ChemicalBook--->CAS DataBase List--->93-03-8

93-03-8

93-03-8 Structure

93-03-8 Structure
IdentificationMore
[Name]

3,4-Dimethoxybenzyl alcohol
[CAS]

93-03-8
[Synonyms]

3,4-DIMETHOXYBENZYL ALCOHOL
3,4-DIMETHOXYBENZYL METHANOL
(3,4-DIMETHOXYPHENYL)METHANOL
RARECHEM AL BD 0062
VERATRYL ALCOHOL
3,4-dimethoxy-benzenemethano
3,4-dimethoxy-Benzenemethanol
3,4-Dimethoxyphenylmethyl alcohol
3,4-Dimethoxybenzyl alcohol (Veratry alcohol)
Benzenemethanol, 3,4-dimethoxy-
3,4-DIMETHOXYBENZYL ALCOHOL/VERATRYL ALCOHOL
3,4-DIMETHOXYBENZYL ALCOHOL 98%
3,4-Dimethoxybenzene-1-methanol
[EINECS(EC#)]

202-212-0
[Molecular Formula]

C9H12O3
[MDL Number]

MFCD00004638
[Molecular Weight]

168.19
[MOL File]

93-03-8.mol
Chemical PropertiesBack Directory
[Appearance]

Colorless to light yellow liqui
[Melting point ]

22 °C
[Boiling point ]

296-297 °C732 mm Hg(lit.)
[density ]

1.157 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.552(lit.)
[Fp ]

>230 °F
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

Oily Liquid
[pka]

14.18±0.10(Predicted)
[color ]

Clear colorless to yellow or golden
[Water Solubility ]

miscible
[BRN ]

639388
[Cosmetics Ingredients Functions]

SKIN CONDITIONING
[InChI]

1S/C9H12O3/c1-11-8-4-3-7(6-10)5-9(8)12-2/h3-5,10H,6H2,1-2H3
[InChIKey]

OEGPRYNGFWGMMV-UHFFFAOYSA-N
[SMILES]

COc1ccc(CO)cc1OC
[LogP]

0.72
[CAS DataBase Reference]

93-03-8(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzenemethanol, 3,4-dimethoxy-(93-03-8)
[EPA Substance Registry System]

93-03-8(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302
[Precautionary statements ]

P301+P312+P330-P264-P270-P301+P312a-P330-P501a
[Hazard Codes ]

Xn,Xi
[Risk Statements ]

R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S24/25:Avoid contact with skin and eyes .
S36/37:Wear suitable protective clothing and gloves .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

3
[TSCA ]

Yes
[REACH Registrations]

Active
[HS Code ]

29062990
[Storage Class]

10 - Combustible liquids
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ethanol-->Hydrochloric acid-->Dichloromethane-->Petroleum ether-->Magnesium sulfate-->Sodium bicarbonate-->Sodium borohydride-->Isopropyl alcohol-->Veratraldehyde-->Sodium bisulfate monohydrate-->veratryl acetate-->3,4-DIMETHOXYBENZAMIDE
[Preparation Products]

DIVERATRYL ETHER-->6,7-Dimethoxy-3,4-dihydroisoquinoline-->4,5-Dimethoxy-1-cyanobenzocyclobutane-->Veratrylamine-->2-Amino-4,5-dimethoxybenzoic acid-->(3,4-Dimethoxybicyclo[4.2.0]octa-1,3,5-trien-7-yl)methanamine hydrochloride
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

3,4-Dimethoxybenzyl alcohol(93-03-8).msds
Hazard InformationBack Directory
[Chemical Properties]

Colorless to light yellow liqui
[Uses]

3,4-Dimethoxybenzyl Alcohol is a secondary metabolite of some lignin degrading fungi. Recent studies have been conducted to explore whether 3,4-Dimethoxybenzyl Alcohol, a product from the biodegradati on of lignocellulosic biomass, could be used as the fuel of the microbial fuel cell (MFC) to generate power.
[Definition]

ChEBI: A member of the class of benzyl alcohols that is benzyl alcohol in which the hydrogens at positions 3 and 4 of the phenyl group are substituted by methoxy groups.
[Synthesis Reference(s)]

Chemical and Pharmaceutical Bulletin, 34, p. 4109, 1986 DOI: 10.1248/cpb.34.4109
The Journal of Organic Chemistry, 59, p. 7138, 1994 DOI: 10.1021/jo00102a048
[General Description]

Pharmaceutical secondary standards for application in quality control, provide pharma laboratories and manufacturers with a convenient and cost-effective alternative to the preparation of in-house working standards.
[Synthesis]

Using 3,4-dimethoxybenzaldehyde as a raw material, reduction is carried out in methanol or other alcohol solvents by adding sodium borohydride (a mild reducing agent commonly used in industry), with the reaction stirred at room temperature to reflux temperature; or in the laboratory, lithium aluminum hydride (in anhydrous tetrahydrofuran or diethyl ether) can be used for reduction. After the reaction is completed, the product 3,4-dimethoxybenzyl alcohol is obtained by acidification, extraction, drying, distillation or recrystallization.
Spectrum DetailBack Directory
[Spectrum Detail]

3,4-Dimethoxybenzyl alcohol(93-03-8)MS
3,4-Dimethoxybenzyl alcohol(93-03-8)1HNMR
3,4-Dimethoxybenzyl alcohol(93-03-8)13CNMR
3,4-Dimethoxybenzyl alcohol(93-03-8)IR1
3,4-Dimethoxybenzyl alcohol(93-03-8)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

3,4-Dimethoxybenzyl alcohol, 96%(93-03-8)
[Alfa Aesar]

3,4-Dimethoxybenzyl alcohol, 97%(93-03-8)
[Sigma Aldrich]

93-03-8(sigmaaldrich)
[TCI AMERICA]

Veratryl Alcohol,>95.0%(GC)(93-03-8)
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