ChemicalBook--->CAS DataBase List--->97-72-3

97-72-3

97-72-3 Structure

97-72-3 Structure
IdentificationMore
[Name]

Isobutyric anhydride
[CAS]

97-72-3
[Synonyms]

2-METHYLPROPANOIC ANHYDRIDE
2-METHYLPROPIONIC ANHYDRIDE
ALPHA-METHYLPROPIONIC ANHYDRIDE
A-METHYLPROPIONIC ANHYDRIDE
BIS(2-METHYLPROPIONIC ACID) ANHYDRIDE
DIMETHYLACETIC ANHYDRIDE
ISOBUTYRIC ANHYDRIDE
(iso-C3H7CO)2O
1-Methylpropanoic anhydride
2-Methylpropanoic acid anhydride
2-methyl-propanoicacianhydride
2-methylpropanoicacidanhydride
anhydrideisobutyrique
Isobutryic anhydride
Isobutyric acid anhydride
isobutyricacidanhydride
Isobutyryl anhydride
isobutyrylanhydride
isobutyryloxide
Propanoicacid,2-methyl-,anhydride
[EINECS(EC#)]

202-603-6
[Molecular Formula]

C8H14O3
[MDL Number]

MFCD00008913
[Molecular Weight]

158.19
[MOL File]

97-72-3.mol
Chemical PropertiesBack Directory
[Appearance]

clear colorless liquid
[Melting point ]

-56 °C (lit.)
[Boiling point ]

182 °C (lit.)
[density ]

0.954 g/mL at 25 °C(lit.)
[vapor density ]

5.45 (vs air)
[vapor pressure ]

10 mm Hg ( 67 °C)
[refractive index ]

n20/D 1.406(lit.)
[Fp ]

152 °F
[storage temp. ]

Store at 0°C
[form ]

Liquid
[color ]

Clear colorless
[explosive limit]

1.09%, 87°F
[Water Solubility ]

decomposes
[Sensitive ]

Moisture Sensitive
[BRN ]

386267
[Dielectric constant]

13.9(20℃)
[Exposure limits]

ACGIH: TWA 10 ppm
NIOSH: TWA 10 ppm(30 mg/m3); STEL 15 ppm(45 mg/m3)
[InChI]

1S/C8H14O3/c1-5(2)7(9)11-8(10)6(3)4/h5-6H,1-4H3
[InChIKey]

LSACYLWPPQLVSM-UHFFFAOYSA-N
[SMILES]

CC(C)C(=O)OC(=O)C(C)C
[LogP]

1.1 at 25℃
[Uses]

Chemical intermediate.
[CAS DataBase Reference]

97-72-3(CAS DataBase Reference)
[NIST Chemistry Reference]

Propanoic acid, 2-methyl-, anhydride(97-72-3)
[EPA Substance Registry System]

97-72-3(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Skull and Crossbones (GHS06)
GHS05,GHS06
[Signal word ]

Danger
[Hazard statements ]

H301+H311-H314
[Precautionary statements ]

P270-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P361+P364
[Hazard Codes ]

C
[Risk Statements ]

R34:Causes burns.
R21/22:Harmful in contact with skin and if swallowed .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

2922
[WGK Germany ]

3
[RTECS ]

NQ5550000
[F ]

13-21
[Autoignition Temperature]

624 °F
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29159000
[Storage Class]

6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials
[Hazard Classifications]

Acute Tox. 3 Dermal
Acute Tox. 3 Oral
Skin Corr. 1B
[Hazardous Substances Data]

97-72-3(Hazardous Substances Data)
[Toxicity]

LD50 orally in Rabbit: 266 mg/kg LD50 dermal Rabbit 475 mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Dichloromethane-->Isobutyric acid-->Dicyclohexylcarbodiimide
[Preparation Products]

1-Boc-4-(4-methoxycarbonylphenyl)piperazine-->1-Boc-4-(4-carboxy-2-nitrophenyl)piperazine-->4-[4-(tert-Butoxycarbonyl)piperazino]benzoic acid-->tert-Butyl 4-(2-cyanophenyl)piperazine-1-carboxylate-->Ibudilast-->CITRONELLYL ISOBUTYRATE-->NERYL ISOBUTYRATE-->Sucrose acetate isobutyrate-->(S)-1-(3-Pyridyl)ethanol-->2,6-Dimethyl-3,5-heptanedione-->LINALYL ISOBUTYRATE-->1-(isobutyryl)pyrrolidin-2-one-->4-iodo-3-isopropyl-1H-pyrazolo[3,4-b]pyridine-->CHEMBRDG-BB 4002112
Hazard InformationBack Directory
[General Description]

A colorless liquid. Flash point 139°F. Burns skin and eyes. Vapors are heavier than air.
[Reactivity Profile]

ISOBUTYRIC ANHYDRIDE(97-72-3) reacts exothermically with water. The reactions are sometimes slow, but can become violent when local heating accelerates their rate. Acids accelerate the reaction with water. Incompatible with a cids, strong oxidizing agents, alcohols, amines, and bases.
[Air & Water Reactions]

Flammable. Reacts exothermically with water or moisture-containing materials to form isobutyric acid.
[Hazard]

Strong irritant to tissue.
[Health Hazard]

May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
[Fire Hazard]

Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
[Chemical Properties]

clear colorless liquid
[Definition]

ChEBI: An acyclic carboxylic anhydride of isobutyric acid. Metabolite observed in cancer metabolism.
[Preparation]

Isobutyric anhydride is prepared from iso-Butyryl chloride and Sodium acetate, or: from iso-Butyryl chloride and Butyric acid with a catalyst.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

isobutyric anhydride(97-72-3).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Isobutyric anhydride(97-72-3)MS
Isobutyric anhydride(97-72-3)1HNMR
Isobutyric anhydride(97-72-3)13CNMR
Isobutyric anhydride(97-72-3)IR1
Isobutyric anhydride(97-72-3)IR2
Isobutyric anhydride(97-72-3)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Isobutyric anhydride, 97%(97-72-3)
[Alfa Aesar]

Isobutyric anhydride, 97%(97-72-3)
[Sigma Aldrich]

97-72-3(sigmaaldrich)
[TCI AMERICA]

Isobutyric Anhydride,>95.0%(GC)(T)(97-72-3)
97-72-3 suppliers list
Company Name: Shanghai Shenju Chemical Co., LTD  Gold
Telephone: 13167128868 13661427209
Website: www.chemicalbook.com/supplier/25939348/
Company Name: Secco work (Beijing) chemical technology co., LTD  Gold
Telephone: 0566-8928158
Website: http://www.tjzkgh.com
Company Name: nanjing huayan chemical corp.  Gold
Telephone: 25-25-86661363 18951712139
Website: http://www.hychemm.com
Company Name: Shanghai Wei Nie Chemical Technology Co., Ltd.  Gold
Telephone: 13046668259
Website: https://www.chemicalbook.com/ShowSupplierProductsList1049667/0_EN.htm
Company Name: CHANGZHOU YUBO CHEMICAL CO.,LTD.  Gold
Telephone: 13961462977 15295086982
Website: www.czyubochem.com
Company Name: Hefei Ergao Chemical Co., Ltd  Gold
Telephone: 13349118557
Website: ergao8.com/gsjj.php?id=5
Company Name: Dalian Idery Biotechnology Co., Ltd.  Gold
Telephone: 15141125520 15141125520
Website: http://www.idery.net
Company Name: Boxuan Chemical (Shandong) Co., Ltd.  Gold
Telephone: 17653188518
Website:
Company Name: Meryer (Shanghai) Chemical Technology Co., Ltd.  
Telephone: 4006356688 18621169109
Website: www.x-labseek.com/
Company Name: Alfa Aesar  
Telephone: 400-6106006
Website: http://chemicals.thermofisher.cn
Company Name: TCI (Shanghai) Development Co., Ltd.  
Telephone: 021-67121386
Website: https://www.tcichemicals.com/CN/zh/
Company Name: ShangHai DEMO Chemical Co.,Ltd  
Telephone: 400-021-7337 2355568890
Website: www.demochem.com
Company Name: Beijing dtftchem Technology Co., Ltd.  
Telephone: 010-60275820 13031183356
Website: www.dtfchem.com
Company Name: Energy Chemical  
Telephone: 400-0056266
Website: www.energy-chemical.com
Company Name: JinYan Chemicals(ShangHai) Co.,Ltd.  
Telephone: 13817811078
Website: www.jingyan-chemical.com
Company Name: Jia Xing Isenchem Co.,Ltd  
Telephone: 0573-85285100 18627885956
Website: https://www.chemicalbook.com/ShowSupplierProductsList14265/0_EN.htm
Company Name: Shandong Xiya Chemical Co., Ltd  
Telephone: 13355009207 13355009207
Website: http://www.xiyashiji.com
Company Name: Syntechem Co.,Ltd  
Telephone:
Website: www.syntechem.com
Tags:97-72-3 Related Product Information
79-30-1 79-31-2 97-62-1 42558-54-3 65416-14-0 41519-23-7 84110-40-7 17980-47-1 513-44-0 115-11-7 78-83-1 103-60-6 103-59-3 547-63-7 2345-24-6 97-87-0 920-36-5 20279-29-2