ChemicalBook >> CAS DataBase List >>Schwartz Reagent
Schwartz Reagent
- CAS No.
- 37342-97-5
- Chemical Name:
- Schwartz Reagent
- Synonyms
- SCHWARTZ REAGENT;SCHWARTZ'S REAGENT;ZIRCONOCENE CHLORIDE HYDRIDE;BIS(CYCLOPENTADIENYL)ZIRCONIUM(IV) CHLORIDE HYDRIDE;BIS(CYCLOPENTADIENYL)ZIRCONIUM HYDRIDOCHLORIDE;Schwartz's;oride hydride;)zirconium chL;SCHWART'S REAGENT;SCHWARTZ' REAGENT
- CBNumber:
- CB00124787
- Molecular Formula:
- C10H11ClZr
- Molecular Weight:
- 257.87
- MDL Number:
- MFCD02089401
- MOL File:
- 37342-97-5.mol
- MSDS File:
- SDS
Last updated:2023-10-21 14:17:13
| Melting point | 300 °C |
|---|---|
| storage temp. | Keep in dark place,Inert atmosphere,2-8°C |
| form | Powder |
| color | off-white |
| Water Solubility | reacts |
| Sensitive | Light, Air & Moisture Sensitive |
| Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| Merck | 14,8396 |
| Exposure limits |
ACGIH: TWA 5 mg/m3; STEL 10 mg/m3 NIOSH: IDLH 25 mg/m3; TWA 5 mg/m3; STEL 10 mg/m3 |
| CAS DataBase Reference | 37342-97-5(CAS DataBase Reference) |
| FDA UNII | S84D01XQGL |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H261-H314 | |||||||||
| Precautionary statements | P223-P231+P232-P260-P280-P303+P361+P353-P305+P351+P338 | |||||||||
| Hazard Codes | F,C | |||||||||
| Risk Statements | 11-15-34 | |||||||||
| Safety Statements | 16-26-27-36/37/39-8-45 | |||||||||
| RIDADR | UN 3131 4.3/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 8-10-23 | |||||||||
| HazardClass | 4.3 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29319090 | |||||||||
| NFPA 704 |
|
Schwartz Reagent price More Price(22)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 223670 | Bis(cyclopentadienyl)zirconium(IV) chloride hydride 95% | 37342-97-5 | 1g | $42.6 | 2024-03-01 | Buy |
| Sigma-Aldrich | 223670 | Bis(cyclopentadienyl)zirconium(IV) chloride hydride 95% | 37342-97-5 | 5g | $143 | 2024-03-01 | Buy |
| TCI Chemical | Z0010 | Zirconocene Chloride Hydride >96.0%(T) | 37342-97-5 | 1g | $39 | 2024-03-01 | Buy |
| TCI Chemical | Z0010 | Zirconocene Chloride Hydride >96.0%(T) | 37342-97-5 | 5g | $118 | 2024-03-01 | Buy |
| Alfa Aesar | L15164 | Bis(cyclopentadienyl)zirconium hydridochloride, 95% | 37342-97-5 | 1g | $38.5 | 2023-06-20 | Buy |
Schwartz Reagent Chemical Properties,Uses,Production
Physical properties
Schwartz Reagent is a white microcrystalline powder. Under the influence of light or heat the color changes to pink, then gradually to dark red.It is sensitive to moisture; it is virtually insoluble in the usual organic solvents such as ethers, consistent with its polymeric character.
Uses
Schwartz Reagent is named after Jeffrey Schwartz, a chemistry professor at Princeton University. This metallocene is used in organic synthesis for various transformations of alkenes and alkynes.
Preparation
Schwartz Reagent can be purchased or readily prepared by reduction of zirconocene dichloride with lithium aluminium hydride:
(C5H5)2ZrCl2 + 1⁄4 LiAlH4 → (C5H5)2ZrHCl + 1⁄4 LiAlCl4
This reaction also affords (C5H5)2ZrH2, which is treated with methylene chloride to give Schwartz Reagent.
Reactions
Schwartz's reagent reacts with alkenes and alkynes via the process called hydrozirconation which formally results in the addition of the Zr-H bond across the C=C or C≡C bond.
Structure and conformation
Schwartz Reagent adopts the usual "clam-shell" structure seen for other Cp2MXn complexes.The dimetallic structure has been confirmed by Microcrystal electron diffraction.The results are consistent with FT-IR spectroscopy, which established that the hydrides are bridging. Solid state NMR spectroscopy also indicates a dimeric structure.
Schwartz Reagent Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
Global( 186)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 16224 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21687 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32715 | 60 |
| career henan chemical co | +86-0371-86658258 15093356674; | sales@coreychem.com | China | 29914 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
| Zhengzhou HQ Material CO.,LTD. | +86-371-55919009 +8615225108189 | sale1@hqmat.com | China | 651 | 58 |
| Wuhan Pengo Technology.,Ltd. | +86-27-81330736 +86-13628634921 | sunny.w@boronicgroup.com | CHINA | 171 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39916 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49391 | 58 |
View Lastest Price from Schwartz Reagent manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-12 | Bredereck's reagent
5815-08-7
|
US $11.00-190.00 / g | 25g | 0.90 | 200kg | Shanghai UCHEM Inc. | |
 |
2024-01-14 | Burgess reagent
29684-56-8
|
US $5.00-0.50 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
 |
2019-07-12 | EATON'S REAGENT
39394-84-8
|
US $1.00 / KG | 1KG | 99% | 25kg | Career Henan Chemical Co |
-
- Bredereck's reagent
5815-08-7
- US $11.00-190.00 / g
- 0.90
- Shanghai UCHEM Inc.
-
- Burgess reagent
29684-56-8
- US $5.00-0.50 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
-
- EATON'S REAGENT
39394-84-8
- US $1.00 / KG
- 99%
- Career Henan Chemical Co
37342-97-5(Schwartz Reagent)Related Search:
Di(cyclopentadienyl)zirconium(IV) chloride hydride
bis(3-cyclopentadienyl)chlorohydrurozirconium
Bis(cyclopentadienyl)zirconium chloride hydride (Schwartz's Reagent),
Bis(cyclopentadienyl)zirconiumchloridehydride~Schwartz'sReagent~Zirconocenehydrochloride
Zirconocenechloridehydride,95%
Bis(cyclopentadienyl)zirconiumchloridehydride(Schwartz'sReagent),95%
Di(cyclopentadienyl)zirconium(IV) chloride hydride, Schwartz reagent, Zirconocene chloride hydride
Schwartz's
Bis(cyclopentadienyl)zirconium chloride hydride,95%
Schwartz’ reagent, Zirconocene chloride hydride
chloridobis(η5-cyclopentadienyl)hydridozirconium
zirconocene hydride
Bis(cyclopentadienyl)zirconiuM chloride hydride, 95% 5GR
Bis(cyclopentadienyl)zirconiuM chloride hydride,95% Schwartz's Reagent
Zirconocene(IV) chloride hydride
Bis(cyclopentadienyl)zirconiuM(IV) chloride hydride 95%
BIS(CYCLOPENTADIENYL)ZIRCONIUM CHLORIDE HYDRIDE
DI(CYCLOPENTADIENYL)ZIRCONIUM CHLORIDE HYDRIDE
SCHWART'S REAGENT
SCHWARTZ' REAGENT
ZIRCONOCENE HYDROCHLORIDE
Bis(cyclopentadienyl)chlorohydrozirconium
Bis(cyclopentadienyl)zirconiumchloridehydride~Schwartz'sReagent~Zirconocenehydroc
Zriconocene hydrochloride
Bis(cyclopentadienyl)zirconium(IV) Chloride Hydride [Zirconocene Dichloride]
Zirconocene chloride hydride, 94%, reagent grade
oride hydride
)zirconium chL
Bis(cyclopentadienyl)zirconium chloride hydride ISO 9001：2015 REACH
Zirconium, chlorobis(h5-2,4-cyclopentadien-1-yl)hydro-
Supply best quality /favorable price Bis(cyclopentadienyl)zirconium chloride hydride
ZIRCONOCENE CHLORIDE HYDRIDE
BIS(CYCLOPENTADIENYL)ZIRCONIUM HYDRIDOCHLORIDE
BIS(CYCLOPENTADIENYL)ZIRCONIUM(IV) CHLORIDE HYDRIDE
SCHWARTZ REAGENT
SCHWARTZ'S REAGENT
Zirconium, chlorobis(η5-?2,?4-?cyclopentadien-?1-?yl)?hydro-
Bis (cyclopentadiene) zirconium dichloride
cyclopenta-1,3-diene hydride zirconium chloride
Bis(cyclopentadienyl)zirconium chloride hydride (Schwartz's Reagent)
37342-97-5
C10H11ClZr
C5H52ZrClH
Reduction
Transition Metal Compounds
Titanocene, etc.
Classes of Metal Compounds
Zr (Zirconium) Compounds
Metallocenes
Metal Hydrides
Synthetic Reagents
Zr
Classes of Metal Compounds
Metallocenes
Reduction
Synthetic Organic Chemistry
Titanocene, etc.
Transition Metal Compounds