ChemicalBook--->CAS DataBase List--->90-64-2

90-64-2

90-64-2 Structure

90-64-2 Structure
IdentificationMore
[Name]

DL-Mandelic acid
[CAS]

90-64-2
[Synonyms]

2-HYDROXY-2-PHENYLACETIC ACID
A-HYDROXYBENZENE ACETIC
ALPHA-HYDROPHENYLACETIC ACID
ALPHA-HYDROXY-ALPHA-TOLUIC ACID
(+/-)-ALPHA-HYDROXYPHENYLACETIC ACID
ALPHA-HYDROXYPHENYLACETIC ACID
DL-A-HYDROXYPHENYLACETIC ACID
DL-ALPHA-HYDROXYPHENYLACETIC ACID
DL-AMYGDALIC ACID
DL-MANDELIC ACID
DL-O-HYDROXYPHENYLACETIC ACID
DL-PHENYLGLYCOLIC ACID
(+/-)-MANDELIC ACID
MANDELIC ACID
MANDELIC ACID, DL-
MANDELIC(D,L-) ACID
PHENYLGLYCOLIC ACID
PHENYLGLYCOLLIC ACID
PHENYLHYDROXYACETIC ACID
RARECHEM AL BO 1098
[EINECS(EC#)]

202-007-6
[Molecular Formula]

C8H8O3
[MDL Number]

MFCD00064250
[Molecular Weight]

152.15
[MOL File]

90-64-2.mol
Chemical PropertiesBack Directory
[Definition]

Exists in stereoisomeric forms. The properties are those of the dl-form.
[Appearance]

White crystalline powder
[Melting point ]

119-121 °C (lit.)
[alpha ]

[α]D20 -0.5~+0.5° (c=2, H2O)
[Boiling point ]

214.6°C (rough estimate)
[bulk density]

750kg/m3
[density ]

1.30
[vapor pressure ]

0.01 Pa (50 °C)
[refractive index ]

1.4810 (estimate)
[storage temp. ]

Store below +30°C.
[solubility ]

139g/l
[form ]

Crystals or Crystalline Powder
[pka]

3.85(at 25℃)
[color ]

White
[Odor]

faint odor
[PH]

2.3 (10g/l, H2O)
[Optical Rotation]

[α]/D 0±1°, c = 5 in H2O
[Water Solubility ]

150 g/L (20 ºC)
[Sensitive ]

Light Sensitive
[Merck ]

14,5717
[BRN ]

510011
[Major Application]

cleaning products
cosmetics
food and beverages
forensics and toxicology
personal care
veterinary
[Cosmetics Ingredients Functions]

ANTIMICROBIAL
[InChI]

1S/C8H8O3/c9-7(8(10)11)6-4-2-1-3-5-6/h1-5,7,9H,(H,10,11)
[InChIKey]

IWYDHOAUDWTVEP-UHFFFAOYSA-N
[SMILES]

OC(C(O)=O)c1ccccc1
[LogP]

0.5 at 23℃
[Uses]

Organic synthesis, medicine (urinary antiseptic).
[CAS DataBase Reference]

90-64-2(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzeneacetic acid, «alpha»-hydroxy-(90-64-2)
[EPA Substance Registry System]

90-64-2(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)
GHS05
[Signal word ]

Danger
[Hazard statements ]

H318
[Precautionary statements ]

P280-P305+P351+P338
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
R22:Harmful if swallowed.
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[WGK Germany ]

3
[RTECS ]

OO6300000
[TSCA ]

Yes
[REACH Registrations]

Active
[HS Code ]

29181990
[Storage Class]

13 - Non Combustible Solids
[Hazard Classifications]

Eye Dam. 1
[Safety Profile]

Poison by intramuscular route. Moderately toxic by ingestion. Continued absorption can cause kidney irritation. When heated to decomposition it emits acrid smoke and irritating fumes.
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Acetone-->Sodium cyanide-->Sodium bisulfite-->Benzaldehyde-->Glycolonitrile-->2-Chloroacetophenone-->Benzoylformic acid
[Preparation Products]

1,2-Phenylenediacetic acid-->DL-alpha-Methoxyphenylacetic acid-->Pemoline
Hazard InformationBack Directory
[Hazard]

Toxic by ingestion.
[Chemical Properties]

White crystalline powder
[Preparation]

Mandelic acid can be prepared by the hydrolysis of amygdalin with sulfuric acid or of mandelonitrile with hydrochloric acid. The mandelonitrile can be prepared by the action of hydrocyanic acid on benzaldehyde, and by the action of sodium or potassium cyanide on the sodium bisulfite addition product of benzaldehyde. The procedure described differs from earlier methods in that the sodium bisulfite addition compound of benzaldehyde is prepared in the presence of sodium cyanide and the nitrile is formed immediately.
synthesis of mandelic acid
[General Description]

DL-Mandelic acid is an aromatic hydrocarbon metabolite of styrene.
[Flammability and Explosibility]

Notclassified
[storage]

Store at -20°C
Spectrum DetailBack Directory
[Spectrum Detail]

DL-Mandelic acid(90-64-2)MS
DL-Mandelic acid(90-64-2)1HNMR
DL-Mandelic acid(90-64-2)13CNMR
DL-Mandelic acid(90-64-2)IR1
DL-Mandelic acid(90-64-2)IR2
DL-Mandelic acid(90-64-2)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

DL-Mandelic acid, 99+%(90-64-2)
[Alfa Aesar]

(+/-)-Mandelic acid, 99%(90-64-2)
[Sigma Aldrich]

90-64-2(sigmaaldrich)
[TCI AMERICA]

DL-Mandelic Acid,>99.0%(GC)(T)(90-64-2)
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