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7429-90-5

7429-90-5 Structure

7429-90-5 Structure
IdentificationMore
[Name]

Aluminium
[CAS]

7429-90-5
[EINECS(EC#)]

231-072-3
[Molecular Formula]

Al
[MDL Number]

MFCD00134029
[Molecular Weight]

26.98
[MOL File]

7429-90-5.mol
Chemical PropertiesBack Directory
[Appearance]

Aluminum is a combustible, light, silverywhite, soft, ductile, malleable, amphoteric metal
[Appearance]

silver foil, shot or powder
[mp ]

660.37 °C(lit.)
[bp ]

2460 °C(lit.)
[density ]

2.7 g/mL at 25 °C(lit.)
[Fp ]

400°C
[storage temp. ]

Flammables area
[form ]

wire
[Stability:]

Stable. Powder is flammable. Reacts very exothermically with halogens. Moisture and air sensitive. Incompatible with strong acids, caustics, strong oxidizing agents, halogenated hydrocarbons.
[Merck ]

13,321/13,321
[History]

The ancient Greeks and Romans used alum in medicine as an astringent, and as a mordant in dyeing. In 1761 de Morveau proposed the name alumine for the base in alum, and Lavoisier, in 1787, thought this to be the oxide of a still undiscovered metal. Wohler is generally credited with having isolated the metal in 1827, although an impure form was prepared by Oersted two years earlier. In 1807, Davy proposed the name alumium for the metal, undiscovered at that time, and later agreed to change it to aluminum. Shortly thereafter, the name aluminium was adopted to conform with the “ium” ending of most elements, and this spelling is now in use elsewhere in the world. Aluminium was also the accepted spelling in the U.S. until 1925, at which time the American Chemical Society officially decided to use the name aluminum thereafter in their publications. The method of obtaining aluminum metal by the electrolysis of alumina dissolved in cryolite was discovered in 1886 by Hall in the U.S. and at about the same time by Heroult in France. Cryolite, a natural ore found in Greenland, is no longer widely used in commercial production, but has been replaced by an artificial mixture of sodium, aluminum, and calcium fluorides. Bauxite, an impure hydrated oxide ore, is found in large deposits in Jamaica, Australia, Suriname, Guyana, Russia, Arkansas, and elsewhere. The Bayer process is most commonly used today to refine bauxite so it can be accommodated in the Hall–Heroult refining process used to make most aluminum. Aluminum can now be produced from clay, but the process is not economically feasible at present. Aluminum is the most abundant metal to be found in the Earth’s crust (8.1%), but is never found free in nature. In addition to the minerals mentioned above, it is found in feldspars, granite, and in many other common minerals. Twenty-two isotopes and isomers are known. Natural aluminum is made of one isotope, 27Al. Pure aluminum, a silvery- white metal, possesses many desirable characteristics. It is light, nontoxic, has a pleasing appearance, can easily be formed, machined, or cast, has a high thermal conductivity, and has excellent corrosion resistance. It is nonmagnetic and nonsparking, stands second among metals in the scale of malleability, and sixth in ductility. It is extensively used for kitchen utensils, outside building decoration, and in thousands of industrial applications where a strong, light, easily constructed material is needed. Although its electrical conductivity is only about 60% that of copper, it is used in electrical transmission lines because of its light weight. Pure aluminum is soft and lacks strength, but it can be alloyed with small amounts of copper, magnesium, silicon, manganese, and other elements to impart a variety of useful properties. These alloys are of vital importance in the construction of modern aircraft and rockets. Aluminum, evaporated in a vacuum, forms a highly reflective coating for both visible light and radiant heat. These coatings soon form a thin layer of the protective oxide and do not deteriorate as do silver coatings. They have found application in coatings for telescope mirrors, in making decorative paper, packages, toys, and in many other uses. The compounds of greatest importance are aluminum oxide, the sulfate, and the soluble sulfate with potassium (alum). The oxide, alumina, occurs naturally as ruby, sapphire, corundum, and emery, and is used in glassmaking and refractories. Synthetic ruby and sapphire have found application in the construction of lasers The Elements 4-3 for producing coherent light. In 1852, the price of aluminum was about $1200/kg, and just before Hall’s discovery in 1886, about $25/kg. The price rapidly dropped to 60¢ and has been as low as 33¢/kg. The price in December 2001 was about 64¢/ lb or $1.40/kg.
[CAS DataBase Reference]

7429-90-5(CAS DataBase Reference)
[NIST Chemistry Reference]

Aluminum(7429-90-5)
[EPA Substance Registry System]

7429-90-5(EPA Substance)
Hazard InformationBack Directory
[Chemical Properties]

Aluminum is the most commonly available element in homes and workplaces. Aluminum is readily available for human ingestion through the use of food additives, antacids, buffered aspirin, astringents, nasal sprays, and antiperspirants; from drinking water; from automobile exhaust and tobacco smoke; and from using aluminum foil, aluminum cookware, cans, ceramics, and fi reworks. Aluminum toxicity and its association with Alzheimer’s disease in humans require more studies. Some data are against and some are for, because the evidences are inadequate and inconclusive to suggest aluminum as the primary cause of the disease. Prolonged periods of exposure to aluminum and dust causes coughing, wheezing, shortness of breath, memory loss, learning diffi culty, loss of coordination, disorientation, mental confusion, colic, heartburn, fl atulence, and headaches. Chronic exposures to alumina dust cause irritation to the eyes, skin, respiratory system, pulmonary fi brosis, and lung damage
[Chemical Properties]

Aluminum metallic powder is a light, silvery-white to gray, odorless powder. Aluminum metallic powder is reactive and flammable. Aluminum is normally coated with a layer of aluminum oxide unless the particles are freshly formed. There are two main types of aluminum powder: the “fl ake” type made by stamping the cold metal and the “granulated” type made from molten aluminum. Pyro powder is an especially fi ne type of “fl ake” powder. Aluminum powders are used in paints, pigments, protective coatings, printing inks, rocket fuel, explosives, abrasives, and ceramics; the production of inorganic and organic aluminum chemicals; and as catalysts. Pyro powder is mixed with carbon and used in the manufacture of fi reworks. The coarse powder is used in aluminothermics.
[General Description]

Aluminum metal held above melting point of 1220°F (660°C) for ease in handling. Cools and solidifies if released. Contact causes thermal burns. Plastic or rubber may melt or lose strength upon contact. Protective equipment designed for chemical exposure only is not effective against direct contact. Take care walking on the surface of a spill to avoid stepping into a pocket of molten aluminum below the crust. Do not attempt to remove aluminum impregnated clothing because of the danger of tearing flesh if there has been a burn.
[Reactivity Profile]

ALUMINUM , MOLTEN, is a reducing agent. Coating moderates or greatly moderates its chemical reactivity compared to the uncoated material. Reacts exothermically if mixed with metal oxides and heated (thermite process). Heating a mixture with copper oxides caused a strong explosion [Mellor 5:217-19 1946-47]. Reacts with metal salts, mercury and mercury compounds, nitrates, sulfates, halogens, and halogenated hydrocarbons to form compounds that are sensitive to mechanical shock [Handling Chemicals Safely 1980. p. 135]. A number of explosions in which ammonium nitrate and powdered aluminum were mixed with carbon or hydrocarbons, with or without oxidizing agents, have occurred [Mellor 5:219 1946-47]. A mixture with powdered ammonium persulfate and water may explode [NFPA 491M 1991]. Heating a mixture with bismuth trioxide leads to an explosively violent reaction [Mellor 9:649 (1946-47)]. Mixtures with finely divided bromates(also chlorates and iodates) of barium, calcium, magnesium, potassium, sodium or zinc can explode by heat, percussion, and friction, [Mellor 2:310 (1946-47]. Burns in the vapor of carbon disulfide, sulfur dioxide, sulfur dichloride, nitrous oxide, nitric oxide, or nitrogen peroxide, [Mellor 5:209-212,1946-47]. A mixture with carbon tetrachloride exploded when heated to 153° C and also by impact, [Chem. Eng. News 32:258 (1954)]; [UL Bull. Research 34 (1945], [ASESB Pot. Incid. 39 (1968)]. Mixing with chlorine trifluoride in the presence of carbon results in a violent reaction [Mellor 2 Supp. 1: 1956]. Ignites in close contact with iodine. Three industrial explosions involving a photoflash composition containing potassium perchlorate with aluminum and magnesium powder have occurred [ACS 146:210 1945], [NFPA 491M 1991]. Is attacked by methyl chloride in the presence of small amounts of aluminum chloride to give flammable aluminum trimethyl. Give a detonable mixture with liquid oxygen [NFPA 491M 1991]. The reaction with silver chloride, once started, proceeds with explosive violence [Mellor 3:402 1946-47]. In an industrial accident, the accidental addition of water to a solid mixture of sodium hydrosulfite and powdered aluminum caused the generation of SO2, heat and more water. The aluminum powder reacted with water and other reactants to generate more heat, leading to an explosion that killed five workers [Case Study, Accident Investigation: Napp Technologies, 14th International Hazardous Material Spills Conference].
[Air & Water Reactions]

Violent reaction with water; contact may cause an explosion or may produce a flammable gas (hydrogen). Moist air produces hydrogen gas. Does not burn on exposure to air.
[Hazard]

Fine powder forms flammable and explo- sive mixtures in air. Confirmed carcinogen.
[Health Hazard]

Contact causes severe burns to skin and eyes. Fire may produce irritating and/or toxic gases.
[Health Hazard]

Exposures to aluminum metallic powder have been known to cause health effects with symptoms such as irritation, redness, and pain to the eyes, coughing, shortness of breath, irritation to the respiratory tract, nausea, and vomiting in extreme cases. In prolonged periods of inhalation exposures, as in occupational situations, aluminum metallic powder is known to cause pulmonary fi brosis, numbness in fi ngers, and (in limited cases) brain effects. Workers with pre-existing skin disorders, eye problems, or impaired respiratory function are known to be more susceptible to the effects of aluminum metallic powder.
[Health Hazard]

Occupational exposure to aluminum dust and fumes during welding provide suggestive evidence that there may be a relationship between chronic aluminum exposure and subclinical neurological effects, such as impairment on neurobehavioral tests for psychomotor and cognitive performance. Inhalation exposure has not been associated with overt symptoms of neurotoxicity. Prolonged exposure to high concentrations of aluminum and its accumulation causes disturbances in renal function, dialysis, and encephalopathy syndrome—a degenerative neurological syndrome characterized by the gradual loss of motor, speech, and cognitive functions
[Potential Exposure]

Most hazardous exposures to aluminum occur in smelting and refining processes. Aluminum is mostly produced by electrolysis of Al2O3 dissolved in molten cryolite (Na3AlF6). Aluminum is alloyed with copper, zinc, silicon, magnesium, manganese, and nickel; special additives may include chromium, lead, bismuth, titanium, zirconium, and vanadium. Aluminum and its alloys can be extruded or processed in rolling mills, wire works, forges, or foundries; and are used in the shipbuilding, electrical, building, aircraft, automobile, light engineering, and jewelry industries. Aluminum foil is widely used in packaging. Powdered aluminum is used in the paints and pyrotechnic industries. Alumina, emery, and corundum has been used for abrasives, refractories, and catalysts; and in the past in the first firing of china and pottery.
[Fire Hazard]

Substance is transported in molten form at a temperature above 705°C (1300°F). Violent reaction with water; contact may cause an explosion or may produce a flammable gas. Will ignite combustible materials (wood, paper, oil, debris, etc.). Contact with nitrates or other oxidizers may cause an explosion. Contact with containers or other materials, including cold, wet or dirty tools, may cause an explosion. Contact with concrete will cause spalling and small pops.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN1309 Aluminum powder, coated, Hazard Class: 4.1; Labels: 4.1-Flammable solid. UN1383 Pyrophoric metals, n.o.s. or Pyrophoric alloys, n.o.s., Hazard Class: 4.2; Labels: 4.2-Spontaneously combustible material, Technical Name Required. UN1396 Aluminum powder, uncoated, Hazard Class: 4.3; Labels: 4.3-Dangerous when wet material. NA9260 (North America) Aluminum, molten, Hazard class: 9; Labels: 9-Miscellaneous hazardous material.
[Incompatibilities]

Aluminum powder forms an explosive mixture with air and is a strong reducing agent that reacts violently with oxidizers, strong bases; strong acids; somehalogenated hydrocarbons; nitrates, sulfates, metal oxides and many other substances. Keep away from combustible materials.
[Waste Disposal]

Consult with environmental regulatory agencies for guidance on acceptable disposalpractices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal of Aluminum Oxide-Disposal in a sanitary landfill. Mixing of industrial process wastes and municipal wastes at such sites is not encouraged however. Aluminum powder may be recovered and sold as scrap. Recycling and recovery is a viable option to disposal for aluminum metal and aluminum fluoride (A-57).
Safety DataBack Directory
[Hazard Codes ]

F,Xi,Xn
[Risk Statements ]

R17:Spontaneously flammable in air.
R15:Contact with water liberates extremely flammable gases.
R36/38:Irritating to eyes and skin .
R10:Flammable.
R67:Vapors may cause drowsiness and dizziness.
R65:Harmful: May cause lung damage if swallowed.
R62:Possible risk of impaired fertility.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation .
R38:Irritating to the skin.
R11:Highly Flammable.
[Safety Statements ]

S7/8:Keep container tightly closed and dry .
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add-Never use water) .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S36/37:Wear suitable protective clothing and gloves .
S33:Take precautionary measures against static discharges .
S29:Do not empty into drains .
S16:Keep away from sources of ignition-No smoking .
S9:Keep container in a well-ventilated place .
[RIDADR ]

1396
[WGK Germany ]

3
[RTECS ]

BD0330000
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

76032000
[storage]

Aluminum metallic powder should be kept stored in a tightly closed container, in a cool, dry, ventilated area, protected against physical damage and isolated from sources of heat, ignition, smoking areas, and moisture. Aluminum metallic powder should be kept away from acidic, alkaline, combustible, and oxidizing materials and separate from halogenated compounds.
[Precautions]

The dry powder is stable but the damp or moist bulk dust may heat spontaneously and form flammable hydrogen gas. Moist aluminum powder may ignite in air, with the formation of flammable hydrogen gas and a combustible dust. Powdered material may form explosive dust-air mixtures. Contact with water, strong acids, strong bases, or alcohols releases flammable hydrogen gas. The dry powder can react violently or explosively with many inorganic and organic chemicals
[Safety Profile]

Although aluminum is not generally regarded as an industrial poison, inhalation of finely dwided powder has been reported to cause pulmonary fibrosis. It is a reactive metal and the greatest industrial hazards are with chemical reactions. As with other metals the powder and dust are the most dangerous forms. Dust is moderately flammable and explosive by heat, flame, or chemical reaction with powerful oxidizers. To fight fire, use special mixtures of dry chemical. following dangerous interactions: explosive reaction after a delay period with KClO4 + Ba(NO3)2 + mo3 + H20, also with Ba(NO3)2 + mo3 + sulfur + vegetable adhesives + H2O. Wxtures with powdered AgCl, NH4NO3 or NH4NO3 + Ca(NO3)2 + formamide + H20 are powerful explosives. Murture with ammonium peroxodisulfate + water is explosive. Violent or explosive "thermite" reaction when heated with metal oxides, oxosalts (nitrates, sulfates), or sulfides, and with hot copper oxide worked with an iron or steel tool. Potentially explosive reaction with ccl4 during ball milling operations. Many violent or explosive reactions with the following halocarbons have occurred in industry: bromomethane, bromotrifluoromethane, ccl4, chlorodfluoromethane, chloroform, chloromethane, chloromethane + 2methylpropane, dchlorodifluoromethane, 1,2-dichloroethane, dichloromethane, 1,2dichloropropane, 1,2-difluorotetrafluoroethane, fluorotrichloroethane, hexachloroethane + alcohol, polytrifluoroethylene oils and greases, tetrachloroethylene, tetrafluoromethane, 1,1,1trichloroethane, trichloroethylene, 1,1,2trichlorotrifluoro-ethane, and trichlorotrifluoroethane-dchlorobenzene. Potentially explosive reaction with chloroform amidinium nitrate. Ignites on contact with vapors of AsCl3, SC4, Se2Cl2, and PCl5. Reacts violently on heating with Sb or As. Ignites on heating in SbCl3 vapor. Ignites on contact with barium peroxide. Potentially violent reaction with sodium acetylide. Mixture with sodum peroxide may ignite or react violently. Spontaneously igmtes in CS2 vapor. Halogens: ignites in Powdered aluminum undergoes the chlorine gas, foil reacts vigorously with liquid Br2, violent reaction with H20 + 12. Violent reaction with hydrochloric acid, hydro-fluoric acid, and hydrogen chloride gas. Violent reaction with disulfur dbromide. Violent reaction with the nonmetals phosphorus, sulfur, and selenium. Violent reaction or ignition with the interhalogens: bromine pentafluoride, chlorine fluoride, iodne chloride, iodine pentafluoride, and iodne heptafluoride. Burns when heated in CO2. Ignites on contact with O2, and mixtures with O2 + H20 ignite and react violently. Mixture with picric acid + water ignites after a delay period. Explosive reaction above 800°C with sodium sulfate. Violent reaction with sulfur when heated. Exothermic reaction with iron powder + water releases explosive hydrogen gas. Aluminum powder also forms sensitive explosive mixtures with oxidants such as: liquid Cl2 and other halogens, N2O4, tetranitromethane, bromates, iodates, NaClO3, KClO3, and other chlorates, NaNO3, aqueous nitrates, KClO4 and other perchlorate salts, nitryl fluoride, ammonium peroxodisulfate, sodium peroxide, zinc peroxide, and other peroxides, red phosphorus, and powdered polytetrafluoroethylene (PTFE). following dangerous interactions: exothermic reaction with butanol, methanol, 2-propanol, or other alcohols, sodium hydroxide to release explosive hydrogen gas. Reaction with dborane forms pyrophoric product. Ignition on contact with niobium oxide + sulfur. Explosive reaction with molten metal oxides, oxosalts (nitrates, sulfates), sulfides, and sodium carbonate. Reaction with arsenic trioxide + sodum arsenate + sodium hydroxide produces the toxic arsine gas. Violent reaction with chlorine trifluoride. Incandescent reaction with formic acid. Potentially violent alloy formation with palladium, platinum at mp of Al, 600℃. Vigorous dssolution reaction in Bulk aluminum may undergo the ALUMINUM CHLORIDE HYDROXIDE AHAOOO 45 methanol + carbon tetrachloride. Vigorous amalgamation reaction with mercury(Ⅱ) salts + moisture. Violent reaction with molten silicon steels. Violent exothermic reaction above 600℃ with sodium diuranate.
[Hazardous Substances Data]

7429-90-5(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Stearic acid-->PASSION FLOWER OIL-->LVBO-->ALUMINUM INGOTS-->ALUMINIUM GRANULAR 50-150 MESH
[Preparation Products]

Aluminium isopropoxide-->Pigment Geen 7-->Boron-->Aluminum ammonium sulfate-->Pigment Yellow 42-->polyethylene conductive plastics-->Aluminum chlorohydrate-->2,6-Diethylaniline-->1-Naphthalene acetic acid-->Decabromodiphenyl oxide-->5-CHLORO-1H-INDAZOLE-3-CARBOXYLIC ACID-->DIETHYLALUMINUM CHLORIDE-->Econazole-->Iopanoic acid -->Miconazole nitrate -->Aluminum nitrate -->3-(1,2,2,2-tetrabromoethyl)-2,2-dimethyl cyclo-propane carboxylic acid-->Titanous chloride-->Iodotrimethylsilane-->Triethylaluminum-->Aluminium nitrate nonahydrate-->Flumetralin-->ferrovanadium-->Triisobutylaluminium-->BISMUTH ALUMINATE-->ALUMINUM POTASSIUM SULFATE-->N-Methylcyclohexylamine-->CALCIUM PHOSPHIDE-->Aluminate coupling agent-->Aluminum phosphide-->ETHYLALUMINUM DICHLORIDE-->PHENYLBORON DICHLORIDE-->2-AMINO-3-PYRIDINECARBOXALDEHYDE HCL-->hydrofining catalyst CH-17-->ALUMINUM DI(ISOPROPOXIDE)ACETOACETIC ESTER CHELATE-->Aluminium 2-ethylhexanoate-->isometheptene-->Aluminum acetylacetonate-->HEXABROMOBENZENE-->Zinc Aluminum Paste
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Aluminium(7429-90-5).msds
Questions And AnswerBack Directory
[Description]

Aluminum is the third most abundant element in the crust of the earth, accounting for 8.13% by weight. It does not occur in free elemental form in nature, but is found in combined forms such as oxides or silicates. It occurs in many minerals including bauxite, cryolite, feldspar and granite. Aluminum alloys have innumerable application; used extensively in electrical transmission lines, coated mirrors, utensils, packages, toys and in construction of aircraft and rockets.
[Production Methods]

Most aluminum is produced from its ore, bauxite, which contains between 40 to 60% alumina either as the trihydrate, gibbsite, or as the monohydrate, boehmite, and diaspore. Bauxite is refined first for the removal of silica and other impurities. It is done by the Bayer process. Ground bauxite is digested with NaOH solution under pressure, which dissolves alumina and silica, forming sodium aluminate and sodium aluminum silicate. Insoluble residues containing most impurities are filtered out. The clear liquor is then allowed to settle and starch is added to precipitate. The residue, so-called “red-mud”, is filtered out. After this “desilication,” the clear liquor is diluted and cooled. It is then seeded with alumina trihydrate (from a previous run) which promotes hydrolysis of the sodium aluminate to produce trihydrate crystals. The crystals are filtered out, washed, and calcined above 1,100°C to produce anhydrous alumina. The Bayer process, however, is not suitable for extracting bauxite that has high silica content (>10%). In the Alcoa process, which is suitable for highly silicious bauxite, the “red mud” is mixed with limestone and soda ash and calcined at 1,300°C. This produces “lime-soda sinter” which is cooled and treated with water. This leaches out water-soluble sodium alumnate, leaving behind calcium silicate and other impurites.
Alumina may be obtained from other minerals, such as nepheline, sodium potassium aluminum silicate, by similar soda lime sintering process.Metal aluminum is obtained from the pure alumina at 950 to 1000°C electrolysis (Hall-Heroult process). Although the basic process has not changed since its discovery, there have been many modifications. Aluminum is also produced by electrolysis of anhydrous AlCl3.
Also, the metal can be obtained by nonelectrolytic reduction processes. In carbothermic process, alumina is heated with carbon in a furnace at 2000 to 2500°C. Similarly, in “Subhalide” process, an Al alloy, Al-Fe-Si-, (obtained by carbothermic reduction of bauxite) is heated at 1250°C with AlCl vapor. This forms the subchloride (AlCl), the vapor of which decomposes when cooled to 800°C.
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Aluminium, shot (2-10 mm), 99.50%(7429-90-5)
[Alfa Aesar]

Aluminum, powder, coarse, 99%(7429-90-5)
[Sigma Aldrich]

7429-90-5(sigmaaldrich)
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