GC,NMR
[BRN ]

2935848
[Major Application]

peptide synthesis
[InChI]

1S/C8H11NO/c9-8(6-10)7-4-2-1-3-5-7/h1-5,8,10H,6,9H2/t8-/m0/s1
[InChIKey]

IJXJGQCXFSSHNL-QMMMGPOBSA-N
[SMILES]

N[C@@H](CO)c1ccccc1
[CAS DataBase Reference]

56613-80-0(CAS DataBase Reference)
[NIST Chemistry Reference]

(R)-(-)-2-phenylglycinol(56613-80-0)
[Storage Precautions]

Store under nitrogen
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P280a-P304+P340-P305+P351+P338-P405-P501a
[Hazard Codes ]

C,T
[Risk Statements ]

R34:Causes burns.
R36/37/38:Irritating to eyes, respiratory system and skin .
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

3
[F ]

2-10
[REACH Registrations]

Active
[HS Code ]

29221980
[Storage Class]

11 - Combustible Solids
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Tetrahydrofuran-->Sodium borohydride-->D-2-Phenylglycine
[Preparation Products]

(R)-(+)-1-(1-Naphthyl)ethylamine-->R)-3-phenyl piperidine-->2,6-Bis[(4R)-4-phenyl-2-oxazolinyl]pyridine-->Benzenesulfonamide, 4-methyl-N-[(1R)-2-[[(4-methylphenyl)sulfonyl]oxy]-1-phenylethyl]--->(R )-(2-Amino-1-phenyl-ethyl)-carbamic acid benzyl ester-->(5R)-N-(tert-Butoxycarbonyl)-3,4,5,6-tetrahydro-5-phenyl-4(H)-1,4-oxazin-2-one
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

(R)-(-)-2-Phenylglycinol(56613-80-0).msds
Hazard InformationBack Directory
[Chemical Properties]

white to light yellow crystal powder.
[Uses]

A chiral arylalkylamine used as organocatalysts. Used in the synthesis and chiral recognition properties of novel fluorescent chemosensors for amino acid.
[Definition]

ChEBI: (R)-(-)-2-Phenylglycinol is an aralkylamine.
[Preparation]

D-Phenylglycinol was synthesized by reducing D-phenylglycine using a sodium borohydride-iodine system. The best reaction conditions were using tetrahydrofuran as the solvent, a 1:2 ratio of D-phenylglycine to sodium borohydride, a hydrolysis temperature of 50°C, and a reaction time of 20 hours.
[reaction suitability]

reaction type: solution phase peptide synthesis
Spectrum DetailBack Directory
[Spectrum Detail]

D-Plenylglycinol(56613-80-0)1HNMR
D-Plenylglycinol(56613-80-0)FT-IR
D-Plenylglycinol(56613-80-0)Raman
D-Plenylglycinol(56613-80-0)IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

(R)-(-)-2-Phenylglycinol, 98%(56613-80-0)
[Alfa Aesar]

(R)-(-)-2-Phenylglycinol, 98%(56613-80-0)
[Sigma Aldrich]

56613-80-0(sigmaaldrich)
[TCI AMERICA]

(R)-(-)-2-Phenylglycinol,>98.0%(GC)(T)(56613-80-0)
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