| Identification | More | [Name]
D-Plenylglycinol | [CAS]
56613-80-0 | [Synonyms]
BENZENEETHANOL, B-AMINO-, (BR)-
BETA-(R)-AMINO-BENZENEETHANOL
D-(-)2-AMINO-2-PHENYLETHANOL
D(-)-ALPHA-PHENYLGLYCINOL
D-(-)-A-PHENYLGLYCINOL
(-)-D-PHENYLGLYCINOL
D-PHENYLGLYCINOL
D-PHG-OL
d-plenylglycinol
H-D-PHG-OL
(R)-(-)-2-AMINO-2-PHENYLETHANOL
(R)-2-AMINO-2-PHENYLETHANOL
(R)-(-)-2-PHENYLGLYCINOL
(R)-2-PHENYLGLYCINOL
(R)-(-)-ALPHA-PHENYLGLYCINOL
(R)-b-Aminophenethyl alcohol
(R)-(-)-PHENYLGLYCINOL
(R)-PHENYLGLYCINOL
Benzeneethanol, beta-amino-, (R)-
(R)-(-)-2-Amino-2-phenylethanol~H-D-Phg-ol | [EINECS(EC#)]
260-287-5 | [Molecular Formula]
C8H11NO | [MDL Number]
MFCD00008062 | [Molecular Weight]
137.18 | [MOL File]
56613-80-0.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powde | [Melting point ]
76-79 °C | [alpha ]
-25.5 º (c=6,MeOH) | [Boiling point ]
252.03°C (rough estimate) | [density ]
1.0630 (rough estimate) | [refractive index ]
-29.5 ° (C=1, EtOH) | [storage temp. ]
Store at 0-5°C | [solubility ]
Aqueous Acid (Slightly, Sonicated), Chloroform (Sparingly, Heated), Methanol (Slightly) | [form ]
Crystalline Powder | [pka]
12.51±0.10(Predicted) | [color ]
White to yellow | [Optical Rotation]
[α]24/D 31.7°, c = 0.76 in 1 M HCl | [Water Solubility ]
Slightly soluble in water. | [Sensitive ]
Air Sensitive | [Detection Methods]
GC,NMR | [BRN ]
2935848 | [Major Application]
peptide synthesis | [InChI]
1S/C8H11NO/c9-8(6-10)7-4-2-1-3-5-7/h1-5,8,10H,6,9H2/t8-/m0/s1 | [InChIKey]
IJXJGQCXFSSHNL-QMMMGPOBSA-N | [SMILES]
N[C@@H](CO)c1ccccc1 | [CAS DataBase Reference]
56613-80-0(CAS DataBase Reference) | [NIST Chemistry Reference]
(R)-(-)-2-phenylglycinol(56613-80-0) | [Storage Precautions]
Store under nitrogen |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335 | [Precautionary statements ]
P261-P280a-P304+P340-P305+P351+P338-P405-P501a | [Hazard Codes ]
C,T | [Risk Statements ]
R34:Causes burns.
R36/37/38:Irritating to eyes, respiratory system and skin .
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [WGK Germany ]
3
| [F ]
2-10 | [HS Code ]
29221980 | [Storage Class]
11 - Combustible Solids |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powder. | [Uses]
A chiral arylalkylamine used as organocatalysts. Used in the synthesis and chiral recognition properties of novel fluorescent chemosensors for amino acid. | [Definition]
ChEBI: (R)-(-)-2-Phenylglycinol is an aralkylamine. | [Preparation]
D-Phenylglycinol was synthesized by reducing D-phenylglycine using a sodium borohydride-iodine system. The best reaction conditions were using tetrahydrofuran as the solvent, a 1:2 ratio of D-phenylglycine to sodium borohydride, a hydrolysis temperature of 50°C, and a reaction time of 20 hours. | [reaction suitability]
reaction type: solution phase peptide synthesis |
|
|