| Identification | More | [Name]
Cylopropylmethyl chloride | [CAS]
5911-08-0 | [Synonyms]
(CHLOROMETHYL)CYCLOPROPANE
CYCLOPROPYLMETHYL CHLORIDE
Cyclopropane, (chloromethyl)-
Cyclopropane,(chloromethyl)-
Cylopropylmethylchloride
Cyclopropylmethychloride
Cyclopropylmethyl Chloride, Pract.
CPMCl
1-(Chloromethyl)cyclopropane
a-(Chloromethyl)cyclopropane
(Chloromethyl)cyclopfropane | [EINECS(EC#)]
227-632-1 | [Molecular Formula]
C4H7Cl | [MDL Number]
MFCD00001307 | [Molecular Weight]
90.55 | [MOL File]
5911-08-0.mol |
| Chemical Properties | Back Directory | [Melting point ]
-91°C | [Boiling point ]
87-89 °C(lit.)
| [density ]
0.98 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.435(lit.)
| [Fp ]
29 °F
| [storage temp. ]
Inert atmosphere,2-8°C | [solubility ]
soluble in Chloroform, Methanol | [form ]
clear liquid | [color ]
Colorless to Almost colorless | [Water Solubility ]
Not miscible in water. | [BRN ]
635697 | [InChI]
InChI=1S/C4H7Cl/c5-3-4-1-2-4/h4H,1-3H2 | [InChIKey]
ZVTQWXCKQTUVPY-UHFFFAOYSA-N | [SMILES]
C1(CCl)CC1 | [CAS DataBase Reference]
5911-08-0(CAS DataBase Reference) | [NIST Chemistry Reference]
(Chloromethyl)cyclopropane(5911-08-0) |
| Safety Data | Back Directory | [Hazard Codes ]
F,Xi | [Risk Statements ]
R11:Highly Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [RIDADR ]
UN 1993 3/PG 2
| [WGK Germany ]
3
| [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29035990 |
| Hazard Information | Back Directory | [Chemical Properties]
Colorless to pale yellow liquid | [Uses]
(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4?-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction. On reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative. | [Synthesis Reference(s)]
Tetrahedron Letters, 13, p. 2135, 1972 DOI: 10.1016/S0040-4039(01)84787-0 | [General Description]
(Chloromethyl)cyclopropane on reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative. |
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