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Mancozeb

CAS No.
8018-01-7
Chemical Name:
Mancozeb
Synonyms
DITHANE;mancozebe;fore;MANCO;f2966;MANZEB;MICENE;C15225;Manaeb;marzin
CBNumber:
CB0290308
Molecular Formula:
C4H8MnN2S4Zn
Molecular Weight:
332.71
MDL Number:
MFCD00078616
MOL File:
8018-01-7.mol
Last updated:2023-11-02 17:49:29

Mancozeb Properties

Melting point 192-194°C
Density 1.92 g/cm3
vapor pressure Negligible at 20 °C
Flash point 138 °C
storage temp. APPROX 4°C
solubility DMSO: 1 mg/mL (1.51 mM); Water: < 0.1 mg/mL (insoluble)
Water Solubility 6-20 mgl-1 (20 °C)
form Solid:particulate/powder
Merck 13,5738
LogP 1.8-2.3 at 20℃ and pH6-10
Dissociation constant 12.09 at 20℃
CAS DataBase Reference 8018-01-7(CAS DataBase Reference)
EWG's Food Scores 6
FDA UNII R0HY55EB9E
Proposition 65 List Mancozeb
Pesticides Freedom of Information Act (FOIA) Mancozeb
EPA Substance Registry System Mancozeb (8018-01-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS08,GHS07,GHS09
Signal word  Danger
Hazard statements  H317-H351-H360D-H373-H410
Precautionary statements  P261-P272-P280-P302+P352-P333+P313-P321-P363-P501-P201-P202-P281-P308+P313-P405-P501-P260-P314-P501-P273-P391-P501
Hazard Codes  Xi,N,Xn
Risk Statements  37-43-50-63
Safety Statements  8-24/25-46-61-36/37
RIDADR  UN 2210
RTECS  ZB3200000
HazardClass  9
PackingGroup  III
HS Code  29309090
Toxicity LC50 (48-hour) for carp 4.0 mg/L (Hartley and Kidd, 1987), catfish 5.2 mg/L, goldfish 9.0 mg/L (21°C) and rainbow trout 2.2 mg/L (17°C) (Worthing and Hance, 1991); acute oral LD50 for rats >8,000 mg/kg (Hartley and Kidd, 1987), mouse 600 mg/kg (RTECS, 1985).

Mancozeb price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC M162200 Mancozeb(TechnicalGrade) 8018-01-7 2g $275 2021-12-16 Buy
Adipogen Life Sciences CDX-M0158-M500 Mancozeb ≥94%(HPLC) 8018-01-7 500mg $38 2021-12-16 Buy
ChemScene CS-0012867 Mancozeb 8018-01-7 500mg $50 2021-12-16 Buy
ChemScene CS-0012867 Mancozeb 8018-01-7 1g $90 2021-12-16 Buy
Medical Isotopes, Inc. 41235 Mancozeb(TechnicalGrade) 8018-01-7 1g $625 2021-12-16 Buy
Product number Packaging Price Buy
M162200 2g $275 Buy
CDX-M0158-M500 500mg $38 Buy
CS-0012867 500mg $50 Buy
CS-0012867 1g $90 Buy
41235 1g $625 Buy

Mancozeb Chemical Properties,Uses,Production

Description

Mancozeb is a fungicide of the ethylene-bis-dit-hiocarbamate group. It is present in Rondo-M with pyrifenox. Occupational exposure occurs mainly in agricultural workers, in vineyard workers or in florists.

Chemical Properties

Grayish-yellow powder

Uses

Fungicide.

Uses

Mancozeb is a mixture of Maneb (M163500) and Zineb, a manganese and zinc (1:1) complex mixture with the ethylene bis(dithiocarbamate) anionic ligand. Mancozeb is a foliate fungicide used to protect cr ops in agriculture. Mancozeb has a broader and more effective fungacidal activity than either of its component on their own. Mancozeb also significantly enhances the copper activity against several ba cteriosis.

Uses

Fungicide used as a foliar or seed treatment to control a wide variety of pathogens in many field crops, fruits, ornamentals and vegetables.

Uses

Mancozeb is a contact fungicide that provides protection against a wide variety of fungal diseases (including rots, leaf spot, blight, rust, downy mildew, scab, etc.) in field crops, fruits, vines, vegetables, ornamentals, potatoes, turf, berries, rice, citrus and cereals. Mancozeb is a mixture containing zineb and maneb as active ingredients.

Agricultural Uses

Fungicide: Mancozeb is used to control a wide variety of fungal diseases, including potato blight, leaf spot, scab (on apples and pears), and rust (on roses). It is used on fruits, vegetables, nuts and field crops, and many more. It is also used as a seed treatment of cotton, potatoes, corn, safflower, sorghum, peanuts, tomatoes, flax, and cereal grains.

Trade name

ACROBAT® (mancozeb + dimethomorph); ASHLAND SOLACE® (cymoxanil + mancozeb); CARMAZINE®; CUPROFIX®; DITHANE®; EMCARB® (mancozeb + carbendez); EMTHANE M-15®; EVOLVE®; F 2966®; FORE®; FORMEC®; GAUCHO® (imidacloprid + mancozeb); GAVEL® (mancozeb + zoxamide); GREEN-DAISEN M®; KARAMATE®; KENCOZEB®; MANCOFOL®; MANOSEB®; MANTOX®; MANZATE 200®; MANZEB®; MANZIN 80®; MARZIN®; MAXIM®; MILOR®; NEMISPOR®; PACE® fungicide (mixture of mancozeb and metalaxyl); PENNCOZEB®; POLICAR®; TRIZIMAN®; TRIZIMAN-D®; VONDOZEB PLUS®; ZIMANAT®; ZIMMAN-DITHANE®; ZIMANEB®

Contact allergens

Mancozeb is a fungicide of the ethylene-bis-dithiocarbamate group. It is present in Rondo-M? with pyrifenox.Occupational exposure occurs mainly in agriculturalworkers, in vineyard workers, or in florists.

Potential Exposure

Mancozeb is a dithiocarbamate fungicide. It is used to control a wide variety of fungal diseases, including potato blight, leaf spot, scab (on apples and pears), and rust (on roses). It is used on fruits, vegetables, nuts and field crops, and many more. It is also used as a seed treatment of cotton, potatoes, corn, safflower, sorghum, peanuts, tomatoes, flax, and cereal grains

Environmental Fate

Plant. Undergoes metabolism in plants to ethyl thiourea, ethylene thiuram disulfide, thiuram monosulfide and sulfur (Hartley and Kidd, 1987).
Chemical/Physical. Decomposes in acids releasing carbon disulfide. In oxygenated waters, mancozeb degraded to ethylene thiuram monosulfide, ethylene diisocyanate, ethylene thiourea, ethylenediamine and sulfur (Worthing and Hance, 1991).

Metabolic pathway

Mancozeb is a mixture containing maneb and zineb as the active ingredients. Maneb and zineb and other alkylenebis( dithiocarbamate) fungicides are degraded and metabolised via a common pathway. The primary degradation reaction of maneb and zineb in water, soil, plants and animals involves the initial dissociation of the metal complex and decomposition to numerous degradation products including ethylenethiourea (ETU) and ethyleneurea (EU) as major products. See zineb and maneb summaries for detailed descriptions.

Shipping

UN2771 Dithiocarbamate and Thiocarbamate pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1- Poisonous materials.

Toxicity evaluation

The mechanism of toxicity for MZ is similar to other EBDC fungicides like maneb. EBDC are able to modify and inactivate redox-sensitive proteins. Because of the thiol reactivity of these compounds, redox-sensitive processes like transcription, translation, and other metabolic processes can be altered, resulting in cytotoxicity. It is due to this multitarget mode of action that MZ and other EBDC compounds are used in fungicide resistance management programs. In contrast to other fungicidal agents, in over 40 years of use, resistance to any of the EBDC compounds has never developed. MZ has also been reported to cause oxidative stress, DNA damage, and apoptosis in rat cells. Additionally, like all EBDC, MZ can act as a chelating agent, allowing it to interfere with enzymes that contain metals which are essential for activity, like dopamine b-hydroxylase.

Degradation

Mancozeb (1) was readily hydrolysed in neutral and alkaline solution with DT9 values of 20 days (pH 5), 17 hours (pH 7) and 34 hours (pH 9) (PM). See zineb and maneb summaries for the hydrolytic degradation pathway.

Incompatibilities

Combustible material. Dust may form explosive mixture in air. Decomposes in temperatures above 170C. Keep away from water, acid, oxidizing materials. Dithiocarbamate esters are combustible. They react violently with powerful oxidizers such as calcium hypochlorite. Poisonous gases are generated by the thermal decomposition of Dithiocarbamate compounds, including carbon disulfide, oxides of sulfur, oxides of nitrogen, hydrogen sulfide, ammonia, and methylamine. Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Flammable gases are generated by the combination of dithiocarbamate with aldehydes, nitrides, and hydrides. Dithiocarbamate are incompatible with acids, peroxides, and acid halides. Corrosive to iron, copper brass, and zinc metals, especially in the presence of moisture. Contact with lime, moisture can cause decomposition. Decomposes on prolonged storage. Degradation produces ethylene thiourea.

Waste Disposal

Disposal Method Suggested: Generators of waste (equal to or greater than 100 kg/mo) containing this contaminant, EPA hazardous waste number N450, must conform to USEPA regulations for storage, transportation, treatment, and disposal of waste. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Dispose of contents and container to an approved waste disposal plant. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office. All federal, state, and local environmental regulations must be observed. Do not discharge into drains or sewers. A potential candidate for liquid injection incineration at a temperature range of 650 to 1600C and a residence time 0.1 to 2 seconds. Also, a potential candidate for rotary kiln incineration at a temperature range of 820 to 1600C and residence times of seconds for liquids and gases, and hours for solids.

Global( 256)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd
+86-13288715578 +86-13231137666 sales@hbmojin.com China 12409 58
Hebei Dangtong Import and export Co LTD
+8615632927689 admin@hbdangtong.com China 1000 58
Anhui Yiao New Material Technology Co., Ltd
+86-199-55145978 +8619955145978 sales8@anhuiyiao.com China 253 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21703 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +86-18949832763 info@tnjchem.com China 2989 55
Shanxi Naipu Import and Export Co.,Ltd
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18871490254 linda@hubeijusheng.com CHINA 28180 58
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View Lastest Price from Mancozeb manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Mancozeb pictures 2024-03-19 Mancozeb
8018-01-7
US $10.00-1.00 / kg 1kg 99% 20tons Hebei Dangtong Import and export Co LTD
Mancozeb pictures 2024-03-19 Mancozeb
8018-01-7
US $4360.00-3800.00 / Tons 1Tons 99.99% 200Tons Hebei Dangtong Import and export Co LTD
Mancozeb pictures 2023-11-02 Mancozeb
8018-01-7
US $0.00 / KG 1KG 99% 1 ton Anhui Yiao New Material Technology Co., Ltd
  • Mancozeb pictures
  • Mancozeb
    8018-01-7
  • US $10.00-1.00 / kg
  • 99%
  • Hebei Dangtong Import and export Co LTD
  • Mancozeb pictures
  • Mancozeb
    8018-01-7
  • US $4360.00-3800.00 / Tons
  • 99.99%
  • Hebei Dangtong Import and export Co LTD
  • Mancozeb pictures
  • Mancozeb
    8018-01-7
  • US $0.00 / KG
  • 99%
  • Anhui Yiao New Material Technology Co., Ltd
DITHANE(R) CRITTOX FORE(R) AIMCOZEB ((1,2-Ethanediylbis(carbamodithioato)))manganese mixture with ((1,2-ethandiylbis(carbamodithioate)))zinc TRIMANOC(R) TRIDEX(R) FUNGICIDE VONDOZEB MANZATE(R) MANZEB MANGANESE-ZINC ETHYLENEBIS(DITHIOCARBAMATE) MANCO MANCOZEB MANCOZEB STANDARD MANEX II ZINC AND MANGANESE ETHYLENE-BISDITHIOCARBAMATE COORDINATION PRODUCT MANCOZEB TEC MANCOZEB TECHNICAL MIXTURE, PESTANAL(MAN Ethylene bis(dithiocarbamic acid), manganese salt, zinc ion coordination product PENNCOZEB(R) PENNFLUID(R) MICENE ((1,2-ethanediylbis(carbamodithioato))(2-))manganesemixturewith(((1,2-ethan ((1,2-ethanediyllbis(carbamodithioato))(2-))manganesezincsalt [[1,2-Ethanediylbis(carbamodithioate)](2-)]manganesezincsalt ziman-dithane zimaneb zincmanganeseethylenebisdithiocarbamate zineb-manebmixt. Manganese, 2-(dithiocarboxy)aminoethylcarbamodithioato(2-)-.kappa.S,.kappa.S-, mixt. with 2-(dithiocarboxy)aminoethylcarbamodithioato(2-)-.kappa.S,.kappa.Szinc Mzncozeb FREE SAMPLE NCV MANCOZEB 750DF blecar mn ethylenebis(dithio-carbamic aci manganese zinc complex Mancozeb W.P. Mancozeb suspension C15225 Mancozeb,Manganese Zinc ethylenebis(dithiocarbamate) [N-[2-[(dithiocarboxy)aMino]ethyl]carbaModithioato(2-)-κS,κS']Manganese Mixture with [N-[2-[(dithiocarboxy)aMino]ethyl]carbaModithioato(2-)-κS,κS']zinc Diesen M Indofil M 45 KaraMate N Liro Manzeb Mancosan Mancozan Mankogal Manzidan Milcozebe Mycotrin Novozir MN Pencozeb Pennfluid Sakozeb Blue Sandozeb Pepite acariem agrox16d blecarmn Carmazine crittoxmz