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2-Phenylphenol

Chemical properties uses Identification test Content analysis Toxicity Usage limit Production method Hazards & Safety Information
2-Phenylphenol
2-Phenylphenol structure
CAS No.
90-43-7
Chemical Name:
2-Phenylphenol
Synonyms
OPP;Xenol;Torsite;Nectryl;o-Xenol;o-Xonal;remoltrf;dowicide1;Dowcide 1;invalonop
CBNumber:
CB0365303
Molecular Formula:
C12H10O
Formula Weight:
170.2072
MOL File:
90-43-7.mol

2-Phenylphenol Properties

Melting point:
57-59 °C(lit.)
Boiling point:
282 °C(lit.)
Density 
1.21
vapor pressure 
7 mm Hg ( 140 °C)
refractive index 
1.6188 (estimate)
FEMA 
3959 | 2-PHENYLPHENOL
Flash point:
255 °F
storage temp. 
0-6°C
solubility 
Soluble in ethanol, acetone, benzene,sodium hydroxide, chloroform, acetonitrile, toluene, hexane, ligroin, ethyl ether, pyridine, ethylene glycol, isopropanol, glycol ethers and polyglycols.
form 
Crystalline Flakes
pka
10.01(at 25℃)
color 
White
PH
7 (0.1g/l, H2O, 20℃)
explosive limit
1.4-9.5%(V)
Water Solubility 
0.7 g/L (20 ºC)
Sensitive 
Hygroscopic
Merck 
14,7304
JECFA Number
735
BRN 
606907
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents, halogens.
InChIKey
LLEMOWNGBBNAJR-UHFFFAOYSA-N
CAS DataBase Reference
90-43-7(CAS DataBase Reference)
NIST Chemistry Reference
o-Hydroxybiphenyl(90-43-7)
EPA Substance Registry System
[1,1'-Biphenyl]- 2-ol(90-43-7)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
  • NFPA
Hazard Codes  Xi,N
Risk Statements  36/37/38-50-37/38/50-36
Safety Statements  22-61
RIDADR  UN 3077 9/PG 3
WGK Germany  2
RTECS  DV5775000
Autoignition Temperature >520 °C
TSCA  Yes
HazardClass  9
PackingGroup  III
HS Code  29071900
Hazardous Substances Data 90-43-7(Hazardous Substances Data)
Toxicity LD50 orally in rats: 2.48 g/kg (Hodge)
Symbol(GHS):
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P391 Collect spillage. Hazardous to the aquatic environment
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container to..…

NFPA 704

Diamond Hazard Value Description
1
3 0
Health   3 Short exposure could cause serious temporary or moderate residual injury (e.g. liquid hydrogen, sulfuric acid, calcium hypochlorite, hexafluorosilicic acid)
Flammability   1 Materials that require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur. Includes some finely divided suspended solids that do not require heating before ignition can occur. Flash point at or above 93.3 °C (200 °F). (e.g. mineral oil, ammonia)
Instability   0 Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2)
Special  

(NFPA, 2010)

2-Phenylphenol price More Price(14)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 45529 2-Phenylphenol PESTANAL , analytical standard 90-43-7 250mg $36.1 2018-11-13 Buy
Sigma-Aldrich P28263 2-Phenylphenol 99% 90-43-7 2kg $182 2018-11-13 Buy
TCI Chemical P0200 2-Phenylphenol >99.0%(GC) 90-43-7 25g $23 2018-11-22 Buy
TCI Chemical P0200 2-Phenylphenol >99.0%(GC) 90-43-7 500g $85 2018-11-22 Buy
Alfa Aesar A10592 2-Phenylphenol, 99% 90-43-7 250g $31.3 2018-11-13 Buy

2-Phenylphenol Chemical Properties,Uses,Production

Chemical properties

Bright purple crystals

uses

1. Fungicides: fruit and vegetable preservative. It is mainly used for the treatment of citrus epidermis mold.
2. For the European Economic Community countries and the United States, in addition to be applied citrus, can still use it for cucumber, carrot, apple, melon, tomatoes and so on. Japan is limited to citrus with the maximum residue 0.01g/kg (1990).
3. The usage condition of each country is as follows (allowable amount, mg/kg) Canadian cherry, 5; citrus, cucumber, pepper, pineapple, tomato, 10; sweet potato, 15; carrot, peach, plum fruit, 20; ; Melon, 12. European citrus, 12. Dutch citrus, 10. English citrus, 70; apple, pear, pineapple, 10; melon, 125. Orange, pepper, pineapple, tomato, sweet potatoes, 15; carrots, peaches, plums, pears, pears, pears, pears, pears, pomegranates, citrus, cucumber, grapefruit: 20; apple, pear, 25; Roman melon, 125 (edible part ≤10).
4. Usage method: The goods is embedded into wax at about 0.8% with spray or dipping way for treatment, being able to prevent the corruption caused by the Gectricnumdidum. This product is of the best efficacy with biphenyl. For the treatment of mildew caused by P. digitation in citrus, 60.% of the untreated product was moldy in about 3 to 5 weeks while only 3.4% of the treated product became moldy finally.
5. 2-Phenylphenol can be used as antiseptic fungicide. China provides that it can be used for citrus preservation with the maximum usage amount of 3.0g/kg and the residue amount being not greater than 12 mg/kg.
6. As antiseptic fungicide, the provisions of China can also be used for citrus preservation, the maximum use of 3.0g/kg and residue being not greater than 12mg/kg.
7. 2-Phenylphenol is used for strong bactericidal function, being used for the preservation of wood, leather and paper as well as storage of fruits and vegetables and meat preservation.
8.  2-hydroxy biphenyl is used as the carrier of carrier dyeing method of hydrophobic synthetic fiber polyvinyl chloride and polyester, surfactants, bactericidal preservatives, dye intermediates. In Japan, 2-hydroxy biphenyl and sodium salt is used for the prevention of citrus mildew. We can embed into wax with 0.8% of the product and spray into the post-harvest citrus, or can also use it in combination with biphenyl, being able to minimize the corruption. Britain, the United States, and Canada allow the use of a larger range of fruits, including apples, pears, pineapple and so on. The goods, as a preservative is also used in cosmetics. The oral LD50 of 2-hydroxybiphenyl to rats was 2.7-3.0 g/kg.
9. It can be used for preservation of fruits and vegetables.
10. 2-Phenylphenol can be applied to fluorescence determination of triose. It can also be used as Dye intermediates.
11. Used as a deoxyribonuclease (DNase) inhibitor;

Identification test

Take 1 mL of 1% ethanol solution, plus 4 mL of 0.2% borax solution and a small amount of small crystals of 2,6-dichloro benzoquinone chloride imine, after shaking, the solution should be green to blue.
Take 1 mL of 1% of the sample ethanol solution, plus 1 mL of formaldehyde sulfuric acid solution (TS-113), the interface should be red.

Content analysis

Accurately weigh about 2 g of powder sample, add 25 mL of sodium hydroxide test solution (TS-224), if necessary, it can be warmly dissolved. Add water to 500ml after cooling and take it as a sample solution. Take 25 mL of this sample solution and transfer into the iodine bottle, accurately add 30 mL of 0.1mol/L potassium bromate solution plus 5 mL potassium bromide test solution (TS-181) 5 mL and 50 mL methanol for thoroughly shaking. Quickly add about 10 mL of 1: 1 dilute hydrochloric acid, immediately plug and gently shake for a reaction of 30s. Take 15 ml of potassium iodide solution (TS-192) and place into the upper part of the iodine bottle, and the stopper was let out to let it flow in. After thoroughly rinsing the stopper and bottle with water, the sample was shaken for 5 min. The free iodine was titrated with 0.1 mol/L sodium thiosulfate solution and the starch test solution (TS-235) was used as the indicator. The same method is applied for blank test to obtain content according to the following formula.
Content (%) = 4.255 × (a-b) /sample amount (g) × 50 × 100%
Where a-blank consumption of sodium thiosulfate volume, m1;
B-Sample solution consumption of sodium thiosulfate volume, ml.

Toxicity

ADI: 0 to 0.2 mg/kg (0.2 to 1.0 mg/kg under certain conditions; FAO/WHO, 2001).
LD50: 2.7 to 3.0 g/kg (rat, oral).
The Tokyo health institute in Japan has found that experimental animals have a significant role in bladder cancer.

Usage limit

GB 2760-2001: citrus fresh 1.0g/kg, residues ≤ 12mg/kg.

Production method

(1) It can be recovered from the distillation residue of the process of phenol production via sulfonation. The phenol distillation residue contains about 40% of phenyl phenol with the other components including phenol, inorganic salts, water and so on. After vacuum distillation, the mixed phenyl phenol fraction is separated out with the vacuum being 53.3-66.7kPa. The temperature, started to be cut at 65-75 ℃ to until 100 ℃ above, but should not higher than 1345 ℃. Then take advantage of the solubility difference of ortho, p-hydroxy biphenyl in the trichlorethylene, the two are separated into pure product. The mixed material (mainly 2-hydroxy biphenyl and 4-hydroxy biphenyl) is heated to be dissolved in the trichlorethylene, after cooling, first precipitate out 4-hydroxy biphenyl crystal. After centrifuge filtration, dry to obtain 4-hydroxy biphenyl. The mother liquor was washed with a sodium carbonate solution, followed by dilute alkaline to make the 2-hydroxybiphenyl salt. After standing stratification, take the upper 2-hydroxybiphenyl sodium salt for dehydration under reduced pressure, namely, sodium salt products. The 2-hydroxybiphenylsodium salt is white to light red powder, being easily soluble in water with the solubility in 100g of water being 122g. The pH value of the 2% aqueous solution is 11.1-12.2. It is also easily soluble in acetone, methanol, soluble in glycerol, but insoluble in oil. The sodium salt of 2-hydroxy biphenyl, after acidification, can lead to the formation of 2-hydroxy biphenyl with both of them being food additives.
(2) The mixture of 2-Phenylphenol (o-phenylphenol) and p-phenylphenol is obtained from the by-product of the phenol production by the sulfonation process. The mixture is heated and dissolved in trichlorethylene. After cooling crystallization, we can obtain para-phenylphenol with centrifuge filtering and solid drying to obtain Phenylphenol. The mother liquor was washed with sodium carbonate solution, neutralized with dilute sodium hydroxide and acidified to give o-phenylphenol.
(3) The distillation residue of sulfonation method for production of phenol production contains about 40% of the mixed (para and ortho) phenyl phenol. Taking advantage of difference of the fractionation and solubility in the trichlorethylene, separate and recover ortho products.
The above distillation residue is subject to vacuum distillation at 53.3~66.7 kPa, collecting the distillate fraction at 65~100 °C, namely mixed phenyl phenol. The mixture was heated to be dissolved in trichlorethylene with cooling first precipitating out the para-phenyl phenol. After centrifugal filtration, wash the mother liquor with sodium carbonate solution so that the o-phenyl phenol will become sodium salt. After standing, take the upper sodium salt, after acidification, we can obtain the product.
(4) It can be obtained through the co-heating of dibenzofuran and sodium metal to about 200 °C with the resulting product subjecting to acid decomposition.
(5) It can be obtained through the diazotization and further hydrolysis of 2-aminobiphenyl.

Hazards & Safety Information

Category Pesticides
Toxic classification poisoning
Acute toxicity Oral-rat LD50: 2000 mg/kg; oral-mouse LD50: 1050 mg/kg
Stimulation Data Skin-Rabbit 20 mg/24hours Moderate; Eyes-Rabbit 0.05 mg/24 h Severe
EXPLOSIVES HAZARDOUS CHARACTERISTICS being explosive when being mixed with air
Flammability and Hazardous properties being flammable with combustion producing irritating fumes
Storage and transportation characteristics Ventilated, low temperature and drying
Fire extinguishing agent dry powder, foam, sand

Chemical Properties

2-Phenylphenol has a distinct odor. It emits acrid smoke and irritating fumes when it is heated to decomposition.

Chemical Properties

o-Phenylphenol is a white to buff-colored crystalline solid.

Chemical Properties

Off-white powder

Uses

2-Phenylphenol is a agriculture fungicide and is no longer used as a food additive.

Uses

2-phenylphenol is remarkably versatile organic chemical products, widely used antiseptic, auxiliaries and surfactant synthesis of new plastics, resins and polymer materials in areas such as stabilizers and flame retardants.

Definition

ChEBI: A member of the class of hydroxybiphenyls that is biphenyl substituted by a hydroxy group at position 2. It is generally used as a post-harvest fungicide for citrus fruits.

Preparation

From chlorobenzene.

General Description

Light lavender crystals or solid.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

2-Phenylphenol react as a weak organic acid. Exothermically neutralizes bases. May react with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides to generate flammable gas (H2) and the heat of the reaction may ignite the gas. Is sulfonated very readily (for example, by concentrated sulfuric acid at room temperature) in exothermic reactions. May be nitrated very rapidly. Nitrated phenols often explode when heated and also form metal salts that tend toward detonation by rather mild shock. Can react with oxidizing agents .

Fire Hazard

2-Phenylphenol is combustible.

Agricultural Uses

Fungicide, Disinfectant, Microbiocide: Used to make fungicides. Also used to make dye stuffs and rubber chemicals, but used primarily as a disinfectant cleaner. Registered for use in the U.S. and U.K.

Trade name

ANTHRAPOLE 73®; DOWCIDE-1®; Invalon OP®; KIWI LUSTR-277®; NECTRYL®; PREVENTOL-O Extra®; REMOL TRF®; TETROSIN OE®; TETROSIN OE-N®; TORSITE®; TUMESCAL OPE®

Potential Exposure

o-Phenylphenol is used in the manufacture of plastics, resins, rubber, as Agricultural chemical, in making fungicides; as an intermediate in making dye stuffs and rubber chemicals; a germicide; used in food packaging.

Shipping

UN3143 Dyes, solid, toxic, n.o.s. or Dye intermediates, solid, toxic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required

Purification Methods

Crystallise it from pet ether. [Beilstein 6 IV 4579.]

Incompatibilities

Strong bases, strong oxidizers

Waste Disposal

In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

2-Phenylphenol Preparation Products And Raw materials

Raw materials

Preparation Products


2-Phenylphenol Suppliers

Global( 268)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Shenzhen Sendi Biotechnology Co.Ltd.
0755-23311925 18102838259
0755-23311925 Abel@chembj.com CHINA 3202 55
Beijing Cooperate Pharmaceutical Co.,Ltd.
+86-10-60279497 +86(0)15646567669
+86-10-60279497 sales01@cooperate-pharm.com CHINA 1817 55
Dalian Richfortune Chemicals Co., Ltd
86-411-84820922, 84821539
86-411-84821380 sales@richfortunechem.com China 360 57
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32447 55
Hefei TNJ Chemical Industry Co.,Ltd.
86-0551-65418684 18949823763
86-0551-65418684 info@tnjchem.com China 1849 55
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 27142 58
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 23964 58
Haihang Industry Co.,Ltd
86-531-88032799
+86 531 8582 1093 export@haihangchem.com CHINA 8260 58
Xiamen AmoyChem Co., Ltd
+86 592-605 1114
sales@amoychem.com CHINA 6370 58
Hubei xin bonus chemical co. LTD
86-13657291602
027-59338440 sales@guangaobio.com CHINA 23049 58

View Lastest Price from 2-Phenylphenol manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-08-08 2-Phenylphenol
90-43-7
US $1.00 / KG 1KG 98% 100Kg career henan chemical co

2-Phenylphenol Spectrum


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