ChemicalBook--->CAS DataBase List--->7790-28-5

7790-28-5

7790-28-5 Structure

7790-28-5 Structure
IdentificationMore
[Name]

Sodium periodate
[CAS]

7790-28-5
[Synonyms]

IONAM
SODIUM METAPERIODATE
SODIUM M-PERIODATE
SODIUM PERIODATE META
SODIUM TETRAOXOIODATE (VII)
SODIUM TETROXOIODATE (VII)
metaperiodate
periodicacid(hio4),sodiumsalt
Periodicacid,sodiumsalt
sodiummetaperidate
sodiummetaperiodate(sodiumperiodate)
Sodium metapriodate
SODIUM TETROXOIODATE(VII) R. G., REAG. A CS, REAG. PH. EUR.
SODIUM M-PERIODATE ACS REAGENT
SODIUM PERIODATE, 99.8+%, A.C.S. REAGENT
SODIUM PERIODATE, 10 WT. % ON SILICA GEL
SODIUM (META)PERIODATE, ACS
SodiumMetaperiodateGr
SodiumMetaperiodateExtraPure
SODIUM META PERIODTAE ( SODIUM PERIODATE )
[EINECS(EC#)]

232-197-6
[Molecular Formula]

INaO4
[MDL Number]

MFCD00003534
[Molecular Weight]

213.89
[MOL File]

7790-28-5.mol
Chemical PropertiesBack Directory
[Appearance]

white powder
[Melting point ]

300 °C (dec.) (lit.)
[Boiling point ]

300°C
[bulk density]

2900kg/m3
[density ]

3.865
[vapor pressure ]

0Pa at 20℃
[storage temp. ]

Store at +5°C to +30°C.
[solubility ]

H2O: 0.5 M at 20 °C, clear, colorless
[form ]

Solid
[color ]

White to almost white
[Specific Gravity]

4.174
[Odor]

Odorless
[PH]

3.5-5.5 (25℃, 0.5M in H2O)
[PH Range]

3.5 - 5.5
[Stability:]

Stable. Incompatible with organic materials, combustible materials. Forms explosive mixtures with reducing agents, finely powdered metals, magnesium.
[Water Solubility ]

80 g/L (20 ºC)
[Sensitive ]

Hygroscopic
[Merck ]

14,8640
[InChI]

1S/HIO4.Na/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
[InChIKey]

JQWHASGSAFIOCM-UHFFFAOYSA-M
[SMILES]

[Na+].[O-]I(=O)(=O)=O
[LogP]

-1 at 20℃
[CAS DataBase Reference]

7790-28-5(CAS DataBase Reference)
[EPA Substance Registry System]

7790-28-5(EPA Substance)
[Absorption]

cut-off at 350nm in H2O at 0.05M
Safety DataBack Directory
[Symbol(GHS) ]

Flame Over Circle (GHS03)Corrosion (GHS05)Health Hazard (GHS08)Environment (GHS09)
GHS03,GHS05,GHS08,GHS09
[Signal word ]

Danger
[Hazard statements ]

H271-H314-H372-H410
[Precautionary statements ]

P210-P260-P273-P280-P303+P361+P353-P305+P351+P338
[Hazard Codes ]

O,Xn,Xi
[Risk Statements ]

R8:Contact with combustible material may cause fire.
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S17:Keep away from combustible material .
[RIDADR ]

UN 3087 5.1/PG 2
[WGK Germany ]

3
[RTECS ]

SD4550000
[F ]

8
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

5.1
[PackingGroup ]

II
[HS Code ]

28299080
[Storage Class]

5.1A - Strongly oxidizing hazardous materials
[Hazard Classifications]

Aquatic Acute 1
Aquatic Chronic 1
Eye Dam. 1
Ox. Sol. 1
Skin Corr. 1C
STOT RE 1
[Hazardous Substances Data]

7790-28-5(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium chloride-->Iodine-->Periodic acid-->iodine
[Preparation Products]

(1R,2R)-N-Boc-1-amino-2-phenylcyclopropanecarboxylic acid-->Bergapten-->Periodic acid-->1-Fluoro-4-(trifluoromethylthio)benzene-->Dropropizine-->2-Methyl-4-hydroxymethylpyridine-->2-Fluoro-6-formylpyridine-->(R)-(-)-2,2-Dimethyl-1,3-dioxolane-4-methanol-->4-Nitrophenylboronic acid-->4-(Methylsulfonyl)phenol-->Suprofen-->Lamivudine-->4-Amino-3-formylpyridine-->3-Nitroisonicotinaldehyde-->(S)-(+)-2,2-Dimethyl-1,3-dioxolane-4-methanol-->Tetrapropylammonium perruthenate-->Ruthenium tetroxide
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Sodium metaperiodate(7790-28-5).msds
Hazard InformationBack Directory
[Hazard]

Fire risk in contact with organic materials. Toxic by ingestion.
[Description]

Sodium periodate is an inorganic salt, composed of a sodium cation and the periodate anion. It may also be regarded as the sodium salt of periodic acid. Like many periodates it can exist in two different forms: sodium metaperiodate, which has the formula NaIO4, and sodium orthoperiodate, normally this means sodium hydrogen periodate (Na2H3IO6) but the fully reacted sodium orthoperiodate salt, Na5IO6, can also be prepared. Both salts are useful oxidising agents.
[Chemical Properties]

Sodium periodate Na2H3IO6, is formed by reaction of sodium iodate plus sodium hydroxide plus chlorine (sodium chloride also formed), and the periodate separates as crystals from the medium. In solution, it is stated, periodate gradually forms ozone and iodate at the ordinary temperatures.
[Chemical Properties]

white powder
[Uses]

Oxidimetric standard; determination of manganese.
[Uses]

Sodium Periodate is the sodium salt of periodic acid used to oxidize cellulose. Sodium Periodate oxidation is often used to selectively label RNA, saccharides and other compounds with vicinal diols.
[Definition]

ChEBI: An inorganic sodium salt having periodate as the counterion.
[General Description]

Sodium periodate (sodium (meta)periodate) supported on silica gel is a solid supported reagent. It may be synthesized by adding silica gel to hot aqueous solution of sodium metaperiodate and evaporating to dryness followed by vigorous swirling and shaking.
[Flammability and Explosibility]

Nonflammable
[reaction suitability]

reagent type: oxidant
[Purification Methods]

Recrystallise it from hot water. [Willard Inorg Synth I 170 1939, Bernays Inorg Synth II 212 1946.]
Spectrum DetailBack Directory
[Spectrum Detail]

Sodium periodate(7790-28-5)IR1
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Sodium periodate, for analysis, 99%(7790-28-5)
[Alfa Aesar]

Sodium metaperiodate, ACS, 99.8-100.3%(7790-28-5)
[Sigma Aldrich]

7790-28-5(sigmaaldrich)
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