| Identification | Back Directory | [Name]
(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97% | [CAS]
817176-80-0 | [Synonyms]
(S)-7,7'-Bis[di(p-methylphenyl)phosphino]-1,1'-spirobiindane ,97%
(S)-()-7,7′-Bis[di(4-methylphenyl)phosphino]-2,2′,3,3′-tetrahydro-1,1′-spirobiindene | [Molecular Formula]
C45H42P2 | [MDL Number]
MFCD08459345 | [MOL File]
817176-80-0.mol | [Molecular Weight]
644.76 |
| Chemical Properties | Back Directory | [Melting point ]
150-152°C | [alpha ]
-221° (c 0.54, CH2Cl2) | [Boiling point ]
722.0±60.0 °C(Predicted) | [storage temp. ]
?20°C | [form ]
solid | [color ]
white | [Optical Rotation]
[α]22/D 206°, c = 1 in chloroform | [Sensitive ]
air sensitive | [InChIKey]
VLIOMJFCGWZUON-UHFFFAOYSA-N | [SMILES]
Cc1ccc(cc1)P(c2ccc(C)cc2)c3cccc4CCC5(CCc6cccc(P(c7ccc(C)cc7)c8ccc(C)cc8)c56)c34 |
| Questions And Answer | Back Directory | [Reaction]
- Ligands used for the ruthenium-catalyzed hydrogenation of simple and cyclic ketones with high activity and enantioselectivity.
- Ligands used for palladium-catalyzed asymmetric allylic alkylations.
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