ChemicalBook--->CAS DataBase List--->59489-71-3

59489-71-3

59489-71-3 Structure

59489-71-3 Structure
IdentificationMore
[Name]

2-Amino-5-bromopyrazine
[CAS]

59489-71-3
[Synonyms]

2-AMINO-5-BROMOPYRAZINE
5-BROMO-2-PYRAZINAMINE
5-BROMOPYRAZIN-2-AMINE
5-BROMO-PYRAZIN-2-YLAMINE
5-BROMOPYRAZINAMINE
BUTTPARK 29\02-91
2-aimo-5-bromopyrazine
5-Bromo-2-aminopyrazine
2-AMINO-5-BROMOPYRAZINE: TECH.
2-Bromo-5-aminopyrazine
[EINECS(EC#)]

626-202-4
[Molecular Formula]

C4H4BrN3
[MDL Number]

MFCD00235015
[Molecular Weight]

174
[MOL File]

59489-71-3.mol
Chemical PropertiesBack Directory
[Appearance]

Brown Needles
[Melting point ]

113-117 °C (lit.)
[Boiling point ]

274.2±35.0 °C(Predicted)
[density ]

1.844±0.06 g/cm3(Predicted)
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[solubility ]

Ethanol, Ethyl Acetate, Methanol
[form ]

Brown Needles
[pka]

1.66±0.10(Predicted)
[color ]

Light yellow to Brown
[InChIKey]

KRRTXVSBTPCDOS-UHFFFAOYSA-N
[CAS DataBase Reference]

59489-71-3(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

R22:Harmful if swallowed.
R36/38:Irritating to eyes and skin .
R43:May cause sensitization by skin contact.
R44:Risk of explosion if heated under confinement.
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S22:Do not breathe dust .
[WGK Germany ]

3
[Hazard Note ]

Irritant
[HS Code ]

29339900
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Dichloromethane-->Sodium carbonate-->Magnesium sulfate-->N-Bromosuccinimide-->Aminopyrazine-->2-Amino-3,5-dibromopyrazine-->2-Amino-3-bromopyrazine-->3-Amino-6-bromopyrazine-2-carboxylic acid
[Preparation Products]

2,5-Dibromopyrazine-->2-BROMO-5-METHOXYPYRAZINE-->Cyclobutanecarbonitrile, 1-[6-(5-amino-2-pyrazinyl)-3-pyridinyl]--->5-(3-THIENYL)-2-PYRAZINAMINE-->6-AMINOPYRAZINE-2-BORONIC ACID PINACOL ESTER-->PyrazinaMine, 5-(4-chlorophenyl)-->5-(4-methoxyphenyl)pyrazin-2-amine
Hazard InformationBack Directory
[Chemical Properties]

Brown Needles
[Uses]

Used without prior protection of the amino group in a palladium-catalyzed cross-coupling with pyridylboronic acids leading to pyrazinylpyridines.
Spectrum DetailBack Directory
[Spectrum Detail]

2-Amino-5-bromopyrazine(59489-71-3)1HNMR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

5-Bromo-2-pyrazinamine, Tech.(59489-71-3)
[Alfa Aesar]

2-Amino-5-bromopyrazine, 97%(59489-71-3)
[Sigma Aldrich]

59489-71-3(sigmaaldrich)
[TCI AMERICA]

2-Amino-5-bromopyrazine,>98.0%(GC)(T)(59489-71-3)
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