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95-69-2

95-69-2 Structure

95-69-2 Structure
IdentificationMore
[Name]

4-Chloro-2-methylaniline
[CAS]

95-69-2
[Synonyms]

1-AMINO-4-CHLORO-6-METHYLBENZENE
2-AMINO-5-CHLOROTOLUENE
2-AMINO-5-CHLORTOLUENE
2-methyl-4-chloroaniline
4-CHLORO-2-METHYLANILINE
4-chloro-2-methylbenzenamine
4-Chloro-6-methylaniline
4-CHLORO-O-METHYLANILINE
4-CHLORO-O-TOLUIDINE
5-CHLORO-2-AMINOTOLUENE
AKOS BBS-00004466
azoene fast red tr base
AZOIC DIAZO COMPONENT 11
AZOIC DIAZO COMPONENT 32
FAST RED TR BASE
LABOTEST-BB LTBB000666
P-CHLORO-O-TOLUIDINE
RED TR BASE
3-Chloro-6-aminotoluene
4-chloro-2-methyl-benzenamin
[EINECS(EC#)]

202-441-6
[Molecular Formula]

C7H8ClN
[MDL Number]

MFCD00007842
[Molecular Weight]

141.6
[MOL File]

95-69-2.mol
Chemical PropertiesBack Directory
[Appearance]

clear brown liquid
[Appearance]

The chloromethylanilines are colorless or white crystalline solids or liquids, some have a mild fishy odor.
[mp ]

29 °C
[bp ]

241 °C(lit.)
[density ]

1.19 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.583(lit.)
[Fp ]

211 °F
[storage temp. ]

2-8°C
[CAS DataBase Reference]

95-69-2(CAS DataBase Reference)
[NIST Chemistry Reference]

Benzenamine, 4-chloro-2-methyl-(95-69-2)
[EPA Substance Registry System]

95-69-2(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

T,N
[Risk Statements ]

R45:May cause cancer.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R68:Possible risk of irreversible effects.
[Safety Statements ]

S53:Avoid exposure-obtain special instruction before use .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

UN 2239 6.1/PG 3
[WGK Germany ]

3
[RTECS ]

XU5000000
[F ]

8-10
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[HS Code ]

29214300
[Safety Profile]

Confirmed carcinogen. Poison by ingestion and subcutaneous routes. Human mutation data reported. In the presence of copperpI) chloride catalyst decomposition occurs above 239'C. When heated to decomposition it emits toxic fumes of Cland NOx. See also other chloro toluidme entries.
[Hazardous Substances Data]

95-69-2(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
【Raw materials】

Glycine-->Benzoyl chloride-->o-Toluidine-->2-NITROSOTOLUENE-->2-Methylphenyl azide-->4-CHLORO-2-METHYLPHENYLBORONIC ACID-->1-Bromo-4-chloro-2-methylbenzene-->2-METHYLACETANILIDE-->5-Chloro-2-nitrotoluene
【Preparation Products】

4-CHLORO-2-METHYLBENZOIC ACID-->CHLOROMETHIURON-->4-CHLORO-2-METHYLPHENYL ISOTHIOCYANATE-->2-Chloro-6-methylaniline-->CHLORDIMEFORM-->4-Chloro-N-methylaniline
Hazard InformationBack Directory
[General Description]

Gray to white solid with a weak fishy odor. Sinks in water. Freezing point is 77°F.
[Reactivity Profile]

4-CHLORO-O-TOLUIDINE(95-69-2) is incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents. . A halogenated amine. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.
[Air & Water Reactions]

May be sensitive to prolonged exposure to air and light. Insoluble in water.
[Hazard]

Toxic by ingestion and inhalation. Probable carcinogen.
[Health Hazard]

Inhalation, ingestion, or skin contact causes bluish tint in fingernails, lips, and ears. Headache, drowsiness, and nausea also occur. Contact with eyes causes irritation.
[Potential Exposure]

Most of the isomers are used in dyestuff manufacture. The 3-chloro-para isomer is used to kill birds. It is marketed as pelleted bait for control of bird populations.
[Fire Hazard]

Special Hazards of Combustion Products: Toxic oxides of nitrogen and hydrochloric acid fumes may form.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN2239 Chlorotoluidines, solid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3429 Chlorotoluidines, liquid, Hazard Class: 6.1; Labels: 6.1- Poisonous materials
[Incompatibilities]

Incompatible with oxidizers, strong acids; chloroformates, and acid anhydrides, isocyanates, aldehydes forming fire and explosive hazards.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

5-Chloro-2-aminotoluene(95-69-2).msds
Spectrum DetailBack Directory
[Spectrum Detail]

4-Chloro-2-methylaniline(95-69-2) IR3
4-Chloro-2-methylaniline(95-69-2) IR2
4-Chloro-2-methylaniline(95-69-2) 13C NMR
4-Chloro-2-methylaniline(95-69-2) IR1
4-Chloro-2-methylaniline(95-69-2) MS
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

4-Chloro-2-methylaniline, 98%(95-69-2)
[Sigma Aldrich]

95-69-2(sigmaaldrich)
[TCI AMERICA]

2-Amino-5-chlorotoluene,>95.0%(GC)(95-69-2)
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