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Benzylbutylphthalat Produkt Beschreibung

Benzyl butyl phthalate Struktur
85-68-7
CAS-Nr.
85-68-7
Bezeichnung:
Benzylbutylphthalat
Englisch Name:
Benzyl butyl phthalate
Synonyma:
BBP;CW17;mZFM;SF01;Sicol;Sicol 160;NCI-C54375;Unimoll BB;Paratinol BB;Palatinol BB
CBNumber:
CB2772688
Summenformel:
C19H20O4
Molgewicht:
312.36
MOL-Datei:
85-68-7.mol

Benzylbutylphthalat Eigenschaften

Schmelzpunkt:
<-35°C
Siedepunkt:
370°C
Dichte
1.1 g/mL at 25 °C(lit.)
Dampfdichte
10.8 (vs air)
Dampfdruck
0.16 mm Hg ( 150 °C)
Brechungsindex
n20/D 1.54(lit.)
Flammpunkt:
>230 °F
storage temp. 
room temp
Aggregatzustand
Oily Liquid
Farbe
Clear
Wichte
1.1
Wasserlöslichkeit
0.000269 g/100 mL
FreezingPoint 
-35℃
BRN 
2062204
Henry's Law Constant
(x 10-6 atm?m3/mol): 1.3 at 25 °C (calculated, Howard, 1989)
InChIKey
IRIAEXORFWYRCZ-UHFFFAOYSA-N
CAS Datenbank
85-68-7(CAS DataBase Reference)
NIST chemische Informationen
Phthalic acid, benzyl butyl ester(85-68-7)
IARC
3 (Vol. Sup 7, 73) 1999
EPA chemische Informationen
Butyl benzyl phthalate (85-68-7)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher T,N
R-Sätze: 61-50/53-62
S-Sätze: 53-45-60-61
RIDADR  UN 3082 9/PG 3
WGK Germany  2
RTECS-Nr. TH9990000
Selbstentzündungstemperatur 450 °F
TSCA  Yes
HazardClass  9
PackingGroup  III
HS Code  29173400
Giftige Stoffe Daten 85-68-7(Hazardous Substances Data)
Toxizität Acute oral LD50 for guinea pigs 13,750 mg/kg, mice 4,170 mg/kg, rats 2,330 mg/kg (quoted, RTECS, 1985).
Bildanzeige (GHS)
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H360 Kann die Fruchtbarkeit beeinträchtigen oder das Kind im Mutterleib schädigen. Fertility (Fruchtbarkeit) Kategorie 1 Achtung
H400 Sehr giftig für Wasserorganismen. Kurzfristig (akut) gewässergefährdend Kategorie 1 Warnung P273, P391, P501
H410 Sehr giftig für Wasserorganismen mit langfristiger Wirkung. Langfristig (chronisch) gewässergefährdend Kategorie 1 Warnung P273, P391, P501
Sicherheit
P201 Vor Gebrauch besondere Anweisungen einholen.
P202 Vor Gebrauch alle Sicherheitshinweise lesen und verstehen.
P273 Freisetzung in die Umwelt vermeiden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P308+P313 BEI Exposition oder falls betroffen: Ärztlichen Rat einholen/ärztliche Hilfe hinzuziehen.
P405 Unter Verschluss aufbewahren.
P501 Inhalt/Behälter ... (Entsorgungsvorschriften vom Hersteller anzugeben) zuführen.

Benzylbutylphthalat Chemische Eigenschaften,Einsatz,Produktion Methoden

ERSCHEINUNGSBILD

FARBLOSE, öLIGE FLüSSIGKEIT.

CHEMISCHE GEFAHREN

Zersetzung beim Verbrennen unter Bildung giftiger Rauche. Reagiert mit Oxidationsmitteln.

ARBEITSPLATZGRENZWERTE

TLV nicht festgelegt (ACGIH 2005).
MAK nicht festgelegt (DFG 2005).

AUFNAHMEWEGE

Aufnahme in den Körper durch Inhalation des Aerosols und durch Verschlucken.

INHALATIONSGEFAHREN

Verdampfung bei 20°C vernachlässigbar; eine gesundheitsschädliche Partikelkonzentration in der Luft kann jedoch beim Versprühen schnell erreicht werden.

WIRKUNGEN NACH WIEDERHOLTER ODER LANGZEITEXPOSITION

Tierversuche zeigen, dass die Substanz möglicherweise fruchtbarkeitsschädigend oder entwicklungsschädigend wirken kann.

LECKAGE

Persönliche Schutzausrüstung: Atemschutzfilter für organische Gase und Dämpfe. NICHT in die Umwelt gelangen lassen. Ausgelaufene Flüssigkeit möglichst in abdichtbaren Behältern sammeln. Reste mit Sand oder inertem Absorptionsmittel aufnehmen und an einen sicheren Ort bringen.

R-Sätze Betriebsanweisung:

R61:Kann das Kind im Mutterleib schädigen.
R50/53:Sehr giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
R62:Kann möglicherweise die Fortpflanzungsfähigkeit beeinträchtigen.

S-Sätze Betriebsanweisung:

S53:Exposition vermeiden - vor Gebrauch besondere Anweisungen einholen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
S60:Dieses Produkt und sein Behälter sind als gefährlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.

Chemische Eigenschaften

Benzyl butyl phthalate is a clear, oily liquid with a slight odor.

Verwenden

A phthalate metabolite with genotoxic effect.

Verwenden

Benzyl n-butyl phthalate is used as a plasticizer for vinyl foams. It is also used in floor tiles, in traffic cones, food conveyor belts and artificial leather. Further, it acts as an organic intermediate. In addition to this, it is used as a perfume fixative.

Vorbereitung Methode

BBP is manufactured by the sequential addition of butanol and benzyl chloride to phthalic anhydride. It is used as a plasticizer for polyvinyl chloride plastics, particularly vinyl floor tile, vinyl leather, and cloth coating.

Allgemeine Beschreibung

A clear colorless liquid with a mild odor. Primary hazard is to the environment. Immediate steps should be taken to limit spread to the environment. Easily penetrates the soil to contaminate groundwater and nearby waterways.

Air & Water Reaktionen

Slightly soluble in water and slightly denser than water.

Reaktivität anzeigen

Benzyl butyl phthalate is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Can generate electrostatic charges. [Handling Chemicals Safely 1980. p. 250].

Health Hazard

Prolonged contact with liquid causes some irritation of eyes and skin.

Health Hazard

The acute oral toxicity of this compoundis low. It is, however, more toxic, thanthe phthalic acid dialkyl esters. The toxic symptomsinclude nausea, dizziness, somnolence, andhallucination. The oral LD50 value in mice iswithin the range of 4200 mg/kg. Oral admin istration produced reproductive toxicity inmale mice (paternal effects). At a dose of2% in diet, it caused maternal and develop mental toxicity and an increased incidence.

Brandgefahr

Special Hazards of Combustion Products: Irritating vapors of unburned chemical may form in fires.

mögliche Exposition

Benzyl butyl phthalate is used as a plasticizer for polyvinyl and cellulosic resins. It is also used as an organic intermediate. Incompatibilities: Incompatible with strong acids; nitrates, oxidizers. Destructive to rubber and paint.

Carcinogenicity

The NTP examined the carcinogenicity of BBP in rats and mice. Groups of 50 male and female rats and mice were exposed to BBP via the diet at levels of 0, 6000, or 12,000 ppm (0, 300, and 600 mg/kg for rats and 0, 780, or 1560 mg/kg for mice). Male and female mice and female rats were exposed for 103 weeks. Due to poor survival, all males were sacrificed at weeks 29–30; this part of the study was later repeated. No treatmentrelated neoplasms were observed in mice. Survival was not affected. A dose-dependent reduction in body weight in both sexes was the only treatment-related effect observed in this study. Furthermore, nonneoplastic changes were all within the normal limits of incidence for B6C3F1 mice. The NTP concluded that under the conditions of the bioassay, BBP “was not carcinogenic for B6C3F1 mice of either sex.” An increased incidence of mononuclear cell leukemias was observed in the high-dose female rats. No other treatmentrelated findings were observed. The NTP concluded that BBP was “probably carcinogenic for female F344/N rats, causing an increased incidence of mononuclear cell leukemias”. The biological significance of this finding is uncertain as the background incidence of this tumor type in F344 rats is quite high.

Source

Detected in distilled water-soluble fractions of new and used motor oil at concentrations of 8.6–13 and 14–17 μg/L, respectively (Chen et al., 1994)

Environmental Fate

Biological. In anaerobic sludge diluted to 10%, benzyl butyl phthalate biodegraded to monobutyl phthalate, which subsequently degraded to phthalic acid. After 40 d, >90% of applied amount degraded (Shelton et al., 1984). When benzyl butyl phthalate (5 and 10 mg/L) was statically incubated in the dark at 25 °C with yeast extract and settled domestic wastewater inoculum, complete biodegradation with rapid adaptation was observed after 7 d (Tabak et al., 1981). In activated sludge, the half-life was 2 h (Saeger and Tucker, 1976). Gledhill et al. (1980) reported half-lives of 2 and <4 d for benzyl butyl phthalate in river water and a lake water microcosm, respectively. Aerobic degradation of benzyl butyl phthalate by acclimated soil and activated sewage sludge microbes was studied using an acclimated shake flask CO2 evolution test. After 28 d, loss of benzyl butyl phthalate (primary degradation) was 43%, with a lag phase of 15.6 d, and ultimate biodegradation (CO2 evolution) was 43%. The half-life under these conditions was 19.4 d (Sugatt et al., 1984).
Surface Water. The biological half-life of benzyl butyl phthalate in river water was determined to be 2 d (Saeger and Tucker, 1976).
Photolytic. Gledhill et al. (1980) reported the photolytic half-life is >100 d.
Chemical/Physical. Benzyl butyl phthalate initially hydrolyzes to butyl hydrogen phthalate. This compound undergoes additional hydrolysis yielding o-phthalic acid, 1-butanol, and benzyl alcohol (Kollig, 1993). Gledhill et al. (1980) reported the hydrolysis half-life is >100 d.

Solubility in organics

4.05 (Veith et al., 1980)
4.73 (Ellington and Floyd, 1996)
4.80 (Hirzy et al., 1978)
4.91 at 20 °C (shake flask-UV spectrophotometry, Leyder and Boulanger, 1983)
4.77 (shake flask-GC, Gledhill et al., 1980)

Versand/Shipping

UN3082 Environmentally hazardous substances, liquid, n.o.s., Hazard class: 9; Labels: 9—Miscellaneous hazardous material, Technical Name Required

Waste disposal

Atomize into an incinerator together with a flammable solvent.

Benzylbutylphthalat Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Benzylbutylphthalat Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 236)Lieferanten
Firmenname Telefon Fax E-Mail Land Produktkatalog Edge Rate
Wuhan Sinocon New chemical Materials Co.,ltd. 027-83229541
027-83096702 whsinocon@aliyun.com China 127 62
J & K SCIENTIFIC LTD. 010-82848833- ;010-82848833-
86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 21-61259100-
86-21-61259102 sh@meryer.com China 40264 62
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30159 84
TCI (Shanghai) Development Co., Ltd. 021-67121386 / 800-988-0390
021-67121385 Sales-CN@TCIchemicals.com China 24555 81
Energy Chemical 021-58432009-
021-58436166 sales8178@energy-chemical.com China 43430 61
Chemsky(shanghai)International Co.,Ltd. 021-50135380
shchemsky@sina.com China 32358 50
Chengdu XiYa Chemical Technology Co., Ltd. ;
0539-6365991 sale@xiyashiji.com;3007716753@qq.com China 10078 57
Syntechem Co.,Ltd Please Email
E-Mail Inquiry info@syntechem.com China 13009 57
BEST-REAGENT 400-1166-196;028-84555506- ;028-84555506-
cdhxsj@163.com;1955352637@qq.com;cdhxsj@163.com China 11718 57

85-68-7(Benzylbutylphthalat)Verwandte Suche:


  • SANTICIZER(R) 160
  • PHTHALIC ACID, BENZYLBUTYL ESTER
  • butyl phenylmethyl 1,2-benzenecarboxylate
  • Benzyl butyl phthalate,100 μL/mL in MeOH
  • Paratinol BB
  • C6H4(COOCH2C6H5)COO(CH2)3CH3
  • 1-O-butyl 2-O-(phenylmethyl) benzene-1,2-dicarboxylate
  • benzene-1,2-dicarboxylic acid O2-(benzyl) ester O1-butyl ester
  • O1-Butyl O2-(phenylmethyl) benzene-1,2-dicarboxylate
  • Butyl benzyl phthalate 1g [85-68-7]
  • Butyl benzyl phthalate 5g [85-68-7]
  • Butyl benzyl phthalate 10g [85-68-7]
  • Butyl phenylmethyl 1,2-benzenedicarboxy
  • Benzyl Butyl Phthalate Standard
  • Benzyl butyl ester
  • BBP benzyl butyl phtalate
  • PHTHALIC ACID BENZYL N-BUTYL ESTER
  • N-BUTYL BENZYL PHTHALATE
  • 1-Benzyl 2-butyl phthalate
  • Benzyl-butylester kyseliny ftalove
  • NCI-C54375
  • Palatinol BB
  • phthalicacidbenzylesterbutylester
  • Santicizer 160
  • Sicol
  • Sicol 160
  • Unimoll BB
  • BENZYL BUTYL PHTHALATE PESTANAL, 250 MG
  • BENZYLBUTYLPHTHALATE, 1000MG, NEAT
  • Benyl n-butyl phthalate
  • Butyl phenylmethyl 1,2-benzenedicarboxylate
  • butyl benzyl phthlate
  • BUTYL BENZYL PHTHALATE
  • BBP
  • BENZYL N-BUTYL PHTHALATE
  • BENZYL BUTYL PHTHALATE
  • 1,2-benzenedicarboxylic acid butyl phenylmethyl ester
  • BUTYLBENZYLPHTHALATEESTER
  • BUTYL-N-BENZYLPHTHALATE
  • MONO-BENZYL-BUTYL-PHTHALATE
  • Phthalsurebenzyl-n-butylester
  • 1,2-Benzenedicarboxylic Acid 1-Butyl 2-(PhenylMethyl) Ester
  • Phthalic Acid Benzyl Butyl Ester BBP
  • Benzyl butyl phthalate solution
  • Butyl Benzyl Phthalate Acid Ester in Methanol Certified Reference Material
  • Benzyl n-butyl phthalate (BBP)
  • Benzyl butyl phthalate 98%
  • Anti-SF1, N-Terminal antibody produced in rabbit
  • CW17
  • mammalian branch point binding protein mBBP
  • mZFM
  • SF01
  • Benzyl n-butyl phthalate Solution, 100ppm
  • Benzyl n-butyl phthalate (BBP) Solution, 100ppm
  • BBP Standard
  • Benzyl butyl phthalate @5.0 mg/mL in MeOH
  • n-Butyl benzyl phthalate@100 μg/mL in Methanol
  • Benzyl Butyl Phthalate @100 μg/mL in MeOH
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