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656233-53-3

656233-53-3 Structure

656233-53-3 Structure
IdentificationBack Directory
[Name]

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY
[CAS]

656233-53-3
[Synonyms]

(R)-SHIP
(S)-SHIP
PHENYL-[(R)-1,1-SPIROBIINDANE-7,7-DIYL]-PHOSPHITE
PHENYL-[(S)-1,1-SPIROBIINDANE-7,7-DIYL]-PHOSPHITE
Phenyl-[(R)-1,1-spirobiindane-7,7-diyl]-phosphite ,97%
(11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-PHENOXY
(11aR)-10,11,12,13-Tetrahydro-5-phenoxy-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin,99%e.e.
(11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-phenoxy,min.98%(R)-ShiP
Phenyl-[(R)-1,1-spirobiindane-7,7-diyl]-phosphite, (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ,7μ-fg][1,3,2]dioxaphosphocin-5-phenoxy
[Molecular Formula]

C23H19O3P
[MDL Number]

MFCD08459341
[MOL File]

656233-53-3.mol
[Molecular Weight]

374.37
Chemical PropertiesBack Directory
[Melting point ]

104-106°C
[alpha ]

+216° (c 0.5, CH2Cl2)
[form ]

solid
[color ]

white
[Sensitive ]

moisture sensitive
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H302
[Precautionary statements ]

P264-P270-P301+P312-P330-P501
[Hazard Codes ]

Xn
[Risk Statements ]

22
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Sodium hydroxide-->Hydrochloric acid-->Ethyl acetate-->Tetrahydrofuran-->Dichloromethane-->PETROLEUM ETHER-->Toluene-->Triethylamine-->Acetone-->Sodium bicarbonate-->Hydrogen peroxide-->Palladium-->Hydrogen-->Phosphorus trichloride-->Nickel-->Phenol-->Benzyl chloride-->N,N-Diisopropylethylamine-->Sodium bromide-->Methanesulfonic acid-->(S)-1,1'-SPIROBIINDANE-7,7'-DIOL-->Boron tribromide-->3-Hydroxybenzaldehyde-->(R)-1,1'-SPIROBIINDANE-7,7'-DIOL-->Cinchonidine-->CALCIUM HYDRIDE
Questions And AnswerBack Directory
[Reaction]

  1. Chiral ligands for rhodium-catalyzed arylation of aldehydes with arylboronic acids.
  2. Chiral ligands for rhodium-catalyzed arylation of imines with arylboronic acids.
  3. Chiral ligands for rhodium-catalyzed arylation of α-ketoesters with arylboronic acids.
  4. Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes.
  5. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of (Z)-β-arylenamides.
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