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ETHYLALUMINUM DICHLORIDE

ETHYLALUMINUM DICHLORIDE
ETHYLALUMINUM DICHLORIDE
CAS No.
563-43-9
Chemical Name:
ETHYLALUMINUM DICHLORIDE
Synonyms
EADC;Ethyldichloroaluminum;DICHLOROETHYLALUMINUM;dichloroethyl-aluminu;dichlororthyl aluminium;Ethylaluminiumdichlorid;Aluminum,dichloroethyl-;ethylaluminiu dichloride;Aluminiumethyldichloride;Dichloro(ethyl)aluminium
CBNumber:
CB1476899
Molecular Formula:
C2H5AlCl2
Formula Weight:
126.95
MOL File:
563-43-9.mol

ETHYLALUMINUM DICHLORIDE Properties

Melting point:
32 °C(lit.)
Boiling point:
68-70°C
Density 
0.927 g/mL at 25 °C
vapor pressure 
5 mm Hg ( 60 °C)
Flash point:
40 °F
storage temp. 
0-6°C
form 
Liquid
color 
Colorless to pale yellow
Water Solubility 
Soluble in acetone. Miscible with alcohol, chloroform, ether. Reacts with water.
FreezingPoint 
32℃
Sensitive 
Air & Moisture Sensitive
Merck 
326
InChIKey
UAIZDWNSWGTKFZ-UHFFFAOYSA-L
CAS DataBase Reference
563-43-9(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  F,T,N,C
Risk Statements  11-15-23/24/25-34-14-67-65-62-51/53-48/20-14/15-17-63
Safety Statements  16-26-36/37/39-45-62-61-43-27
RIDADR  UN 3399 4.3/PG 1
WGK Germany  1
RTECS  BD0705000
10-21
TSCA  Yes
HazardClass  4.3
PackingGroup  I
HS Code  29319090
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H250 Catches fire spontaneously if exposed to air Pyrophoric liquids; Pyrorophoric solids Category 1 Danger P210, P222, P280, P302+P334,P370+P378, P422
H252 Self-heating in large quantities; may catch fire Self-heating substances and mixtures Category 2 Warning P235+P410, P280, P407, P413, P420
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H261 In contact with water releases flammable gas Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 2
Category 3
Danger
Warning
P231+P232, P280, P370+P378,P402+P404, P501
H304 May be fatal if swallowed and enters airways Aspiration hazard Category 1 Danger
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H336 May cause drowsiness or dizziness Specific target organ toxicity,single exposure; Narcotic effects Category 3 Warning P261, P271, P304+P340, P312,P403+P233, P405, P501
H361 Suspected of damaging fertility or the unborn child Reproductive toxicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H373 May cause damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 2 Warning P260, P314, P501
H401 Toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 2 P273, P501
H411 Toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 2
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P222 Do not allow contact with air.
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P231+P232 Handle under inert gas. Protect from moisture.
P331 Do NOT induce vomiting.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P302+P334 IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P335+P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P370+P378 In case of fire: Use … for extinction.
P405 Store locked up.
P422 Store contents under …

ETHYLALUMINUM DICHLORIDE price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 192759 Ethylaluminum dichloride solution 25wt. % in toluene 563-43-9 100g $53.9 2018-11-20 Buy
Sigma-Aldrich 192759 Ethylaluminum dichloride solution 25wt. % in toluene 563-43-9 800g $169 2018-11-20 Buy
Alfa Aesar 041712 Ethylaluminum dichloride, 1M in hexane 563-43-9 10ml $10.5 2018-11-16 Buy
Alfa Aesar 041712 Ethylaluminum dichloride, 1M in hexane 563-43-9 250ml $106 2018-11-16 Buy
Sigma-Aldrich 251615 Ethylaluminum dichloride solution 1.0M in hexanes 563-43-9 800ml $112 2018-11-20 Buy

ETHYLALUMINUM DICHLORIDE Chemical Properties,Uses,Production

Chemical Properties

Clear colorless to yellow solution

Chemical Properties

The aluminum alkyl halides are flammable, reactive, and may be spontaneously combustible in air. They are colorless to yellow liquids. Ethylaluminum dichloride:(563-43-9):

Uses

Catalyst for olefin polymerization, aromatic hydrogenation; intermediate.

General Description

A colorless to light-yellow heated liquid. Freezing point 90°F.

Air & Water Reactions

Highly flammable. Ignites when exposed to air. Reacts violently with water or moisture in air forming hydrogen chloride fumes and flammable ethane gas (Rose 1961).

Reactivity Profile

Organometallics, such as ETHYLALUMINUM DICHLORIDE, are reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases. Organometallics containing halogens (fluorine, chlorine, bromine, iodine) bonded to the metal typically with generate gaseous hydrohalic acids (HF, HCl, HBr, HI) with water.

Hazard

Ignites on contact with air, dangerous fire risk, reacts violently with water. Skin irritant.

Health Hazard

Inhalation of smoke from fire causes metal-fume fever (flu-like symptoms); acid fumes irritate nose and throat. Contact with liquid (which is spontaneously flammable) causes severe burns of eyes and skin.

Potential Exposure

These materials are used as components of olefin polymerization catalysts. The reader is referred to the entry on “Aluminum alkyls” for additional information on this entry. The aluminum alkyl halides parallel very closely the aluminum alkyls

Shipping

UN3052 Spontaneously combustible. Water reactive releasing large quantities of toxic and deadly hydrogen gas. (Note: this number does not appear in the 49/CFR HazMat tables)

Incompatibilities

The aluminum alkyl halides are strong reducing agents; they react—possibly violently—with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. These chemicals react violently with nitromethaneEthylaluminum sesquichloride reacts explosively with carbon tetrachloride at room temperature. This chemical reacts violently with water, forming corrosive hydrogen chloride and flammable ethane gas. Diethylaluminum chloride may form an explosive product with chlorine azide.

ETHYLALUMINUM DICHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products


ETHYLALUMINUM DICHLORIDE Suppliers

Global( 60)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Mainchem Co., Ltd.
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Shanghai Hanhong Scientific Co.,Ltd. 021-54306202,021-54308259
+86-21-54291107 info@hanhonggroup.com China 43421 64

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