ChemicalBook--->CAS DataBase List--->6935-27-9

6935-27-9

6935-27-9 Structure

6935-27-9 Structure
IdentificationMore
[Name]

2-Benzylaminopyridine
[CAS]

6935-27-9
[Synonyms]

2-BENZYLAMINOPYRIDINE
ALPHA-BENZYLAMINOPYRIDINE
AURORA KA-4160
BENZYL-PYRIDIN-2-YL-AMINE
N-(2-PYRIDYL)BENZYLAMINE
N-BENZYL-2-PYRIDYLAMINE
N-BENZYLPYRIDIN-2-AMINE
N-(PHENYLMETHYL)-2-PYRIDINAMINE
n-(phenylmethyl)-2-pyridinamin
N-(2-Pyridine)benzylamine
N-Benzyl-2-pyridinamine
N-Benzyl-2-pyridylamine~N-(2-Pyridyl)benzylamine
2-Pyridinamine, N-(phenylmethyl)-
N-(Phenylmethyl)pyridin-2-amine
Benzyl(2-pyridyl)amine
N-(2-Pyridinyl)benzenemethanamine
[EINECS(EC#)]

230-060-5
[Molecular Formula]

C12H12N2
[MDL Number]

MFCD00006251
[Molecular Weight]

184.24
[MOL File]

6935-27-9.mol
Chemical PropertiesBack Directory
[Appearance]

white to off-white powder
[Melting point ]

95-97 °C (lit.)
[Boiling point ]

116-131 °C/0.6 mmHg (lit.)
[density ]

1.1160 (rough estimate)
[refractive index ]

1.6266 (estimate)
[Fp ]

182°C/12mm
[storage temp. ]

Sealed in dry,2-8°C
[form ]

powder to crystal
[pka]

6.61±0.10(Predicted)
[color ]

White to Light yellow to Light orange
[BRN ]

134309
[InChI]

1S/C12H12N2/c1-2-6-11(7-3-1)10-14-12-8-4-5-9-13-12/h1-9H,10H2,(H,13,14)
[InChIKey]

WYHXNQXDQQMTQI-UHFFFAOYSA-N
[SMILES]

C(Nc1ccccn1)c2ccccc2
[CAS DataBase Reference]

6935-27-9(CAS DataBase Reference)
[EPA Substance Registry System]

6935-27-9(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

R22:Harmful if swallowed.
R37/38:Irritating to respiratory system and skin .
R41:Risk of serious damage to eyes.
R40:Limited evidence of a carcinogenic effect.
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S39:Wear eye/face protection .
S36:Wear suitable protective clothing .
S22:Do not breathe dust .
[WGK Germany ]

3
[RTECS ]

US2700000
[TSCA ]

Yes
[HS Code ]

29333999
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Acute Tox. 4 Oral
Eye Dam. 1
Skin Irrit. 2
STOT SE 3
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Potassium hydroxide-->2-Aminopyridine-->Benzenecarboximidamide, N-2-pyridinyl--->(4-Chloro-benzyl)-pyridin-2-yl-amine dihydrochloride-->2-Nitropyridine-->2-Iodopyridine-->Benzaldehyde-->Benzamide-->4-Chlorobenzyl alcohol-->2-Bromopyridine-->2-Chloropyridine-->Pyridine-N-oxide-->Benzyl alcohol-->Benzyl bromide-->Benzylamine
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Benzylaminopyridine(6935-27-9).msds
Hazard InformationBack Directory
[Chemical Properties]

white to off-white powder
[Uses]

2-(Benzylamino)pyridine is used as a reactant in the amination of aryl chlorides, bromides, and triflates catalyzed by palladium complexes.
[Synthesis Reference(s)]

Organic Syntheses, Coll. Vol. 4, p. 91, 1963
The Journal of Organic Chemistry, 67, p. 4965, 2002 DOI: 10.1021/jo020057z
[General Description]

2-Benzylaminopyridine on reaction with BBr3 yields the corresponding amino or hydroxy substituted compounds. It forms 5- and 6-coordinated organometallic complexes of gallium(III) and indium(III).
Spectrum DetailBack Directory
[Spectrum Detail]

2-Benzylaminopyridine(6935-27-9)MS
2-Benzylaminopyridine(6935-27-9)1HNMR
2-Benzylaminopyridine(6935-27-9)13CNMR
2-Benzylaminopyridine(6935-27-9)IR1
2-Benzylaminopyridine(6935-27-9)IR2
2-Benzylaminopyridine(6935-27-9)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Benzylaminopyridine, 98%(6935-27-9)
[Alfa Aesar]

2-Benzylaminopyridine, 98%(6935-27-9)
[Sigma Aldrich]

6935-27-9(sigmaaldrich)
[TCI AMERICA]

2-Benzylaminopyridine,>97.0%(T)(6935-27-9)
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