| Identification | More | [Name]
2-Furoic acid | [CAS]
88-14-2 | [Synonyms]
2-FURANCARBONYL CHLORIDE
2-FURANCARBOXYLIC ACID CHLORIDE
2-FUROYL CHLORIDE
AKOS BBS-00003923
FURAN-2-CARBONYL CHLORIDE
FUROYL CHLORIDE
TIMTEC-BB SBB004224
2-Furancarbosylicacid
a-Furoicacid
alpha-Furancarboxylic acid
alpha-furancarboxylicacid
Furancarbonylicacid
Furancarboxylic acid-(2)
furancarboxylicacid
Furoica
Kyselina 2-furoova
Kyselina pyroslizova
kyselina2-furoova
kyselinapyroslizova
2-FUROIC ACID 99.5% | [EINECS(EC#)]
208-422-9 | [Molecular Formula]
C5H4O3 | [MDL Number]
MFCD00003228 | [Molecular Weight]
112.08 | [MOL File]
88-14-2.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powde | [Melting point ]
−2 °C(lit.)
| [Boiling point ]
173-174 °C(lit.)
| [density ]
1.324 g/mL at 25 °C(lit.)
| [vapor pressure ]
13.732Pa at 25℃ | [refractive index ]
n20/D 1.531(lit.)
| [Fp ]
185 °F
| [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
37g/l | [form ]
Fine Crystalline Powder | [pka]
3.16(at 25℃) | [color ]
Off-white to beige | [Odor]
odorless | [Odor Type]
odorless | [Water Solubility ]
36 g/L (20 ºC) | [Merck ]
14,4307 | [BRN ]
110149 | [InChIKey]
SMNDYUVBFMFKNZ-UHFFFAOYSA-N | [LogP]
0.628 at 25℃ | [Uses]
Substitute for chloropicrin in disinfecting grain
elevators. | [CAS DataBase Reference]
88-14-2(CAS DataBase Reference) | [NIST Chemistry Reference]
2-Furancarboxylic acid(88-14-2) | [EPA Substance Registry System]
88-14-2(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
C,Xi | [Risk Statements ]
R34:Causes burns.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [RIDADR ]
UN 3265 8/PG 2
| [WGK Germany ]
3
| [RTECS ]
LV1763000
| [F ]
10-19-21 | [TSCA ]
Yes | [HS Code ]
29321900 |
| Hazard Information | Back Directory | [Hazard]
Strong irritant to eyes and skin. | [Chemical Properties]
white to light yellow crystal powde | [Application]
2-Furoic acid (FA) is a preservative, acting as a bactericide and fungicide. Some of the applications of 2-furoic acid include:
Synthesis of a single-molecule magnet, Mn11Gd2 based high-nuclearity heterometallic complex.
Synthesis of orally active antidiabetic vanadyl complex, bis(α-furancarboxylato)oxovanadium(IV).
As a ligand in the synthesis of luminescent 4f-3d heterometallic one-dimensional coordination polymers.
Synthesis of biocompatible multifunctional dextran furoate nanospheres.
FA is often used as a starting material for the production of furoate esters.
FA and its derivatives are also used in the production of nylons principally applied in biomedical researches. | [Definition]
ChEBI: A furoic acid having the carboxylic acid group located at position 2. | [Preparation]
2-furoic acid can be synthesized by the oxidation of furfural. The reaction was carried out at 45°C with vigorous stirring. The reactant is filtered to recover the catalyst copper oxide, the filtrate is acidified with 50% sulfuric acid to pH 3-2.5, suction filtered, washed with water, and dried to obtain 2-furoic acid. | [Flammability and Explosibility]
Notclassified | [storage]
Store at -20°C | [Purification Methods]
Crystallise the acid from hot water (charcoal), dry it at 120o for 2hours, then recrystallise it from CHCl3, and again dry it at 120o for 2hours. For use as a standard in volumetric analysis, good quality commercial acid should be crystallised from CHCl3 and dried as above or sublimed at 130-140o/50-60mm or less. [Beilstein 18 I 438, 18 II 265, 18 III/IV 3914, 18/6 V 102.] |
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